Strongly correlated perovskite fuel cells

Zhou, You; Guan, Xiaofei; Zhou, Hua; Ramadoss, Koushik; Adam, Suhare; Liu, Huajun; Lee, Sungsik; Shi, Jian; Tsuchiya, Masaru; Fong, Dillon D.; Ramanathan, Shriram

doi:10.1038/nature17653

Title: Strongly correlated perovskite fuel cells

Journal Article · Mon May 16 00:00:00 EDT 2016 · Nature (London)

DOI:https://doi.org/10.1038/nature17653· OSTI ID:1261104

Zhou, You ^[1]; Guan, Xiaofei ^[1]; Zhou, Hua ^[2]; Ramadoss, Koushik ^[1]; Adam, Suhare ^[1]; Liu, Huajun ^[3]; Lee, Sungsik ^[2]; Shi, Jian ^[4]; Tsuchiya, Masaru ^[5]; Fong, Dillon D. ^[3]; Ramanathan, Shriram ^[6]

Harvard Univ., Cambridge, MA (United States). John A. Paulson School of Engineering and Applied Sciences
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division
Harvard Univ., Cambridge, MA (United States). John A. Paulson School of Engineering and Applied Sciences; Rensselaer Polytechnic Inst., Troy, NY (United States). Dept. of Materials Science and Engineering
SiEnergy Systems, Cambridge, MA (United States)
Harvard Univ., Cambridge, MA (United States). John A. Paulson School of Engineering and Applied Sciences; Purdue Univ., West Lafayette, IN (United States). School of Materials Engineering

Fuel cells convert chemical energy directly into electrical energy with high efficiencies and environmental benefits, as compared with traditional heat engines. Yttria-stabilized zirconia is perhaps the material with the most potential as an electrolyte in solid oxide fuel cells (SOFCs), owing to its stability and near-unity ionic transference number. Although there exist materials with superior ionic conductivity, they are often limited by their ability to suppress electronic leakage when exposed to the reducing environment at the fuel interface. Such electronic leakage reduces fuel cell power output and the associated chemo-mechanical stresses can also lead to catastrophic fracture of electrolyte membranes. Here we depart from traditional electrolyte design that relies on cation substitution to sustain ionic conduction. Instead, we use a perovskite nickelate as an electrolyte with high initial ionic and electronic conductivity. Since many such oxides are also correlated electron systems, we can suppress the electronic conduction through a filling-controlled Mott transition induced by spontaneous hydrogen incorporation. Using such a nickelate as the electrolyte in free-standing membrane geometry, we demonstrate a low-temperature micro-fabricated SOFC with high performance. The ionic conductivity of the nickelate perovskite is comparable to the best-performing solid electrolytes in the same temperature range, with a very low activation energy. The results present a design strategy for high-performance materials exhibiting emergent properties arising from strong electron correlations.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences and Engineering Division; US Army Research Office (ARO); US Air Force Office of Scientific Research (AFOSR)

Grant/Contract Number:: AC02-06CH11357; W911NF-14-1-0348; W911NF-14-1-0669; FA9550-12-1-0189

OSTI ID:: 1261104

Journal Information:: Nature (London), Vol. 534, Issue 7606; ISSN 0028-0836

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 328 works

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