Visible-light-driven Bi 2 O 3 /WO 3 composites with enhanced photocatalytic activity

Adhikari, Shiba P.; Dean, Hunter; Hood, Zachary D.; Peng, Rui; More, Karren L.; Ivanov, Ilia; Wu, Zili; Lachgar, Abdou

doi:10.1039/c5ra13579f

Title: Visible-light-driven Bi ₂ O ₃ /WO ₃ composites with enhanced photocatalytic activity

Journal Article · Mon Oct 19 00:00:00 EDT 2015 · RSC Advances

DOI:https://doi.org/10.1039/c5ra13579f· OSTI ID:1286959

Adhikari, Shiba P. ^[1]; Dean, Hunter ^[1]; Hood, Zachary D. ^[2]; Peng, Rui ^[2]; More, Karren L. ^[2]; Ivanov, Ilia ^[2]; Wu, Zili ^[2]; Lachgar, Abdou ^[1]

Wake Forest Univ., Winston Salem, NC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Semiconductor heterojunctions (composites) have been shown to be effective photocatalytic materials to overcome the drawbacks of low photocatalytic efficiency that results from electron–hole recombination and narrow photo-response range. We prepared a novel visible-light-driven Bi₂O₃/WO₃ composite photocatalyst by hydrothermal synthesis. The composite was characterized by scanning transmission electron microscopy (STEM), scanning electron microscopy (SEM), powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), Brunauer–Emmett–Teller (BET) surface area, Raman spectroscopy, photoluminescence spectroscopy (PL) and electrochemical impedance spectroscopy (EIS) to better understand the structures, compositions, morphologies and optical properties. Bi₂O₃/WO₃ heterojunction was found to exhibit significantly higher photocatalytic activity towards the decomposition of Rhodamine B (RhB) and 4-nitroaniline (4-NA) under visible light irradiation compared to that of Bi₂O₃ and WO₃. A tentative mechanism for the enhanced photocatalytic activity of the heterostructured composite is discussed based on observed activity, band position calculations, photoluminescence, and electrochemical impedance data. Our study provides a new strategy for the design of composite materials with enhanced visible light photocatalytic performance.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1286959

Journal Information:: RSC Advances, Vol. 5, Issue 111; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 43 works

Citation information provided by
Web of Science

References (61)

Solar Energy Conversion and Environmental Remediation Using Inorganic Semiconductor–Liquid Interfaces: The Road Traveled and the Way Forward Rajeshwar, Krishnan The Journal of Physical Chemistry Letters, Vol. 2, Issue 11 https://doi.org/10.1021/jz200396h	journal	May 2011
Electrochemical Photolysis of Water at a Semiconductor Electrode Fujishima, Akira; Honda, Kenichi Nature, Vol. 238, Issue 5358, p. 37-38 https://doi.org/10.1038/238037a0	journal	July 1972
Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting Osterloh, Frank E. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35266D	journal	January 2013
Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides Asahi, R. Science, Vol. 293, Issue 5528 https://doi.org/10.1126/science.1061051	journal	July 2001
A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production Ni, Meng; Leung, Michael K. H.; Leung, Dennis Y. C. Renewable and Sustainable Energy Reviews, Vol. 11, Issue 3 https://doi.org/10.1016/j.rser.2005.01.009	journal	April 2007
Recent progress on photocatalytic and photoelectrochemical water splitting under visible light irradiation Abe, Ryu Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Vol. 11, Issue 4 https://doi.org/10.1016/j.jphotochemrev.2011.02.003	journal	December 2010
Doped-TiO2: A Review Zaleska, Adriana Recent Patents on Engineering, Vol. 2, Issue 3 https://doi.org/10.2174/187221208786306289	journal	November 2008
Semiconductor heterojunction photocatalysts: design, construction, and photocatalytic performances Wang, Huanli; Zhang, Lisha; Chen, Zhigang Chemical Society Reviews, Vol. 43, Issue 15 https://doi.org/10.1039/C4CS00126E	journal	January 2014
Semiconductor Composites: Strategies for Enhancing Charge Carrier Separation to Improve Photocatalytic Activity Marschall, Roland Advanced Functional Materials, Vol. 24, Issue 17 https://doi.org/10.1002/adfm.201303214	journal	December 2013
WO ₃ −Fe ₂ O ₃ Photoanodes for Water Splitting: A Host Scaffold, Guest Absorber Approach Sivula, Kevin; Formal, Florian Le; Grätzel, Michael Chemistry of Materials, Vol. 21, Issue 13 https://doi.org/10.1021/cm900565a	journal	July 2009
Hydrothermal synthesis of monoclinic WO3 nanoplates and nanorods used as an electrocatalyst for hydrogen evolution reactions from water Ham, Dong Jin; Phuruangrat, Anukorn; Thongtem, Somchai Chemical Engineering Journal, Vol. 165, Issue 1 https://doi.org/10.1016/j.cej.2010.09.003	journal	November 2010
Inactivation of avian influenza virus H1N1 by photocatalyst under visible light irradiation Takehara, Kazuaki; Yamazaki, Kumiko; Miyazaki, Mai Virus Research, Vol. 151, Issue 1 https://doi.org/10.1016/j.virusres.2010.03.006	journal	July 2010
Pristine Simple Oxides as Visible Light Driven Photocatalysts: Highly Efficient Decomposition of Organic Compounds over Platinum-Loaded Tungsten Oxide Abe, Ryu; Takami, Hitoshi; Murakami, Naoya Journal of the American Chemical Society, Vol. 130, Issue 25 https://doi.org/10.1021/ja800835q	journal	June 2008
Removal of Rhodamine 6G induced by laser and catalyzed by Pt/WO3 nanocomposite Qamar, M.; Gondal, M. A.; Yamani, Z. H. Catalysis Communications, Vol. 11, Issue 8 https://doi.org/10.1016/j.catcom.2010.02.012	journal	March 2010
Improved Photocatalytic Activity of WO ₃ through Clustered Fe ₂ O ₃ for Organic Degradation in the Presence of H ₂ O ₂ Bi, Dongqin; Xu, Yiming Langmuir, Vol. 27, Issue 15 https://doi.org/10.1021/la2012793	journal	August 2011
Thermodecomposition synthesis of WO3/H2WO4 heterostructures with enhanced visible light photocatalytic properties Cao, Jing; Luo, Bangde; Lin, Haili Applied Catalysis B: Environmental, Vol. 111-112 https://doi.org/10.1016/j.apcatb.2011.10.010	journal	January 2012
