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Title: High-rate in-plane micro-supercapacitors scribed onto photo paper using in situ femtolaser-reduced graphene oxide/Au nanoparticle microelectrodes

Abstract

Direct laser-reduction of graphene oxide (GO), as a lithography-free approach, has been proven effective in manufacturing in-plane micro-supercapacitors (MSCs) with fast ion diffusion. However, the power density and the charge/discharge rate are still limited by the relatively low conductivity of electrodes. Here, we report a facile approach by exploiting femtolaser in situ reduction of the hydrated GO and chloroauric acid (HAuCl4) nanocomposite simultaneously, which incorporates both the patterning of rGO electrodes and the fabrication of Au current collectors in a single step. These flexible MSCs boast achievements of one-hundred fold increase in electrode conductivities of up to 1.1 × 106 S m–1, which provide superior rate capability (50% for the charging rate increase from 0.1 V s–1 to 100 V s–1), sufficiently high frequency responses (362 Hz, 2.76 ms time constant), and large specific capacitances of 0.77 mF cm–2 (17.2 F cm–3 for volumetric capacitance) at 1 V s–1, and 0.46 mF cm–2 (10.2 F cm–3) at 100 V s–1. The use of photo paper substrates enables the flexibility of this fabrication protocol. Moreover, proof-of-concept 3D MSCs are demonstrated with enhanced areal capacitance (up to 3.84 mF cm–2 at 1 V s–1) while keeping high rate capabilities. As a result,more » this prototype of all solid-state MSCs demonstrates the broad range of potentials of thin-film based energy storage device applications for flexible, portable, and wearable electronic devices that require a fast charge/discharge rate and high power density.« less

Authors:
 [1];  [2];  [2];  [2];  [3];  [4];  [4];  [5];  [6];  [2];  [7]
  1. Univ. of Tennessee, Knoxville, TN (United States); Southeast Univ., Key Lab. of Micro-Inertial Instrument and Advanced Navigation Technology, Ministry of Education, Nanjing (China)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. University of Tennessee, Knoxville (UTK)
  4. Univ. of Tennessee, Knoxville, TN (United States)
  5. Southeast Univ., Key Lab. of Micro-Inertial Instrument and Advanced Navigation Technology, Ministry of Education, Nanjing (China)
  6. Univ. di Catania, Catania (Italy)
  7. Univ. of Tennessee, Knoxville, TN (United States); Beijing Univ. of Technology, Beijing (China)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1286936
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 9; Journal Issue: 4; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Li, Ruozhou, Peng, Rui, Tumuluri, Uma, Wu, Zili, Hu, Anming, Kihm, K. D., Bridges, D., Zhang, T., Compagnini, G., Feng, Z., and Hu, A.. High-rate in-plane micro-supercapacitors scribed onto photo paper using in situ femtolaser-reduced graphene oxide/Au nanoparticle microelectrodes. United States: N. p., 2016. Web. doi:10.1039/C5EE03637B.
Li, Ruozhou, Peng, Rui, Tumuluri, Uma, Wu, Zili, Hu, Anming, Kihm, K. D., Bridges, D., Zhang, T., Compagnini, G., Feng, Z., & Hu, A.. High-rate in-plane micro-supercapacitors scribed onto photo paper using in situ femtolaser-reduced graphene oxide/Au nanoparticle microelectrodes. United States. https://doi.org/10.1039/C5EE03637B
Li, Ruozhou, Peng, Rui, Tumuluri, Uma, Wu, Zili, Hu, Anming, Kihm, K. D., Bridges, D., Zhang, T., Compagnini, G., Feng, Z., and Hu, A.. 2016. "High-rate in-plane micro-supercapacitors scribed onto photo paper using in situ femtolaser-reduced graphene oxide/Au nanoparticle microelectrodes". United States. https://doi.org/10.1039/C5EE03637B. https://www.osti.gov/servlets/purl/1286936.
@article{osti_1286936,
title = {High-rate in-plane micro-supercapacitors scribed onto photo paper using in situ femtolaser-reduced graphene oxide/Au nanoparticle microelectrodes},
author = {Li, Ruozhou and Peng, Rui and Tumuluri, Uma and Wu, Zili and Hu, Anming and Kihm, K. D. and Bridges, D. and Zhang, T. and Compagnini, G. and Feng, Z. and Hu, A.},
abstractNote = {Direct laser-reduction of graphene oxide (GO), as a lithography-free approach, has been proven effective in manufacturing in-plane micro-supercapacitors (MSCs) with fast ion diffusion. However, the power density and the charge/discharge rate are still limited by the relatively low conductivity of electrodes. Here, we report a facile approach by exploiting femtolaser in situ reduction of the hydrated GO and chloroauric acid (HAuCl4) nanocomposite simultaneously, which incorporates both the patterning of rGO electrodes and the fabrication of Au current collectors in a single step. These flexible MSCs boast achievements of one-hundred fold increase in electrode conductivities of up to 1.1 × 106 S m–1, which provide superior rate capability (50% for the charging rate increase from 0.1 V s–1 to 100 V s–1), sufficiently high frequency responses (362 Hz, 2.76 ms time constant), and large specific capacitances of 0.77 mF cm–2 (17.2 F cm–3 for volumetric capacitance) at 1 V s–1, and 0.46 mF cm–2 (10.2 F cm–3) at 100 V s–1. The use of photo paper substrates enables the flexibility of this fabrication protocol. Moreover, proof-of-concept 3D MSCs are demonstrated with enhanced areal capacitance (up to 3.84 mF cm–2 at 1 V s–1) while keeping high rate capabilities. As a result, this prototype of all solid-state MSCs demonstrates the broad range of potentials of thin-film based energy storage device applications for flexible, portable, and wearable electronic devices that require a fast charge/discharge rate and high power density.},
doi = {10.1039/C5EE03637B},
url = {https://www.osti.gov/biblio/1286936}, journal = {Energy & Environmental Science},
issn = {1754-5692},
number = 4,
volume = 9,
place = {United States},
year = {2016},
month = {2}
}

