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Title: Chemical vapour deposition: Transition metal carbides go 2D

Journal Article · · Nature Materials
DOI:https://doi.org/10.1038/nmat4386· OSTI ID:1265654
 [1]
  1. Drexel Univ., Philadelphia, PA (United States)

Here, the research community has been steadily expanding the family of few-atom-thick crystals beyond graphene, discovering new materials or producing known materials in a 2D state and demonstrating their unique properties1, 2. Recently, nanometre-thin 2D transition metal carbides have also joined this family3. Writing in Nature Materials, Chuan Xu and colleagues now report a significant advance in the field, showing the synthesis of large-area, high-quality, nanometre-thin crystals of molybdenum carbide that demonstrate low-temperature 2D superconductivity4. Moreover, they also show that other ultrathin carbide crystals, such as tungsten and tantalum carbides, can be grown by chemical vapour deposition with a high crystallinity and very low defect concentration.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1265654
Journal Information:
Nature Materials, Vol. 14, Issue 11; ISSN 1476-1122
Publisher:
Springer Nature - Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 207 works
Citation information provided by
Web of Science

References (11)

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The rise of graphene book August 2009
Two Dimensional Atomic Crystals text January 2005

Cited By (40)

MXene‐Enabled Electrochemical Microfluidic Biosensor: Applications toward Multicomponent Continuous Monitoring in Whole Blood journal November 2018
Synthesis of Two-Dimensional Materials for Capacitive Energy Storage journal June 2016
Tri- s -triazine-Based Crystalline Carbon Nitride Nanosheets for an Improved Hydrogen Evolution journal April 2017
Two-Dimensional Metal Oxide Nanomaterials for Next-Generation Rechargeable Batteries journal April 2017
Clay-Inspired MXene-Based Electrochemical Devices and Photo-Electrocatalyst: State-of-the-Art Progresses and Challenges journal January 2018
Structural Design and Electronic Modulation of Transition-Metal-Carbide Electrocatalysts toward Efficient Hydrogen Evolution journal August 2018
Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes) journal November 2018
Self‐Assembly of Large‐Area 2D Polycrystalline Transition Metal Carbides for Hydrogen Electrocatalysis journal August 2018
MXene‐Based Composites: Synthesis and Applications in Rechargeable Batteries and Supercapacitors journal February 2019
Transition Metal Carbides and Nitrides in Energy Storage and Conversion journal February 2016
MXene-Silicon Van Der Waals Heterostructures for High-Speed Self-Driven Photodetectors journal July 2017
Ti 3 C 2 T x (MXene)‐Silicon Heterojunction for Efficient Photovoltaic Cells journal July 2019
2 D MXene‐based Energy Storage Materials: Interfacial Structure Design and Functionalization journal March 2020
Recent Progress of MXene-Based Nanomaterials in Flexible Energy Storage and Electronic Devices journal December 2018
Two‐Dimensional Transition Metal Carbides and Nitrides (MXenes): Synthesis, Properties, and Electrochemical Energy Storage Applications journal March 2020
Two‐dimensional MXenes for lithium‐sulfur batteries journal January 2020
Broadband Nonlinear Photonics in Few-Layer MXene Ti 3 C 2 T x (T = F, O, or OH) journal November 2017
2D metal carbides and nitrides (MXenes) for energy storage journal January 2017
Hierarchical porous carbons with layer-by-layer motif architectures from confined soft-template self-assembly in layered materials journal June 2017
Laser-sculptured ultrathin transition metal carbide layers for energy storage and energy harvesting applications journal July 2019
Asymmetric MXene/monolayer transition metal dichalcogenide heterostructures for functional applications journal February 2019
Inkjet-printed MXene micro-scale devices for integrated broadband ultrafast photonics journal September 2019
One-step Solution Processing of Ag, Au and Pd@MXene Hybrids for SERS journal August 2016
Theoretical exploration of the potential applications of Sc-based MXenes journal January 2017
Recent advances in ternary two-dimensional materials: synthesis, properties and applications journal January 2017
Atomic layer deposition of nickel carbide for supercapacitors and electrocatalytic hydrogen evolution journal January 2018
Thickness biased capture of CO 2 on carbide MXenes journal January 2019
In situ synthesis of BiOCl nanosheets on three-dimensional hierarchical structures for efficient photocatalysis under visible light journal January 2019
Multifunctional two-dimensional nanocomposites for photothermal-based combined cancer therapy journal January 2019
Germanane synthesis with simultaneous covalent functionalization: towards highly functionalized fluorescent germananes journal January 2019
Modulation engineering of 2D MXene-based compounds for metal-ion batteries journal January 2019
Effect of vacancies on the structural and electronic properties of Ti 2 CO 2 journal January 2019
Ionic sieving through Ti 3 C 2 (OH) 2 MXene: First-principles calculations journal March 2016
Novel elastic, lattice dynamics and thermodynamic properties of metallic single-layer transition metal phosphides: 2H- M 2 P (Mo 2 P, W 2 P, Nb 2 P and Ta 2 P) journal March 2018
Mo 2 C/graphene heterostructures: low temperature chemical vapor deposition on liquid bimetallic Sn–Cu and hydrogen evolution reaction electrocatalytic properties journal January 2019
Strategies for improving the lithium-storage performance of 2D nanomaterials journal July 2017
Overview of Rational Design of Binary Alloy for the Synthesis of Two-Dimensional Materials journal January 2020
Laser-sculptured ultrathin transition metal carbide layers for energy storage and energy harvesting applications text January 2019
Transition Metal Carbides and Nitrides in Energy Storage and Conversion journal February 2017
Degradable and Dissolvable Thin-Film Materials for the Applications of New-Generation Environmental-Friendly Electronic Devices journal February 2020

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