WO3/TiO2 composite with morphology change via hydrothermal template-free route as an efficient visible light photocatalyst Leghari, Sajjad Ahmed Khan; Sajjad, Shamaila; Chen, Feng Chemical Engineering Journal, Vol. 166, Issue 3 https://doi.org/10.1016/j.cej.2010.11.065	journal	February 2011
CuO/WO3 and Pt/WO3 nanocatalysts for efficient pollutant degradation using visible light irradiation Widiyandari, Hendri; Purwanto, Agus; Balgis, Ratna Chemical Engineering Journal, Vol. 180 https://doi.org/10.1016/j.cej.2011.10.095	journal	January 2012
Efficient Complete Oxidation of Acetaldehyde into CO ₂ over CuBi ₂ O ₄ /WO ₃ Composite Photocatalyst under Visible and UV Light Irradiation Arai, Takeo; Yanagida, Masatoshi; Konishi, Yoshinari The Journal of Physical Chemistry C, Vol. 111, Issue 21 https://doi.org/10.1021/jp0725533	journal	May 2007
Efficient Visible Light Active CaFe ₂ O ₄ /WO ₃ Based Composite Photocatalysts: Effect of Interfacial Modification Liu, Zhifu; Zhao, Zhi-Gang; Miyauchi, Masahiro The Journal of Physical Chemistry C, Vol. 113, Issue 39 https://doi.org/10.1021/jp906195f	journal	September 2009
Photocatalytic activity of zinc modified Bi2O3 Hameed, Abdul; Gombac, Valentina; Montini, Tiziano Chemical Physics Letters, Vol. 483, Issue 4-6 https://doi.org/10.1016/j.cplett.2009.10.087	journal	December 2009
Tailoring the band structure of β-Bi2O3 by co-doping for realized photocatalytic hydrogen generation Li, Min; Li, Feng; Yin, Peng Gang Chemical Physics Letters, Vol. 601 https://doi.org/10.1016/j.cplett.2014.03.091	journal	May 2014
Heterojunctioned BiOCl/Bi2O3, a new visible light photocatalyst Chai, Seung Yong; Kim, Yong Joo; Jung, Myong Hak Journal of Catalysis, Vol. 262, Issue 1 https://doi.org/10.1016/j.jcat.2008.12.020	journal	February 2009
Contributions of conduction band offset to the enhanced separation efficiency of photoinduced charges for SrTiO3/Bi2O3 heterojunction semiconductor Zhang, Zhenlong; Zhu, Jichun; Li, Shengjun Journal of Solid State Chemistry, Vol. 211 https://doi.org/10.1016/j.jssc.2013.12.022	journal	March 2014
Facile fabrication of Bi2O3/TiO2-xNx nanocomposites for excellent visible light driven photocatalytic hydrogen evolution Naik, Brundabana; Martha, Satyabadi; Parida, K. M. International Journal of Hydrogen Energy, Vol. 36, Issue 4 https://doi.org/10.1016/j.ijhydene.2010.11.104	journal	February 2011
Photocatalytic Activities of Heterojunction Semiconductors Bi ₂ O ₃ /BaTiO ₃ : A Strategy for the Design of Efficient Combined Photocatalysts Lin, Xinping; Xing, Jingcheng; Wang, Wendeng The Journal of Physical Chemistry C, Vol. 111, Issue 49 https://doi.org/10.1021/jp073955d	journal	December 2007
Visible light assisted photocatalytic hydrogen generation by Ta ₂ O ₅ /Bi ₂ O ₃ , TaON/Bi ₂ O ₃ , and Ta ₃ N ₅ /Bi ₂ O ₃ composites Adhikari, Shiba P.; Hood, Zachary D.; More, Karren L. RSC Advances, Vol. 5, Issue 68 https://doi.org/10.1039/C5RA06563A	journal	January 2015
Microwave-assisted solution-phase preparation of flower-like Bi ₂ WO ₆ and its visible-light-driven photocatalytic properties Cao, Xiao-Feng; Zhang, Lei; Chen, Xue-Tai CrystEngComm, Vol. 13, Issue 1 https://doi.org/10.1039/C0CE00031K	journal	January 2011
Significant enhanced performance for Rhodamine B, phenol and Cr(VI) removal by Bi2WO6 nancomposites via reduced graphene oxide modification Ma, Hongwei; Shen, Jianfeng; Shi, Min Applied Catalysis B: Environmental, Vol. 121-122 https://doi.org/10.1016/j.apcatb.2012.03.023	journal	June 2012
Synthesis and visible light photocatalytic behavior of WO3 (core)/Bi2WO6 (shell) He, Guo-Hua; He, Gang-Ling; Li, An-Jie Journal of Molecular Catalysis A: Chemical, Vol. 385 https://doi.org/10.1016/j.molcata.2014.01.022	journal	April 2014
Novel BiIO ₄ /BiVO ₄ composite photocatalyst with highly improved visible-light-induced photocatalytic performance for rhodamine B degradation and photocurrent generation Huang, Hongwei; Liu, Liyuan; Zhang, Yihe RSC Advances, Vol. 5, Issue 2 https://doi.org/10.1039/C4RA12916D	journal	January 2015
