Synthesis, selected coordination chemistry and extraction behavior of a (phosphinoylmethyl)pyridyl N-oxide-functionalized ligand based upon a 1,4-diazepane platform

Ouizem, Sabrina; Rosario Amorin, Daniel; Dickie, Diane A.; Cramer, Roger E.; Campana, Charles F.; Hay, Benjamin P.; Podair, Julien; Delmau, Laetitia H.; Paine, Robert T.

doi:10.1016/j.poly.2015.05.006

Title: Synthesis, selected coordination chemistry and extraction behavior of a (phosphinoylmethyl)pyridyl N-oxide-functionalized ligand based upon a 1,4-diazepane platform

Journal Article · Sat May 09 00:00:00 EDT 2015 · Polyhedron

DOI:https://doi.org/10.1016/j.poly.2015.05.006· OSTI ID:1261469

Ouizem, Sabrina ^[1]; Rosario Amorin, Daniel ^[1]; Dickie, Diane A. ^[1]; Cramer, Roger E. ^[2]; Campana, Charles F. ^[3]; Hay, Benjamin P. ^[4]; Podair, Julien ^[5]; Delmau, Laetitia H. ^[5]; Paine, Robert T. ^[1]

Univ. of New Mexico, Albuquerque, NM (United States)
Univ. of Hawaii, Honolulu, HI (United States)
Bruker AXS Inc., Madison, WI (United States)
Supramolecular Design Inst., Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

For syntheses of new multidentate chelating ligands ((6,6'4(1,4-diazepane-1,4-diyl)bis(methylene))bis(pyridine-6,2-diyl))bis(methylene))bis(diphenylphosphine oxide) (2) and 6,6'-((1,4-diazepane1,4-diyl)bis(methylene))bis(2-((diphenylphosphoryl)methyl)pyridine 1-oxide) (3), based upon a 1,4-diazepane platform functionalized with 2-(diphenylphosphinoylmethyl)pyridine P-oxide and 2-(diphenylphosphinoylmethyl)pyridine NP-dioxide fragments, respectively, the results are reported. Our results from studies of the coordination chemistry of the ligands with selected lanthanide nitrates and Cu(BF₄)(2) are outlined, and crystal structures for two complexes, [Cu(2)](BF₄)₂ and [Cu(3)](BF₄)₂, are described along with survey Eu(III) and Am(III) solvent extraction analysis, for 3.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; FG02-03ER15419; CHE-0443580

OSTI ID:: 1261469

Alternate ID(s):: OSTI ID: 1249607

Journal Information:: Polyhedron, Vol. 97, Issue C; ISSN 0277-5387

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 3 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Diazepane
Pyridyl
Phosphine oxide
Coordination chemistry
X-ray crystal structures
MM3 FORCE-FIELD
MOLECULAR-MECHANICS
CRYSTAL-STRUCTURE
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CCDC 1045031: Experimental Crystal Structure Determination: (2,2'-((1,4-Diazepane-1,4-diyl)bis(methylene))bis(6-((diphenylphosphoryl)methyl)-1λ5-pyridin-1-olato))-copper(ii) bis(tetrafluoroborate) diethyl ether solvate Ouizem, Sabrina; Amorin, Daniel Rosario; Dickie, Diane A. https://doi.org/10.5517/cc142fpb The current record is supplemented by this dataset	dataset	January 2015
CCDC 1045029: Experimental Crystal Structure Determination: TULWII : 2-(Chloromethyl)-6-((diphenylphosphoryl)methyl)pyridine Ouizem, Sabrina; Amorin, Daniel Rosario; Dickie, Diane A. https://doi.org/10.5517/cc142fm8 The current record is supplemented by this dataset	dataset	January 2015
CCDC 1045030: Experimental Crystal Structure Determination: TULWOO : (1-((6-((Diphenylphosphoryl)methyl)pyridin-2-yl)methyl)-4-((6-((diphenylphosphoryl)methyl)pyridin-2-yl)methyl)-1,4-diazepane)-copper(ii) bis(tetrafluoroborate) Ouizem, Sabrina; Amorin, Daniel Rosario; Dickie, Diane A. https://doi.org/10.5517/cc142fn9 The current record is supplemented by this dataset	dataset	January 2015