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Title: Real-time 3D imaging of microstructure growth in battery cells using indirect MRI

Abstract

Lithium metal is an ideal anode material for rechargeable Li-ion batteries, but its use is prevented by the growth of lithium deposits, or “dendrites,” during charging that can cause performance loss and serious safety concerns. Understanding the growth of dendrites in situ is crucial for the progress of this technology. MRI has been limited to directly studying the lithium signal until now, resulting in low sensitivity, limited resolution, and long experiment times. We present here an approach that detects the “shadows” of dendrites growing through the electrolyte, allowing the dendrites’ growth to be imaged very quickly in 3D with high resolution. In conclusion, this technique can also be applied to other electrodes, such as those based on sodium, zinc, and magnesium.

Authors:
 [1];  [1];  [2];  [3];  [1]
  1. New York Univ., New York, NY (United States)
  2. Stony Brook Univ., Stony Brook, NY (United States)
  3. Stony Brook Univ., Stony Brook, NY (United States); Univ. of Cambridge, Cambridge (United Kingdom)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC), Washington, D.C. (United States). Northeastern Center for Chemical Energy Storage (NECCES)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1324322
Alternate Identifier(s):
OSTI ID: 1388038
Grant/Contract Number:  
SC0001294; SC0012583; AC02-05CH11231
Resource Type:
Journal Article: Published Article
Journal Name:
Proceedings of the National Academy of Sciences of the United States of America
Additional Journal Information:
Journal Volume: 113; Journal Issue: 39; Related Information: NECCES partners with Stony Brook University (lead); Argonne National Laboratory; Binghamton University; Brookhaven National University; University of California, San Diego; University of Cambridge, UK; Lawrence Berkeley National Laboratory; Massachusetts Institute of Technology; University of Michigan; Rutgers University; Journal ID: ISSN 0027-8424
Publisher:
National Academy of Sciences, Washington, DC (United States)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE; energy storage (including batteries and capacitors); defects; charge transport; materials and chemistry by design; synthesis (novel materials)

Citation Formats

Ilott, Andrew J., Mohammadi, Mohaddese, Chang, Hee Jung, Grey, Clare P., and Jerschow, Alexej. Real-time 3D imaging of microstructure growth in battery cells using indirect MRI. United States: N. p., 2016. Web. doi:10.1073/pnas.1607903113.
Ilott, Andrew J., Mohammadi, Mohaddese, Chang, Hee Jung, Grey, Clare P., & Jerschow, Alexej. Real-time 3D imaging of microstructure growth in battery cells using indirect MRI. United States. doi:10.1073/pnas.1607903113.
Ilott, Andrew J., Mohammadi, Mohaddese, Chang, Hee Jung, Grey, Clare P., and Jerschow, Alexej. Mon . "Real-time 3D imaging of microstructure growth in battery cells using indirect MRI". United States. doi:10.1073/pnas.1607903113.
@article{osti_1324322,
title = {Real-time 3D imaging of microstructure growth in battery cells using indirect MRI},
author = {Ilott, Andrew J. and Mohammadi, Mohaddese and Chang, Hee Jung and Grey, Clare P. and Jerschow, Alexej},
abstractNote = {Lithium metal is an ideal anode material for rechargeable Li-ion batteries, but its use is prevented by the growth of lithium deposits, or “dendrites,” during charging that can cause performance loss and serious safety concerns. Understanding the growth of dendrites in situ is crucial for the progress of this technology. MRI has been limited to directly studying the lithium signal until now, resulting in low sensitivity, limited resolution, and long experiment times. We present here an approach that detects the “shadows” of dendrites growing through the electrolyte, allowing the dendrites’ growth to be imaged very quickly in 3D with high resolution. In conclusion, this technique can also be applied to other electrodes, such as those based on sodium, zinc, and magnesium.},
doi = {10.1073/pnas.1607903113},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 39,
volume = 113,
place = {United States},
year = {Mon Sep 12 00:00:00 EDT 2016},
month = {Mon Sep 12 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1073/pnas.1607903113

Citation Metrics:
Cited by: 7 works
Citation information provided by
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Works referenced in this record:

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644