Template-Free Fabrication of Bi ₂ O ₃ and (BiO) ₂ CO ₃ Nanotubes and Their Application in Water Treatment Qin, Fan; Li, Guangfang; Wang, Runming Chemistry - A European Journal, Vol. 18, Issue 51 https://doi.org/10.1002/chem.201201989	journal	October 2012
ZnWO ₄ /WO ₃ Composite for Improving Photoelectrochemical Water Oxidation Leonard, Kevin C.; Nam, Ki Min; Lee, Heung Chan The Journal of Physical Chemistry C, Vol. 117, Issue 31 https://doi.org/10.1021/jp403506q	journal	July 2013
Photocatalytic properties of nanosized Bi2WO6 catalysts synthesized via a hydrothermal process Fu, Hongbo; Zhang, Liwu; Yao, Wenqing Applied Catalysis B: Environmental, Vol. 66, Issue 1-2 https://doi.org/10.1016/j.apcatb.2006.02.022	journal	June 2006
Enhancement of Visible-Light Photocatalysis by Coupling with Narrow-Band-Gap Semiconductor: A Case Study on Bi ₂ S ₃ /Bi ₂ WO ₆ Zhang, Zhijie; Wang, Wenzhong; Wang, Lu ACS Applied Materials & Interfaces, Vol. 4, Issue 2 https://doi.org/10.1021/am2017199	journal	January 2012
Synthesis of one-dimensional WO ₃ –Bi ₂ WO ₆ heterojunctions with enhanced photocatalytic activity Peng, Yin; Chen, Qing-Guo; Wang, Dan CrystEngComm, Vol. 17, Issue 3 https://doi.org/10.1039/C4CE01884B	journal	January 2015
Bi ₂ O ₃ −Bi ₂ WO ₆ Composite Microspheres: Hydrothermal Synthesis and Photocatalytic Performances Ge, Ming; Li, Yafei; Liu, Lu The Journal of Physical Chemistry C, Vol. 115, Issue 13 https://doi.org/10.1021/jp108414e	journal	March 2011
Preparation of novel Sb2O3/WO3 photocatalysts and their activities under visible light irradiation He, Guo-Hua; Liang, Can-Jian; Ou, Yu-Da Materials Research Bulletin, Vol. 48, Issue 6 https://doi.org/10.1016/j.materresbull.2013.02.055	journal	June 2013
A Templated Method to Bi ₂ WO ₆ Hollow Microspheres and Their Conversion to Double-Shell Bi ₂ O ₃ /Bi ₂ WO ₆ Hollow Microspheres with Improved Photocatalytic Performance Li, Xiaona; Huang, Renkun; Hu, Yanhua Inorganic Chemistry, Vol. 51, Issue 11 https://doi.org/10.1021/ic300454q	journal	May 2012
Hierarchical SiO ₂ @Bi ₂ O ₃ core/shell electrospun fibers for infrared stealth camouflage Liu, Xin-Fang; Lai, Yue-Kun; Huang, Jian-Ying Journal of Materials Chemistry C, Vol. 3, Issue 2 https://doi.org/10.1039/C4TC01873G	journal	January 2015
Visible-light-induced WO3/g-C3N4 composites with enhanced photocatalytic activity Huang, Liying; Xu, Hui; Li, Yeping Dalton Transactions, Vol. 42, Issue 24 https://doi.org/10.1039/c3dt00115f	journal	January 2013
Agx@WO3 core-shell nanostructure for LSP enhanced chemical sensors Xu, Lijie; Yin, Ming-Li; (Frank) Liu, Shengzhong Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep06745	journal	October 2014
Photocatalytic degradation of methylene blue on CaBi6O10/Bi2O3 composites under visible light Wang, Yongjiao; He, Yiming; Li, Tingting Chemical Engineering Journal, Vol. 189-190 https://doi.org/10.1016/j.cej.2012.02.079	journal	May 2012
Polymorph-Tuned Synthesis of α- and β-Bi2O3 Nanowires and Determination of Their Growth Direction from Polarized Raman Single Nanowire Microscopy In, Juneho; Yoon, Ilsun; Seo, Kwanyong Chemistry - A European Journal, Vol. 17, Issue 4 https://doi.org/10.1002/chem.201001684	journal	November 2010
Enhanced visible-light photocatalytic activity of plasmonic Ag and graphene co-modified Bi ₂ WO ₆ nanosheets Low, Jingxiang; Yu, Jiaguo; Li, Qin Phys. Chem. Chem. Phys., Vol. 16, Issue 3 https://doi.org/10.1039/C3CP53820F	journal	January 2014
Carbon-modified Bi2WO6 nanostructures with improved photocatalytic activity under visible light Li, Yuanyuan; Liu, Jinping; Huang, Xintang Dalton Transactions, Vol. 39, Issue 14 https://doi.org/10.1039/b924584g	journal	January 2010
