skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Enhanced thermoelectric performance driven by high-temperature phase transition in the phase change material Ge 4SbTe 5

Abstract

Phase change materials are identified for their ability to rapidly alternate between amorphous and crystalline phases and have large contrast in the optical/electrical properties of the respective phases. The materials are primarily used in memory storage applications, but recently they have also been identified as potential thermoelectric materials. Many of the phase change materials researched today can be found on the pseudo-binary (GeTe) 1-x(Sb 2Te 3) x tie-line. While many compounds on this tie-line have been recognized as thermoelectric materials, here we focus on Ge 4SbTe 5, a single phase compound just off of the (GeTe) 1-x(Sb 2Te 3) x tie-line, that forms in a stable rocksalt crystal structure at room temperature. We find that stoichiometric and undoped Ge 4SbTe 5 exhibits a thermal conductivity of ~1.2 W/m-K at high temperature and a large Seebeck coefficient of ~250 μV/K. The resistivity decreases dramatically at 623 K due to a structural phase transition which lends to a large enhancement in both thermoelectric power factor and thermoelectric figure of merit at 823 K. In a more general sense the research presents evidence that phase change materials can potentially provide a new route to highly efficient thermoelectric materials for power generation at highmore » temperature.« less

Authors:
 [1];  [2];  [2];  [2];  [1]
  1. Michigan State Univ., East Lansing, MI (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1265317
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Materials Research
Additional Journal Information:
Journal Volume: 30; Journal Issue: 17; Journal ID: ISSN 0884-2914
Publisher:
Materials Research Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; thermoelectric; phase transformation; semiconducting

Citation Formats

Williams, Jared B., Lara-Curzio, Edgar, Cakmak, Ercan, Watkins, Thomas R., and Morelli, Donald T.. Enhanced thermoelectric performance driven by high-temperature phase transition in the phase change material Ge4SbTe5. United States: N. p., 2015. Web. doi:10.1557/jmr.2015.124.
Williams, Jared B., Lara-Curzio, Edgar, Cakmak, Ercan, Watkins, Thomas R., & Morelli, Donald T.. Enhanced thermoelectric performance driven by high-temperature phase transition in the phase change material Ge4SbTe5. United States. doi:10.1557/jmr.2015.124.
Williams, Jared B., Lara-Curzio, Edgar, Cakmak, Ercan, Watkins, Thomas R., and Morelli, Donald T.. Fri . "Enhanced thermoelectric performance driven by high-temperature phase transition in the phase change material Ge4SbTe5". United States. doi:10.1557/jmr.2015.124. https://www.osti.gov/servlets/purl/1265317.
@article{osti_1265317,
title = {Enhanced thermoelectric performance driven by high-temperature phase transition in the phase change material Ge4SbTe5},
author = {Williams, Jared B. and Lara-Curzio, Edgar and Cakmak, Ercan and Watkins, Thomas R. and Morelli, Donald T.},
abstractNote = {Phase change materials are identified for their ability to rapidly alternate between amorphous and crystalline phases and have large contrast in the optical/electrical properties of the respective phases. The materials are primarily used in memory storage applications, but recently they have also been identified as potential thermoelectric materials. Many of the phase change materials researched today can be found on the pseudo-binary (GeTe)1-x(Sb2Te3)x tie-line. While many compounds on this tie-line have been recognized as thermoelectric materials, here we focus on Ge4SbTe5, a single phase compound just off of the (GeTe)1-x(Sb2Te3)x tie-line, that forms in a stable rocksalt crystal structure at room temperature. We find that stoichiometric and undoped Ge4SbTe5 exhibits a thermal conductivity of ~1.2 W/m-K at high temperature and a large Seebeck coefficient of ~250 μV/K. The resistivity decreases dramatically at 623 K due to a structural phase transition which lends to a large enhancement in both thermoelectric power factor and thermoelectric figure of merit at 823 K. In a more general sense the research presents evidence that phase change materials can potentially provide a new route to highly efficient thermoelectric materials for power generation at high temperature.},
doi = {10.1557/jmr.2015.124},
journal = {Journal of Materials Research},
issn = {0884-2914},
number = 17,
volume = 30,
place = {United States},
year = {2015},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share: