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Title: Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H 2O at 298.15 K to high ionic strengths: Experimental validation and model applications]

Abstract

In this paper, the experimental results from long-term solubility experiments on micro crystalline neodymium hydroxide, Nd(OH) 3(micro cr), in high ionic strength solutions at 298.15 K under well-constrained conditions are presented. The starting material was synthesized according to a well-established method in the literature. In contrast with the previous studies in which hydrogen ion concentrations in experiments were adjusted with addition of either an acid or a base, the hydrogen ion concentrations in our experiments are controlled by the dissolution of Nd(OH) 3(micro cr), avoiding the possibility of phase change.

Authors:
 [1];  [1];  [1]
  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Carlsbad Programs Group
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
1324611
Report Number(s):
SAND2016-5527J
Journal ID: ISSN 1380-6165; 641757
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Aquatic Geochemistry
Additional Journal Information:
Journal Volume: 23; Journal Issue: 5-6; Journal ID: ISSN 1380-6165
Publisher:
Springer
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Xiong, Yongliang, Kirkes, Leslie Dawn, and Marrs, Cassandra. Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]. United States: N. p., 2017. Web. doi:10.1007/s10498-017-9326-6.
Xiong, Yongliang, Kirkes, Leslie Dawn, & Marrs, Cassandra. Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]. United States. doi:10.1007/s10498-017-9326-6.
Xiong, Yongliang, Kirkes, Leslie Dawn, and Marrs, Cassandra. Fri . "Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]". United States. doi:10.1007/s10498-017-9326-6.
@article{osti_1324611,
title = {Long-Term Experimental Determination of Solubilities of Micro-Crystalline Nd(III) Hydroxide in High Ionic Strength Solutions: Applications to Nuclear Waste Management [A Pitzer Model for Am(III)/Nd(III) hydroxide solubility in NaCl-H2O at 298.15 K to high ionic strengths: Experimental validation and model applications]},
author = {Xiong, Yongliang and Kirkes, Leslie Dawn and Marrs, Cassandra},
abstractNote = {In this paper, the experimental results from long-term solubility experiments on micro crystalline neodymium hydroxide, Nd(OH)3(micro cr), in high ionic strength solutions at 298.15 K under well-constrained conditions are presented. The starting material was synthesized according to a well-established method in the literature. In contrast with the previous studies in which hydrogen ion concentrations in experiments were adjusted with addition of either an acid or a base, the hydrogen ion concentrations in our experiments are controlled by the dissolution of Nd(OH)3(micro cr), avoiding the possibility of phase change.},
doi = {10.1007/s10498-017-9326-6},
journal = {Aquatic Geochemistry},
number = 5-6,
volume = 23,
place = {United States},
year = {Fri Dec 01 00:00:00 EST 2017},
month = {Fri Dec 01 00:00:00 EST 2017}
}

Journal Article:
Free Publicly Available Full Text
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