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Title: CaO-MgO-Al 2O 3-SiO 2 (CMAS) corrosion of Gd 2Zr 2O 7 and Sm 2Zr 2O 7

Abstract

Ceramic thermal barrier coatings are applied to superalloys used in gas turbine engineering to increase the operating temperature and the energy conversion efficiency. However, dust consisting of CaO-MgO-Al 2O 3-SiO 2 (CMAS) from the air can be injected into the engines and corrode the thermal barrier coatings. Lanthanide zirconates are promising materials in thermal barrier coatings due to their low thermal conductivities, good phase stability and good corrosion resistance. However, the corrosion resistance mechanism of CMAS on lanthanide zirconates is still not clearly understood. In this work, the corrosion mechanism of Gd 2Zr 2O 7 and Sm 2Zr 2O 7 in CMAS is studied. Here, the results show that the CMAS can easily react with lanthanide zirconate thermal barrier coatings to form a dense layer, which can resist further corrosion

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Auburn Univ., Auburn, AL (United States)
Publication Date:
Research Org.:
Auburn Univ., AL (United States)
Sponsoring Org.:
USDOE Office of Fossil Energy (FE), Clean Coal and Carbon (FE-20)
OSTI Identifier:
1289513
Grant/Contract Number:
FE0011245
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 163; Journal Issue: 10; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Wang, Honglong, Bakal, Ahmet, Zhang, Xingxing, Tarwater, Emily, Sheng, Zhizhi, and Fergus, Jeffrey W. CaO-MgO-Al2O3-SiO2 (CMAS) corrosion of Gd2Zr2O7 and Sm2Zr2O7. United States: N. p., 2016. Web. doi:10.1149/2.0301610jes.
Wang, Honglong, Bakal, Ahmet, Zhang, Xingxing, Tarwater, Emily, Sheng, Zhizhi, & Fergus, Jeffrey W. CaO-MgO-Al2O3-SiO2 (CMAS) corrosion of Gd2Zr2O7 and Sm2Zr2O7. United States. doi:10.1149/2.0301610jes.
Wang, Honglong, Bakal, Ahmet, Zhang, Xingxing, Tarwater, Emily, Sheng, Zhizhi, and Fergus, Jeffrey W. 2016. "CaO-MgO-Al2O3-SiO2 (CMAS) corrosion of Gd2Zr2O7 and Sm2Zr2O7". United States. doi:10.1149/2.0301610jes. https://www.osti.gov/servlets/purl/1289513.
@article{osti_1289513,
title = {CaO-MgO-Al2O3-SiO2 (CMAS) corrosion of Gd2Zr2O7 and Sm2Zr2O7},
author = {Wang, Honglong and Bakal, Ahmet and Zhang, Xingxing and Tarwater, Emily and Sheng, Zhizhi and Fergus, Jeffrey W.},
abstractNote = {Ceramic thermal barrier coatings are applied to superalloys used in gas turbine engineering to increase the operating temperature and the energy conversion efficiency. However, dust consisting of CaO-MgO-Al2O3-SiO2 (CMAS) from the air can be injected into the engines and corrode the thermal barrier coatings. Lanthanide zirconates are promising materials in thermal barrier coatings due to their low thermal conductivities, good phase stability and good corrosion resistance. However, the corrosion resistance mechanism of CMAS on lanthanide zirconates is still not clearly understood. In this work, the corrosion mechanism of Gd2Zr2O7 and Sm2Zr2O7 in CMAS is studied. Here, the results show that the CMAS can easily react with lanthanide zirconate thermal barrier coatings to form a dense layer, which can resist further corrosion},
doi = {10.1149/2.0301610jes},
journal = {Journal of the Electrochemical Society},
number = 10,
volume = 163,
place = {United States},
year = 2016,
month = 8
}

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