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Title: MCrAlY bond coat with enhanced yttrium

Patent ·
OSTI ID:1312646

One or more embodiments relates to a method of producing an MCrAlY bond coat comprising an MCrAlY layer in contact with a Y--Al.sub.2O.sub.3 layer. The MCrAlY layer is comprised of a .gamma.-M solid solution, a .beta.-MAl intermetallic phase, and Y-type intermetallics. The Y--Al.sub.2O.sub.3 layer is comprised of Yttrium atoms coordinated with oxygen atoms comprising the Al.sub.2O.sub.3 lattice. The method comprises depositing an MCrAlY material on a substrate, applying an Y.sub.2O.sub.3 paste, and heating the substrate in a non-oxidizing atmosphere at a temperature between 400-1300.degree. C. for a time sufficient to generate the Y--Al.sub.2O.sub.3 layer. Both the MCrAlY layer and the Y--Al.sub.2O.sub.3 layer have a substantial absence of Y.sub.2O.sub.3, YAG, and YAP phases.

Research Organization:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)
Sponsoring Organization:
USDOE
Assignee:
U.S. Department of Energy (Washington, DC)
Patent Number(s):
9,428,825
Application Number:
13/363,486
OSTI ID:
1312646
Resource Relation:
Patent File Date: 2012 Feb 01
Country of Publication:
United States
Language:
English

References (9)

In-situ formation of multiphase deposited thermal barrier coatings patent January 2004
Halogen gas plasma-resistive members and method for producing the same, laminates, and corrosion-resistant members patent August 2004
Highly oxidation resistant component patent May 2008
Method of applying a cerium diffusion coating to a metallic alloy patent June 2009
Methods for fabricating YAG barrier coatings patent May 2011
Parameters affecting TGO growth and adherence on MCrAlY-bond coats for TBC's journal December 2006
Y-rich oxide distribution in plasma sprayed MCrAlY-coatings studied by SEM with a cathodoluminescence detector and Raman spectroscopy journal November 2009
Effect of manufacturing related parameters on oxidation properties of MCrAlY-bondcoats journal June 2008
Optimization of Reactive-Element Additions to Improve Oxidation Performance of Alumina-Forming Alloys journal April 2003

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