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Works referenced in this record:

Monolithic Carbide-Derived Carbon Films for Micro-Supercapacitors
journal, April 2010


All-Solid-State Flexible Ultrathin Micro-Supercapacitors Based on Graphene
journal, May 2013


Scalable fabrication of high-power graphene micro-supercapacitors for flexible and on-chip energy storage
journal, February 2013


Graphene-based in-plane micro-supercapacitors with high power and energy densities
journal, September 2013


Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon
journal, August 2010


3-Dimensional Graphene Carbon Nanotube Carpet-Based Microsupercapacitors with High Electrochemical Performance
journal, December 2012


Capacitive energy storage in micro-scale devices: recent advances in design and fabrication of micro-supercapacitors
journal, January 2014


Solid-State Supercapacitor Based on Activated Carbon Cloths Exhibits Excellent Rate Capability
journal, February 2014


Direct laser writing of micro-supercapacitors on hydrated graphite oxide films
journal, July 2011


Carbon Materials for Chemical Capacitive Energy Storage
journal, September 2011


Highly Conductive and Porous Activated Reduced Graphene Oxide Films for High-Power Supercapacitors
journal, January 2012


Towards superior volumetric performance: design and preparation of novel carbon materials for energy storage
journal, January 2015


Ultrathin Planar Graphene Supercapacitors
journal, April 2011


Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors
journal, March 2012


Paper Electronics
journal, March 2011


Direct Writing on Paper of Foldable Capacitive Touch Pads with Silver Nanowire Inks
journal, November 2014


Pen-on-Paper Flexible Electronics
journal, June 2011


Sensing approaches on paper-based devices: a review
journal, April 2013


Toward Paper-Based Sensors: Turning Electrical Signals into an Optical Readout System
journal, August 2015