Photodegradation of rhodamine B in aqueous solution via SiO2@TiO2 nano-spheres Wilhelm, Patrick; Stephan, Dietmar Journal of Photochemistry and Photobiology A: Chemistry, Vol. 185, Issue 1 https://doi.org/10.1016/j.jphotochem.2006.05.003	journal	January 2007
Visible Photocatalytic Activity Enhancement of ZnWO ₄ by Graphene Hybridization Bai, Xiaojuan; Wang, Li; Zhu, Yongfa ACS Catalysis, Vol. 2, Issue 12 https://doi.org/10.1021/cs3005852	journal	November 2012
Hydrothermal synthesis of In 2 S 3 /g-C 3 N 4 heterojunctions with enhanced photocatalytic activity Xing, Chaosheng; Wu, Zhudong; Jiang, Deli Journal of Colloid and Interface Science, Vol. 433 https://doi.org/10.1016/j.jcis.2014.07.015	journal	November 2014
Visible-light-induced photocatalytic hydrogenation of 4-nitroaniline over In2S3 photocatalyst in water Wu, Weiming; Lin, Rui; Shen, Lijuan Catalysis Communications, Vol. 40 https://doi.org/10.1016/j.catcom.2013.05.016	journal	October 2013
Photocatalytic reduction of nitrobenzenes to aminobenzenes in aqueous suspensions of titanium(iv) oxide in the presence of hole scavengers under deaerated and aerated conditions Imamura, Kazuya; Iwasaki, Shin-ichi; Maeda, Tsuyoshi Physical Chemistry Chemical Physics, Vol. 13, Issue 11 https://doi.org/10.1039/c0cp02279a	journal	January 2011
Efficient visible-light-induced photocatalytic reduction of 4-nitroaniline to p-phenylenediamine over nanocrystalline PbBi2Nb2O9 Wu, Weiming; Liu, Guodong; Liang, Shijing Journal of Catalysis, Vol. 290 https://doi.org/10.1016/j.jcat.2012.02.005	journal	June 2012
Efficient plasmonic photocatalytic activity on silver-nanoparticle-decorated AgVO ₃ nanoribbons Wei, Zhao; Feng, Liang; Zhi-Ming, Jin J. Mater. Chem. A, Vol. 2, Issue 33 https://doi.org/10.1039/C4TA02369B	journal	January 2014
Efficient Photocatalytic Degradation of Phenol over Co ₃ O ₄ /BiVO ₄ Composite under Visible Light Irradiation Long, Mingce; Cai, Weimin; Cai, Jun The Journal of Physical Chemistry B, Vol. 110, Issue 41 https://doi.org/10.1021/jp063441z	journal	October 2006
Prediction of Flatband Potentials at Semiconductor-Electrolyte Interfaces from Atomic Electronegativities Butler, M. A. Journal of The Electrochemical Society, Vol. 125, Issue 2 https://doi.org/10.1149/1.2131419	journal	January 1978
Preparation, characterization, and enhanced visible-light photocatalytic activity of AgI/Bi2WO6 composite Chen, Bingang; Deng, Yongyong; Tong, Hanxuan Superlattices and Microstructures, Vol. 69 https://doi.org/10.1016/j.spmi.2014.01.019	journal	May 2014
Synthesis of Bi2O3/Cu2O nanoflowers by hydrothermal method and its photocatalytic activity enhancement under simulated sunlight Abdulkarem, A. M.; Aref, A. A.; Abdulhabeeb, A. Journal of Alloys and Compounds, Vol. 560 https://doi.org/10.1016/j.jallcom.2013.01.134	journal	May 2013
Photophysical and Photocatalytic Properties of AgInW ₂ O ₈ Tang, Junwang; Zou, Zhigang; Ye, Jinhua The Journal of Physical Chemistry B, Vol. 107, Issue 51 https://doi.org/10.1021/jp0359891	journal	December 2003
Roles of TaON and Ta3N5 in the visible-Fenton-like degradation of atrazine Du, Yingxun; Zhao, Lu; Zhang, Yuanyuan Journal of Hazardous Materials, Vol. 267 https://doi.org/10.1016/j.jhazmat.2013.12.042	journal	February 2014
Hematite/Si Nanowire Dual-Absorber System for Photoelectrochemical Water Splitting at Low Applied Potentials Mayer, Matthew T.; Du, Chun; Wang, Dunwei Journal of the American Chemical Society, Vol. 134, Issue 30 https://doi.org/10.1021/ja3051734	journal	July 2012
Fabrication of High Conductivity TiO ₂ /Ag Fibrous Electrode by the Electrophoretic Deposition Method Hosseini, Z.; Taghavinia, N.; Sharifi, N. The Journal of Physical Chemistry C, Vol. 112, Issue 47 https://doi.org/10.1021/jp8046054	journal	November 2008

