Quantum effects in the dynamics of deeply supercooled water

Agapov, Alexander L.; Kolesnikov, Alexander I.; Novikov, Vladimir N.; Richert, Ranko; Sokolov, Alexei P

doi:10.1103/PhysRevE.91.022312

Title: Quantum effects in the dynamics of deeply supercooled water

Journal Article · Thu Feb 26 00:00:00 EST 2015 · Physical Review E

DOI:https://doi.org/10.1103/PhysRevE.91.022312· OSTI ID:1265363

Agapov, Alexander L. ^[1]; Kolesnikov, Alexander I. ^[2]; Novikov, Vladimir N. ^[1]; Richert, Ranko ^[3]; Sokolov, Alexei P ^[1]

Univ. of Tennessee, Knoxville, TN (United States). Department of Chemistry and Joint Institute for Neutron Sciences; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division
Arizona State Univ., Tempe, AZ (United States). Dept. of Chemistry and Biochemistry

In spite of its simple chemical structure, water remains one of the most puzzling liquids with many anomalies at low temperatures. Combining neutron scattering and dielectric relaxation spectroscopy, we show that quantum fluctuations are not negligible in deeply supercooled water. Our dielectric measurements reveal the anomalously weak temperature dependence of structural relaxation in vapor-deposited water close to the glass transition temperature T_g~136K. We demonstrate that this anomalous behavior can be explained well by quantum effects. In conclusion, these results have significant implications for our understanding of water dynamics.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1265363

Alternate ID(s):: OSTI ID: 1180248

Journal Information:: Physical Review E, Vol. 91, Issue 2; ISSN 2470-0045

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 19 works

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