Photoelectrochemical Lab-on-Paper Device Based on an Integrated Paper Supercapacitor and Internal Light Source
journal, March 2013


Paper Microfluidics Goes Digital
journal, January 2014


Organic Electronics on Banknotes
journal, December 2010


Highly Transparent and Flexible Nanopaper Transistors
journal, February 2013


Transparent Nanopaper-Based Flexible Organic Thin-Film Transistor Array
journal, November 2013


4% Efficient Polymer Solar Cells on Paper Substrates
journal, May 2014


Paper Electronics: Direct Monolithic Integration of Organic Photovoltaic Circuits on Unmodified Paper (Adv. Mater. 31/2011)
journal, August 2011


All-Printed Paper Memory
journal, July 2014


Thin, Flexible Secondary Li-Ion Paper Batteries
journal, September 2010


Ultrafast All-Polymer Paper-Based Batteries
journal, October 2009


Printed energy storage devices by integration of electrodes and separators into single sheets of paper
journal, May 2010


Multicolor Polymer Nanocomposites: In Situ Synthesis and Fabrication of 3D Microstructures
journal, March 2008


Two-photon polymerization initiators for three-dimensional optical data storage and microfabrication
journal, March 1999


Two-photon-induced reduction of metal ions for fabricating three-dimensional electrically conductive metallic microstructure
journal, February 2006


Surface-Plasmon-Mediated Programmable Optical Nanofabrication of an Oriented Silver Nanoplate
journal, June 2014


Femtosecond-laser generation of self-organized bubble patterns in fused silica
journal, January 2011


Direct imprinting of microcircuits on graphene oxides film by femtosecond laser reduction
journal, February 2010


Porous Graphene Materials for Advanced Electrochemical Energy Storage and Conversion Devices
journal, December 2013


Finer features for functional microdevices
journal, August 2001


Polypyrrole-coated paper for flexible solid-state energy storage
journal, January 2013


Solvothermal Reduction of Chemically Exfoliated Graphene Sheets
journal, July 2009


Robust Ag nanoplate ink for flexible electronics packaging
journal, January 2015


A Facile and Novel Synthesis of Ag–Graphene-Based Nanocomposites
journal, October 2009


In Situ Synthesis of Metal Nanoparticles on Single-Layer Graphene Oxide and Reduced Graphene Oxide Surfaces
journal, May 2009


Enhancing the conductivity of transparent graphene films via doping
journal, June 2010


Thermal Conversion of Electronic and Electrical Properties of AuCl 3 -Doped Single-Walled Carbon Nanotubes
journal, January 2011


Controlled Electroless Deposition of Noble Metal Nanoparticle Films on Germanium Surfaces
journal, October 2002


Uniform polystyrene microspheres decorated with noble metal nanoparticles formed without using extra reducing agent
journal, September 2007


Layer-by-layer assembly of graphene and gold nanoparticles by vacuum filtration and spontaneous reduction of gold ions
journal, January 2009


Spontaneous Reduction of Metal Ions on the Sidewalls of Carbon Nanotubes
journal, August 2002


Role of Anions in the AuCl 3 -Doping of Carbon Nanotubes
journal, January 2011


Controlling work function of reduced graphite oxide with Au-ion concentration
journal, June 2009


On chip, all solid-state and flexible micro-supercapacitors with high performance based on MnOx/Au multilayers
journal, January 2013


Superior Micro-Supercapacitors Based on Graphene Quantum Dots
journal, March 2013


3D Printing of Interdigitated Li-Ion Microbattery Architectures
journal, June 2013


Building Energy Storage Device on a Single Nanowire
journal, August 2011


Three-dimensional bicontinuous ultrafast-charge and -discharge bulk battery electrodes
journal, March 2011


Microstructuring of Graphene Oxide Nanosheets Using Direct Laser Writing
journal, January 2010


