Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks

Stupp, Samuel I.; Stoddart, J. Fraser; Shveyd, Alex K.; Tayi, Alok S.; Sue, Andrew C. H.; Narayanan, Ashwin

Title: Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks

Patent · Tue Sep 20 00:00:00 EDT 2016

OSTI ID:1325722

Stupp, Samuel I.; Stoddart, J. Fraser; Shveyd, Alex K.; Tayi, Alok S.; Sue, Andrew C. H.; Narayanan, Ashwin

Organic charge-transfer (CT) co-crystals in a mixed stack system are disclosed, wherein a donor molecule (D) and an acceptor molecule (A) occupy alternating positions (DADADA) along the CT axis. A platform is provided which amplifies the molecular recognition of donors and acceptors and produces co-crystals at ambient conditions, wherein the platform comprises (i) a molecular design of the first constituent (.alpha.-complement), (ii) a molecular design of the second compound (.beta.-complement), and (iii) a solvent system that promotes co-crystallization.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: SC0000989

Assignee:: Northwestern University (Evanston, IL)

Patent Number(s):: 9,449,731

Application Number:: 13/476,974

OSTI ID:: 1325722

Resource Relation:: Patent File Date: 2012 May 21

Country of Publication:: United States

Language:: English

References (6)

Supramolecular Networks with Electron Transfer in Two Dimensions Stupp, Samuel I.; Stoddart, J. Fraser; Shveyed, Alexander K. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120319058 US Patent Application 13/526215; 20120319058	patent-application	December 2012
¹H NMR Investigation of Solvent Effects in Aromatic Stacking Interactions Cubberley, Mark S.; Iverson, Brent L. Journal of the American Chemical Society, Vol. 123, Issue 31, p. 7560-7563 https://doi.org/10.1021/ja015817m	journal	August 2001
Cation-reinforced donor-acceptor pseudorotaxanes Pascu, Sofia I.; Jarrosson, Thibaut; Naumann, Christoph New Journal of Chemistry, Vol. 29, Issue 1 https://doi.org/10.1039/B415418E	journal	January 2005
Above-room-temperature ferroelectricity in a single-component molecular crystal Horiuchi, Sachio; Tokunaga, Yusuke; Giovannetti, Gianluca Nature, Vol. 463, Issue 7282, p. 789-792 https://doi.org/10.1038/nature08731	journal	February 2010
Organic ferroelectrics Horiuchi, Sachio; Tokura, Yoshinori Nature Materials, Vol. 7, Issue 5, p. 357-366 https://doi.org/10.1038/nmat2137	journal	May 2008
Electron Transfer in the Supramolecular Donor−Acceptor Dyad of Zinc Hemiporphycene Fujitsuka, Mamoru; Shimakoshi, Hisashi; Tojo, Sachiko The Journal of Physical Chemistry A, Vol. 114, Issue 12, p. 4156-4162 https://doi.org/10.1021/jp9119342	journal	April 2010

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE

Title: Modular supramolecular approach for co-crystallization of donors and acceptors into ordered networks

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