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Title: Intriguing Optoelectronic Properties of Metal Halide Perovskites

Abstract

Here, a new chapter in the long and distinguished history of perovskites is being written with the breakthrough success of metal halide perovskites (MHPs) as solution-processed photovoltaic (PV) absorbers. The current surge in MHP research has largely arisen out of their rapid progress in PV devices; however, these materials are potentially suitable for a diverse array of optoelectronic applications. Like oxide perovskites, MHPs have ABX 3 stoichiometry, where A and B are cations and X is a halide anion. Here, the underlying physical and photophysical properties of inorganic (A = inorganic) and hybrid organic-inorganic (A = organic) MHPs are reviewed with an eye toward their potential application in emerging optoelectronic technologies. Significant attention is given to the prototypical compound methylammonium lead iodide (CH 3NH 3PbI 3) due to the preponderance of experimental and theoretical studies surrounding this material. We also discuss other salient MHP systems, including 2- dimensional compounds, where relevant. More specifically, this review is a critical account of the interrelation between MHP electronic structure, absorption, emission, carrier dynamics and transport, and other relevant photophysical processes that have propelled these materials to the forefront of modern optoelectronics research.

Authors:
 [1];  [2];  [3]
  1. Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, United States, Department of Chemical &, Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, United States
  2. Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, United States
  3. Radiation Laboratory, University of Notre Dame, Notre Dame, Indiana 46556, United States, Department of Chemical &, Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, United States, Department of Chemistry &, Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, United States
Publication Date:
Research Org.:
Univ. of Notre Dame, Notre Dame, IN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1258727
Alternate Identifier(s):
OSTI ID: 1331812
Grant/Contract Number:  
FC02-04ER15533; SC0014334
Resource Type:
Journal Article: Published Article
Journal Name:
Chemical Reviews
Additional Journal Information:
Journal Name: Chemical Reviews Journal Volume: 116 Journal Issue: 21; Journal ID: ISSN 0009-2665
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE

Citation Formats

Manser, Joseph S., Christians, Jeffrey A., and Kamat, Prashant V. Intriguing Optoelectronic Properties of Metal Halide Perovskites. United States: N. p., 2016. Web. doi:10.1021/acs.chemrev.6b00136.
Manser, Joseph S., Christians, Jeffrey A., & Kamat, Prashant V. Intriguing Optoelectronic Properties of Metal Halide Perovskites. United States. doi:10.1021/acs.chemrev.6b00136.
Manser, Joseph S., Christians, Jeffrey A., and Kamat, Prashant V. Tue . "Intriguing Optoelectronic Properties of Metal Halide Perovskites". United States. doi:10.1021/acs.chemrev.6b00136.
@article{osti_1258727,
title = {Intriguing Optoelectronic Properties of Metal Halide Perovskites},
author = {Manser, Joseph S. and Christians, Jeffrey A. and Kamat, Prashant V.},
abstractNote = {Here, a new chapter in the long and distinguished history of perovskites is being written with the breakthrough success of metal halide perovskites (MHPs) as solution-processed photovoltaic (PV) absorbers. The current surge in MHP research has largely arisen out of their rapid progress in PV devices; however, these materials are potentially suitable for a diverse array of optoelectronic applications. Like oxide perovskites, MHPs have ABX3 stoichiometry, where A and B are cations and X is a halide anion. Here, the underlying physical and photophysical properties of inorganic (A = inorganic) and hybrid organic-inorganic (A = organic) MHPs are reviewed with an eye toward their potential application in emerging optoelectronic technologies. Significant attention is given to the prototypical compound methylammonium lead iodide (CH3NH3PbI3) due to the preponderance of experimental and theoretical studies surrounding this material. We also discuss other salient MHP systems, including 2- dimensional compounds, where relevant. More specifically, this review is a critical account of the interrelation between MHP electronic structure, absorption, emission, carrier dynamics and transport, and other relevant photophysical processes that have propelled these materials to the forefront of modern optoelectronics research.},
doi = {10.1021/acs.chemrev.6b00136},
journal = {Chemical Reviews},
issn = {0009-2665},
number = 21,
volume = 116,
place = {United States},
year = {2016},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1021/acs.chemrev.6b00136

