skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Laser damage mechanisms in conductive widegap semiconductor films

Journal Article · · Optics Express
DOI:https://doi.org/10.1364/OE.24.017616· OSTI ID:1313552
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [3];  [1];  [1]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  2. Cornell Univ., Ithaca, NY (United States)
  3. Univ. of Rochester, Rochester, NY (United States)

Here, laser damage mechanisms of two conductive wide-bandgap semiconductor films - indium tin oxide (ITO) and silicon doped GaN (Si:GaN) were studied via microscopy, spectroscopy, photoluminescence (PL), and elemental analysis. Nanosecond laser pulse exposures with a laser photon energy (1.03 eV, 1064 nm) smaller than the conductive films bandgaps were applied and radically different film damage morphologies were produced. The laser damaged ITO film exhibited deterministic features of thermal degradation. In contrast, laser damage in the Si:GaN film resulted in highly localized eruptions originating at interfaces. For ITO, thermally driven damage was related to free carrier absorption and, for GaN, carbon complexes were proposed as potential damage precursors or markers.

Research Organization:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC52-07NA27344
OSTI ID:
1313552
Report Number(s):
LLNL-JRNL-694293; OPEXFF
Journal Information:
Optics Express, Vol. 24, Issue 16; ISSN 1094-4087
Publisher:
Optical Society of America (OSA)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 25 works
Citation information provided by
Web of Science

References (44)

Morphologies of laser-induced damage in hafnia-silica multilayer mirror and polarizer coatings
  • Genin, Francois Y.; Stolz, Christopher J.
  • Third International Workshop on Laser Beam and Optics Characterization, SPIE Proceedings https://doi.org/10.1117/12.259929
conference November 1996
Chemical origin of the yellow luminescence in GaN journal May 2002
Novel geometrical effects observed in debris when polymers are laser sputtered journal December 1992
Effect of substrate absorption on the efficiency of laser patterning of indium tin oxide thin films journal April 1999
Flattening of a Nearly Plane Solid Surface due to Capillarity journal January 1959
Scattering mechanisms of charge carriers in transparent conducting oxide films journal May 1996
Fabrication of periodic nano-hole array on GaN surface by fs laser for improvement of extraction efficiency in blue LED journal January 2010
Low resistivity indium–tin oxide transparent conductive films. II. Effect of sputtering voltage on electrical property of films journal May 1990
GaN surface ablation by femtosecond pulses: atomic force microscopy studies and accumulation effects conference January 2000
Incubation effect and its influence on laser patterning of ITO thin film journal March 2012
Depth profiling of thin ITO films by grazing incidence X-ray diffraction journal May 1996
Phase equilibria in the pseudo-binary In2O3–SnO2 system journal May 2007
Raman scattering studies on single-crystalline bulk AlN under high pressures journal February 2001
Thermal stress in GaN epitaxial layers grown on sapphire substrates journal May 1995
Thermal mechanisms of laser micromachining of indium tin oxide conference July 2004
Epitaxial growth of GaN films on unconventional oxide substrates journal January 2014
Laser‐damage‐resistant transparent conductive indium tin oxide coatings journal February 1979
Degenerate layer at GaN/sapphire interface: Influence on Hall-effect measurements journal June 1997
Directed dewetting of amorphous silicon film by a donut-shaped laser pulse journal April 2015
Laser-Induced Damage Threshold and Surface Processing of GaN at 400 nm Wavelength journal July 1999
Thermal transport in CO2 laser irradiated fused silica: In situ measurements and analysis journal November 2009
Fine structure of the red luminescence band in undoped GaN journal January 2014
Strain-related phenomena in GaN thin films journal December 1996
Progress in high average power ultrafast lasers journal October 2015
Optical and electrical properties of doped In2O3 films journal May 1975
GaN decomposition in H2 and N2 at MOVPE temperatures and pressures journal March 2001
Hardness and fracture toughness of bulk single crystal gallium nitride journal December 1996
Mechanisms and fast kinetics of the catastrophic optical damage (COD) in GaAs-based diode lasers journal March 2011
The surface and materials science of tin oxide journal January 2005
Thermal stability of sputter-deposited ZnO thin films journal February 1995
Yellow Luminescence of Gallium Nitride Generated by Carbon Defect Complexes journal February 2013
Raman spectroscopy of GaN, AlGaN and AlN for process and growth monitoring/control journal January 2001
Stress relaxation in Si-doped GaN studied by Raman spectroscopy journal June 1998
Thickness effect on laser-induced-damage threshold of indium-tin oxide films at 1064 nm journal December 2011
Photoinscription domains for ultrafast laser writing of refractive index changes in BK7 borosilicate crown optical glass journal December 2012
Dislocation effect on light emission efficiency in gallium nitride journal December 2002
Laser ablation of polymers in pressurized gas ambients journal January 1987
Femtosecond laser machining of gallium nitride journal May 2001
Luminescence properties of defects in GaN journal March 2005
Damage on fused silica optics caused by laser ablation of surface-bound microparticles journal January 2016
Fracture-induced subbandgap absorption as a precursor to optical damage on fused silica surfaces journal January 2010
Dewetting Patterns and Molecular Forces: A Reconciliation journal June 2001
Transient plasma shielding effects during pulsed laser ablation of materials journal January 1996
Deep acceptors trapped at threading-edge dislocations in GaN journal November 1998

Cited By (5)

A Survey of Transparent Conducting Films and Optoelectrical Materials for High Optical Power Applications journal September 2019
Mid-infrared femtosecond laser-induced damages in As2S3 and As2Se3 chalcogenide glasses journal July 2017
Lifetime laser damage performance of β-Ga 2 O 3 for high power applications journal March 2018
Thermally ruggedized ITO transparent electrode films for high power optoelectronics journal January 2017
A Survey of Transparent Conducting Films and Optoelectrical Materials for High Optical Power Applications journal September 2019

Figures / Tables (17)