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Title: Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2

Abstract

Flowing supercritical CO.sub.2 is used to activate metal organic framework materials (MOF). MOFs are activated directly from N,N-dimethylformamide (DMF) thus avoiding exchange with a volatile solvent. Most MCPs display increased surface areas directly after treatment although those with coordinatively unsaturated metal centers benefit from additional heating.

Inventors:
; ;
Publication Date:
Research Org.:
The Regents Of The University Of Michigan, Ann Arbor, MI (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1264476
Patent Number(s):
9,393,548
Application Number:
14/139,184
Assignee:
The Regents Of The University Of Michigan (Ann Arbor, MI) DOESC
DOE Contract Number:
SC0004888
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Dec 23
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Matzger, Adam J., Liu, Baojian, and Wong-Foy, Antek G. Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2. United States: N. p., 2016. Web.
Matzger, Adam J., Liu, Baojian, & Wong-Foy, Antek G. Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2. United States.
Matzger, Adam J., Liu, Baojian, and Wong-Foy, Antek G. Tue . "Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2". United States. doi:. https://www.osti.gov/servlets/purl/1264476.
@article{osti_1264476,
title = {Rapid and enhanced activation of microporous coordination polymers by flowing supercritical CO.sub.2},
author = {Matzger, Adam J. and Liu, Baojian and Wong-Foy, Antek G.},
abstractNote = {Flowing supercritical CO.sub.2 is used to activate metal organic framework materials (MOF). MOFs are activated directly from N,N-dimethylformamide (DMF) thus avoiding exchange with a volatile solvent. Most MCPs display increased surface areas directly after treatment although those with coordinatively unsaturated metal centers benefit from additional heating.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 19 00:00:00 EDT 2016},
month = {Tue Jul 19 00:00:00 EDT 2016}
}

Patent:

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