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Title: The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe 3P 5SiO 19

Abstract

We report the synthesis, structure, and electrochemistry of the first Na +-ion cathode with two distinct types of polyanions: Fe 3P 5SiO 19. The Fe-based cathode has a reversible capacity of ca. 70 mAh g -1; ca. 1.7 Na + ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na +/Na.

Authors:
 [1];  [2];  [1]
  1. Univ. of Texas at Austin, Austin, TX (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
Sponsoring Org.:
USDOE: NSF
OSTI Identifier:
1261442
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 51; Journal Issue: 52; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Kan, W. H., Huq, A., and Manthiram, A. The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. United States: N. p., 2015. Web. doi:10.1039/C5CC03070F.
Kan, W. H., Huq, A., & Manthiram, A. The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. United States. doi:10.1039/C5CC03070F.
Kan, W. H., Huq, A., and Manthiram, A. Fri . "The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19". United States. doi:10.1039/C5CC03070F. https://www.osti.gov/servlets/purl/1261442.
@article{osti_1261442,
title = {The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19},
author = {Kan, W. H. and Huq, A. and Manthiram, A.},
abstractNote = {We report the synthesis, structure, and electrochemistry of the first Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. The Fe-based cathode has a reversible capacity of ca. 70 mAh g-1; ca. 1.7 Na+ ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na+/Na.},
doi = {10.1039/C5CC03070F},
journal = {ChemComm},
number = 52,
volume = 51,
place = {United States},
year = {Fri May 15 00:00:00 EDT 2015},
month = {Fri May 15 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 4 works
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Works referenced in this record:

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997

  • Padhi, A. K.
  • Journal of The Electrochemical Society, Vol. 144, Issue 4, p. 1188-1194
  • DOI: 10.1149/1.1837571