skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Synthesis of sodium polyhydrides at high pressures

Journal Article · · Nature Communications
DOI:https://doi.org/10.1038/ncomms12267· OSTI ID:1282373

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research in Extreme Environments (EFree); Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - BASIC ENERGY SCIENCESDOE - OTHERFOREIGN
OSTI ID:
1282373
Journal Information:
Nature Communications, Vol. 7, Issue 2016; ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
ENGLISH

References (56)

Generalized Gradient Approximation Made Simple journal October 1996
High-pressure synthesis of noble metal hydrides text January 2013
Metallic Hydrogen: A High-Temperature Superconductor? journal December 1968
High-pressure synthesis of lithium hydride journal August 2012
A superconductor to superfluid phase transition in liquid metallic hydrogen journal October 2004
Compressed Cesium Polyhydrides: Cs + Sublattices and H 3 Three-Connected Nets journal August 2012
Dihydrogen complexes as prototypes for the coordination chemistry of saturated molecules journal April 2007
High capacity hydrogenstorage materials: attributes for automotive applications and techniques for materials discovery journal January 2010
Composition and Constitution of Compressed Strontium Polyhydrides journal March 2014
Transition Metal Polyhydrides:  From Qualitative Ideas to Reliable Computational Studies journal February 2000
Strong electronic correlation in the Hydrogen chain: a variational Monte Carlo study text January 2011
Observations of H3− and D3− from dielectric barrier discharge plasmas journal August 2003
Superconductive "sodalite"-like clathrate calcium hydride at high pressures text January 2012
Ab initio random structure searching journal January 2011
Ground-State Structures of Atomic Metallic Hydrogen journal April 2011
Dihydrogen Complexes as Prototypes for the Coordination Chemistry of Saturated Molecules journal September 2007
Polyhydrides of the Alkaline Earth Metals: A Look at the Extremes under Pressure journal February 2013
Large-Scale Semidefinite Programming for Many-Electron Quantum Mechanics journal February 2011
Strong electronic correlation in the hydrogen chain: A variational Monte Carlo study journal December 2011
The Chemical Imagination at Work in Very Tight Places journal July 2007
Hydrogen Dominant Metallic Alloys: High Temperature Superconductors? journal May 2004
High-pressure studies of NaH to 54 GPa journal November 1987
Superconductive sodalite-like clathrate calcium hydride at high pressures journal April 2012
The Chemical Imagination at Work inVery Tight Places journal May 2007
Bonding in the trihalides (X3−), mixed trihalides (X2Y−) and hydrogen bihalides (X2H−). The connection between hypervalent, electron-rich three-center, donor–acceptor and strong hydrogen bonding ‡ journal January 1997
Rubidium Polyhydrides Under Pressure: Emergence of the Linear H3- Anion text January 2012
Potential energy and dipole moment surfaces of H3- molecule text January 2010
Unconventional Hydrogen Bonds: Intermolecular B-H.cntdot..cntdot..cntdot.H-N Interactions journal December 1995
Pressure-Stabilized Sodium Polyhydrides: NaH n ( n > 1 ) journal June 2011
Metallization of magnesium polyhydrides under pressure journal February 2013
Potential energy and dipole moment surfaces of H3− molecule journal May 2010
Rubidium Polyhydrides Under Pressure: Emergence of the Linear H 3 Species journal March 2012
Self-Consistent Equations Including Exchange and Correlation Effects journal November 1965
High-pressure synthesis of noble metal hydrides journal April 2013
Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand journal January 1984
Ab initio Random Structure Searching text January 2011
Predicted Formation of Superconducting Platinum-Hydride Crystals under Pressure in the Presence of Molecular Hydrogen journal September 2011
Phonons and related crystal properties from density-functional perturbation theory journal July 2001
High-pressure phases of silane text January 2006
High Pressure Potassium Polyhydrides: A Chemical Perspective journal June 2012
X ray diffraction with a double hot-plate laser-heated diamond cell book January 1998
Special points for Brillouin-zone integrations journal June 1976
Advanced flat top laser heating system for high pressure research at GSECARS: application to the melting behavior of germanium journal September 2008
A little bit of lithium does a lot for hydrogen journal October 2009
A superconductor to superfluid phase transition in liquid metallic hydrogen text January 2004
Inhomogeneous Electron Gas journal November 1964
Atoms, molecules, solids, and surfaces: Applications of the generalized gradient approximation for exchange and correlation journal September 1992
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism journal April 1990
Ab initio study revealing a layered structure in hydrogen-rich KH 6 under high pressure journal July 2012
Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system journal August 2015
The Electronic Structure of journal April 1935
High-Pressure Phases of Silane journal July 2006
Superconductivity of lithium-doped hydrogen under high pressure journal January 2014
Synthesis of lithium polyhydrides above 130 GPa at 300 K journal June 2015
Ultrahigh-pressure transitions in solid hydrogen journal April 1994
First principles methods using CASTEP journal January 2005

Cited By (18)

Multiple states and roles of hydrogen in p-type SnS semiconductors journal January 2018
Synthesis and Stability of Lanthanum Superhydrides journal December 2017
Polyhydride CeH9 with an atomic-like hydrogen clathrate structure journal August 2019
Superconducting praseodymium superhydrides journal February 2020
Phase diagrams and electronic properties of B-S and H-B-S systems under high pressure journal October 2019
Potential high- T c superconducting lanthanum and yttrium hydrides at high pressure journal June 2017
Superconducting TaH 5 at high pressure journal December 2019
Polyhydride CeH9 with an atomic-like hydrogen clathrate structure. text January 2019
Divergent synthesis routes and superconductivity of ternary hydride MgSiH 6 at high pressure journal October 2017
Superconductivity of light‐metal hydrides journal March 2019
Synthesis of clathrate cerium superhydride CeH9 at 80-100 GPa with atomic hydrogen sublattice journal October 2019
Hydrogen-rich superconductors at high pressures: Hydrogen-rich superconductors journal September 2017
High-Pressure Synthesis of Barium Superhydrides: Pseudocubic BaH12 text January 2020
Synthesis and Stability of Lanthanum Superhydrides journal December 2017
Helium-hydrogen immiscibility at high pressures journal March 2019
High-temperature superconductivity in alkaline and rare earth polyhydrides at high pressure: A theoretical perspective journal February 2019
Unexpected calcium polyhydride CaH 4 : A possible route to dissociation of hydrogen molecules journal January 2019
Synthesis of FeH 5 : A layered structure with atomic hydrogen slabs journal July 2017

Similar Records

Synthesis of sodium polyhydrides at high pressures
Journal Article · Thu Jul 28 00:00:00 EDT 2016 · Nature Communications · OSTI ID:1282373

Uranium polyhydrides at moderate pressures: Prediction, synthesis, and expected superconductivity
Journal Article · Fri Oct 12 00:00:00 EDT 2018 · Science Advances · OSTI ID:1282373

High-temperature superconductivity in alkaline and rare earth polyhydrides at high pressure: A theoretical perspective
Journal Article · Fri Feb 01 00:00:00 EST 2019 · Journal of Chemical Physics · OSTI ID:1282373

Related Subjects