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Title: Advancing polymers of intrinsic microporosity by mechanochemistry

Abstract

Herein, we report a fast (15 min) and solvent-free mechanochemical approach to construct polymers of intrinsic microporosity (PIMs) with high molecular mass and low polydispersity by solid grinding. The enhanced reaction efficiency results from the instantaneous frictional heating and continuous exposure of active sites within those solid reactants.

Authors:
 [1];  [2];  [1];  [3]
  1. Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States)
  3. Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1265468
Grant/Contract Number:
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 3; Journal Issue: 13; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Zhang, Pengfei, Jiang, Xueguang, Wan, Shun, and Dai, Sheng. Advancing polymers of intrinsic microporosity by mechanochemistry. United States: N. p., 2015. Web. doi:10.1039/C4TA07196D.
Zhang, Pengfei, Jiang, Xueguang, Wan, Shun, & Dai, Sheng. Advancing polymers of intrinsic microporosity by mechanochemistry. United States. doi:10.1039/C4TA07196D.
Zhang, Pengfei, Jiang, Xueguang, Wan, Shun, and Dai, Sheng. Fri . "Advancing polymers of intrinsic microporosity by mechanochemistry". United States. doi:10.1039/C4TA07196D. https://www.osti.gov/servlets/purl/1265468.
@article{osti_1265468,
title = {Advancing polymers of intrinsic microporosity by mechanochemistry},
author = {Zhang, Pengfei and Jiang, Xueguang and Wan, Shun and Dai, Sheng},
abstractNote = {Herein, we report a fast (15 min) and solvent-free mechanochemical approach to construct polymers of intrinsic microporosity (PIMs) with high molecular mass and low polydispersity by solid grinding. The enhanced reaction efficiency results from the instantaneous frictional heating and continuous exposure of active sites within those solid reactants.},
doi = {10.1039/C4TA07196D},
journal = {Journal of Materials Chemistry. A},
number = 13,
volume = 3,
place = {United States},
year = {Fri Feb 20 00:00:00 EST 2015},
month = {Fri Feb 20 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

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Cited by: 10 works
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