Cited By (1)

Role of fullerene to improve the WO ₃ performance for photocatalytic applications and hydrogen evolution Bilal Tahir, Muhammad; Nabi, Ghulam; Rafique, M. International Journal of Energy Research, Vol. 42, Issue 15 https://doi.org/10.1002/er.4231	journal	October 2018

Similar Records

Visible Light Assisted Photocatalytic Hydrogen Generation by Ta₂O₅/Bi₂O₃, TaON/Bi₂O₃, and Ta₃N₅/Bi₂O₃ Composites

Journal Article · Mon Jun 15 00:00:00 EDT 2015 · RSC Advances · OSTI ID:1286959

Adhikari, Shiba; Hood, Zachary D.; More, Karren Leslie; +4 more

Highly efficient visible-light-induced photocatalytic activity of Bi{sub 2}WO{sub 6}/BiVO{sub 4} heterojunction photocatalysts

Journal Article · Sun Jun 01 00:00:00 EDT 2014 · Materials Research Bulletin · OSTI ID:1286959

Chaiwichian, Saranyoo; Inceesungvorn, Burapat; Wetchakun, Khatcharin; +3 more

Novel Y doped Bi{sub 2}WO{sub 6} photocatalyst: Hydrothermal fabrication, characterization and enhanced visible-light-driven photocatalytic activity for Rhodamine B degradation and photocurrent generation

Journal Article · Sun Mar 15 00:00:00 EDT 2015 · Materials Characterization · OSTI ID:1286959

Cao, Ranran; Huang, Hongwei; Tian, Na; +3 more

Related Subjects

36 MATERIALS SCIENCE

Title: Visible-light-driven Bi 2 O 3 /WO 3 composites with enhanced photocatalytic activity

Citation Formats

References (61)

Cited By (1)

Similar Records

Related Subjects

Title: Visible-light-driven Bi ₂ O ₃ /WO ₃ composites with enhanced photocatalytic activity