Enhanced Photothermal Effect of Plasmonic Nanoparticles Coated with Reduced Graphene Oxide
journal, August 2013


Works referencing / citing this record:

Design of Architectures and Materials in In-Plane Micro-supercapacitors: Current Status and Future Challenges
journal, November 2016


Laser Fabrication of Graphene‐Based Flexible Electronics
journal, August 2019


Laser-Reduced Graphene: Synthesis, Properties, and Applications
journal, February 2018


Recent Development of Fabricating Flexible Micro-Supercapacitors for Wearable Devices
journal, June 2018


Graphene-Based Planar Microsupercapacitors: Recent Advances and Future Challenges
journal, October 2018


Wearable Textile-Based In-Plane Microsupercapacitors
journal, August 2016


Coordination Polymer Framework Based On-Chip Micro-Supercapacitors with AC Line-Filtering Performance
journal, March 2017


On‐Chip Microsupercapacitors: From Material to Fabrication
journal, September 2019


Flexible Micro-Supercapacitor Based on Graphene with 3D Structure
journal, January 2017


The Research Development of Quantum Dots in Electrochemical Energy Storage
journal, August 2018


Pencil-Drawing Skin-Mountable Micro-Supercapacitors
journal, November 2018


Recent Advances in Design of Flexible Electrodes for Miniaturized Supercapacitors
journal, February 2020


Design and integration of flexible planar micro-supercapacitors
journal, January 2017


Recent progress on printable power supply devices and systems with nanomaterials
journal, May 2018


Environmental impact of the production of graphene oxide and reduced graphene oxide
journal, January 2019


Fully laser-patterned stretchable microsupercapacitors integrated with soft electronic circuit components
journal, October 2018


Two-photon-induced stretchable graphene supercapacitors
journal, August 2018


All-solid state, flexible, high-energy integrated hybrid micro-supercapacitors based on 3D LSG/CoNi 2 S 4 nanosheets
journal, January 2016


Excellent energy–power characteristics from a hybrid sodium ion capacitor based on identical carbon nanosheets in both electrodes
journal, January 2016


Two-dimensional materials for miniaturized energy storage devices: from individual devices to smart integrated systems
journal, January 2018


Challenges and prospects of 3D micro-supercapacitors for powering the internet of things
journal, January 2019


Processing and manufacturing of graphene-based microsupercapacitors
journal, January 2018


Highly conductive and bendable gold networks attached on intertwined cellulose fibers for output controllable power paper
journal, January 2018


A synergistic self-assembled 3D PEDOT:PSS/graphene composite sponge for stretchable microsupercapacitors
journal, January 2020


Graphene quantum dot/Co(OH) 2 electrode on nanoporous Au–Ag alloy for superior hybrid micro-supercapacitors
journal, January 2019


Synthesis and patterning of graphene: Strategies and prospects
journal, June 2019


All-solid-state supercapacitors from natural lignin-based composite film by laser direct writing
journal, August 2019


Direct laser writing of graphene electrodes
journal, January 2020


Laser-Scribed Lossy Microstrip Lines for Radio Frequency Applications
journal, January 2019


Recent Progress of Metal–Air Batteries—A Mini Review
journal, July 2019


Ultrafast Laser Pulses for Structuring Materials at Micro/Nano Scale: From Waveguides to Superhydrophobic Surfaces
journal, January 2017


Miniaturized Energy Storage Devices Based on Two‐Dimensional Materials
journal, March 2020


Laser-scribed reduced graphene oxide as counter electrode for dye-sensitized solar cell
journal, September 2019


One-step selective laser patterning of copper/graphene flexible electrodes
journal, February 2019


Laser-induced electrodes towards low-cost flexible UV ZnO sensors
journal, December 2018


Supercapacitors with alternating current line-filtering performance
journal, February 2020


Facile Fabrication of Flexible In-Plane Graphene Micro-Supercapacitor via Flash Reduction
journal, April 2018