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Title: Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding

Abstract

In this study, polyoxometalates (POMs) covalently functionalized with methyl methacrylate groups were applied as surfactants in the emulsion polymerization reaction of styrene. Due to the copolymerization of the methyl methacrylate groups and the styrene monomers, the polyoxometalate clusters are covalently grafted onto the surface of polystyrene latex nanoparticles. Finally, such latex particles are fully covered with catalytic POM clusters and might serve as quasi-homogeneous catalysts.

Authors:
 [1];  [1];  [2];  [1]
  1. Univ. of Akron, OH (United States). Dept. of Polymer Science
  2. Univ. of Akron, OH (United States). Dept. of Polymer Science; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division. Neutron Science Directorate
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1265540
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 51; Journal Issue: 28; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Chen, Xinyue, Li, Hui, Yin, Panchao, and Liu, Tianbo. Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding. United States: N. p., 2015. Web. doi:10.1039/C5CC00239G.
Chen, Xinyue, Li, Hui, Yin, Panchao, & Liu, Tianbo. Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding. United States. doi:10.1039/C5CC00239G.
Chen, Xinyue, Li, Hui, Yin, Panchao, and Liu, Tianbo. Fri . "Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding". United States. doi:10.1039/C5CC00239G. https://www.osti.gov/servlets/purl/1265540.
@article{osti_1265540,
title = {Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding},
author = {Chen, Xinyue and Li, Hui and Yin, Panchao and Liu, Tianbo},
abstractNote = {In this study, polyoxometalates (POMs) covalently functionalized with methyl methacrylate groups were applied as surfactants in the emulsion polymerization reaction of styrene. Due to the copolymerization of the methyl methacrylate groups and the styrene monomers, the polyoxometalate clusters are covalently grafted onto the surface of polystyrene latex nanoparticles. Finally, such latex particles are fully covered with catalytic POM clusters and might serve as quasi-homogeneous catalysts.},
doi = {10.1039/C5CC00239G},
journal = {ChemComm},
number = 28,
volume = 51,
place = {United States},
year = {Fri Feb 27 00:00:00 EST 2015},
month = {Fri Feb 27 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 4 works
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Works referenced in this record:

A Fast Soluble Carbon-Free Molecular Water Oxidation Catalyst Based on Abundant Metals
journal, March 2010