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Title: Impeding 99Tc(IV) mobility in novel waste forms

Abstract

Technetium ( 99Tc) is a long-lived radioactive fission product whose mobility in the subsurface is largely governed by its oxidation state1. Immobilization of Tc in mineral substrates is crucial for radioactive waste management and environmental remediation. Tc(IV) incorporation in spinels2, 3 has been proposed as a novel method to increase Tc retention in glass waste forms. However, experiments with Tc-magnetite under high temperature and oxic conditions showed re-oxidation of Tc(IV) to volatile pertechnetate Tc(VII)O4-.4, 5 Here we address this problem with large-scale ab initio molecular dynamics simulations and propose that elevated temperatures, 1st row transition metal dopants can significantly enhance Tc retention in the order Co > Zn > Ni. Experiments with doped spinels at T=700 ºC provided quantitative confirmation of increased Tc retention in the same order predicted by theory. This work highlights the power of modern state-of-the-art simulations to provide essential insights and generate bottom-up design criteria of complex oxide materials at elevated temperatures.

Authors:
 [1];  [2];  [3];  [4];  [5];  [1];  [1]
  1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Fundamental and Computational Sciences Directorate
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environment Directorate; Pohang Univ. of Science and Technology (POSTECH) (South Korea)
  3. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Energy and Environment Directorate
  4. United States Dept. of Energy, Richland, WA (United States). Office of River Protection
  5. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23)
OSTI Identifier:
1282477
Alternate Identifier(s):
OSTI ID: 1436595
Report Number(s):
PNNL-SA-114552
Journal ID: ISSN 2041-1723; 830403000
Grant/Contract Number:  
AC05-76RL01830; AC02-05CH11231; AC02-76SF00515
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES

Citation Formats

Lee, Mal-Soon, Um, Wooyong, Wang, Guohui, Kruger, Albert A., Lukens, Wayne W., Rousseau, Roger, and Glezakou, Vassiliki-Alexandra. Impeding 99Tc(IV) mobility in novel waste forms. United States: N. p., 2016. Web. doi:10.1038/ncomms12067.
Lee, Mal-Soon, Um, Wooyong, Wang, Guohui, Kruger, Albert A., Lukens, Wayne W., Rousseau, Roger, & Glezakou, Vassiliki-Alexandra. Impeding 99Tc(IV) mobility in novel waste forms. United States. doi:10.1038/ncomms12067.
Lee, Mal-Soon, Um, Wooyong, Wang, Guohui, Kruger, Albert A., Lukens, Wayne W., Rousseau, Roger, and Glezakou, Vassiliki-Alexandra. Thu . "Impeding 99Tc(IV) mobility in novel waste forms". United States. doi:10.1038/ncomms12067. https://www.osti.gov/servlets/purl/1282477.
@article{osti_1282477,
title = {Impeding 99Tc(IV) mobility in novel waste forms},
author = {Lee, Mal-Soon and Um, Wooyong and Wang, Guohui and Kruger, Albert A. and Lukens, Wayne W. and Rousseau, Roger and Glezakou, Vassiliki-Alexandra},
abstractNote = {Technetium (99Tc) is a long-lived radioactive fission product whose mobility in the subsurface is largely governed by its oxidation state1. Immobilization of Tc in mineral substrates is crucial for radioactive waste management and environmental remediation. Tc(IV) incorporation in spinels2, 3 has been proposed as a novel method to increase Tc retention in glass waste forms. However, experiments with Tc-magnetite under high temperature and oxic conditions showed re-oxidation of Tc(IV) to volatile pertechnetate Tc(VII)O4-.4, 5 Here we address this problem with large-scale ab initio molecular dynamics simulations and propose that elevated temperatures, 1st row transition metal dopants can significantly enhance Tc retention in the order Co > Zn > Ni. Experiments with doped spinels at T=700 ºC provided quantitative confirmation of increased Tc retention in the same order predicted by theory. This work highlights the power of modern state-of-the-art simulations to provide essential insights and generate bottom-up design criteria of complex oxide materials at elevated temperatures.},
doi = {10.1038/ncomms12067},
journal = {Nature Communications},
number = ,
volume = 7,
place = {United States},
year = {Thu Jun 30 00:00:00 EDT 2016},
month = {Thu Jun 30 00:00:00 EDT 2016}
}

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Works referenced in this record:

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865