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Structural origins of the electronic properties of materials via time-resolved infrared spectroscopy
journal, January 2019

  • Munson, Kyle T.; Kennehan, Eric R.; Asbury, John B.
  • Journal of Materials Chemistry C, Vol. 7, Issue 20
  • DOI: 10.1039/c9tc01348b

Determination of the structural phase and octahedral rotation angle in halide perovskites
journal, February 2018

  • dos Reis, Roberto; Yang, Hao; Ophus, Colin
  • Applied Physics Letters, Vol. 112, Issue 7
  • DOI: 10.1063/1.5017537

On the prospect of CZTSSe-based thin film solar cells for indoor photovoltaic applications: A simulation study
journal, May 2019

  • Haque, K. A.; Baten, Md Zunaid
  • AIP Advances, Vol. 9, Issue 5
  • DOI: 10.1063/1.5099274

Detection of Rashba spin splitting in 2D organic-inorganic perovskite via precessional carrier spin relaxation
journal, August 2019

  • Todd, Seth B.; Riley, Drew B.; Binai-Motlagh, Ali
  • APL Materials, Vol. 7, Issue 8
  • DOI: 10.1063/1.5099352

Optically pumped white light-emitting diodes based on metal halide perovskites and perovskite-related materials
journal, January 2020

  • Worku, Michael; Xu, Liang-Jin; Chaaban, Maya
  • APL Materials, Vol. 8, Issue 1
  • DOI: 10.1063/1.5140441

The templating effect of 1,2-cyclohexanediamine configuration on iodoplumbate organic–inorganic hybrid structures
journal, February 2020


Cs 2 TlBiI 6 : a new lead-free halide double perovskite with direct band gap
journal, August 2019

  • Nair, Shruthi; Deshpande, Mrinalini; Shah, Vaishali
  • Journal of Physics: Condensed Matter, Vol. 31, Issue 44
  • DOI: 10.1088/1361-648x/ab32a5

Synthesis and Characterization of Methylammonium Lead Iodide Perovskite and its Application in Planar Hetero-junction Devices
journal, May 2018

  • Upadhyaya, Aditi; Negi, Chandra Mohan Singh; Yadav, Anjali
  • Semiconductor Science and Technology, Vol. 33, Issue 6
  • DOI: 10.1088/1361-6641/aac066

Advances in modelling and simulation of halide perovskites for solar cell applications
journal, January 2019


Introduction: minerals to metal-organic frameworks
journal, May 2019

  • Phillips, Anthony E.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2149
  • DOI: 10.1098/rsta.2019.0153

Free-electron effects on the optical absorption of the hybrid perovskite CH 3 NH 3 PbI 3 from first principles
journal, July 2019


Explaining observed stability of excitons in highly excited CdSe nanoplatelets
journal, December 2019

  • García Flórez, F.; Kulkarni, Aditya; Siebbeles, Laurens D. A.
  • Physical Review B, Vol. 100, Issue 24
  • DOI: 10.1103/physrevb.100.245302

Calculating polaron mobility in halide perovskites
journal, November 2017


Design of p -type transparent conductors from inverted band structure: The case of inorganic metal halide perovskites
journal, May 2019


Time stamping of single optical photons with 10 ns resolution
conference, May 2017

  • Chakaberia, Irakli; Cotlet, Mircea; Fisher-Levine, Merlin
  • SPIE Commercial + Scientific Sensing and Imaging, SPIE Proceedings
  • DOI: 10.1117/12.2262212

Lead halide perovskites: Crystal-liquid duality, phonon glass electron crystals, and large polaron formation
journal, October 2017

  • Miyata, Kiyoshi; Atallah, Timothy L.; Zhu, X. -Y.
  • Science Advances, Vol. 3, Issue 10
  • DOI: 10.1126/sciadv.1701469

Aggregation-induced emission in lamellar solids of colloidal perovskite quantum wells
journal, December 2017

  • Jagielski, Jakub; Kumar, Sudhir; Wang, Mingchao
  • Science Advances, Vol. 3, Issue 12
  • DOI: 10.1126/sciadv.aaq0208

Constructive molecular configurations for surface-defect passivation of perovskite photovoltaics
journal, December 2019


Diagnosis of electrically active defects in CH 3 NH 3 PbI 3 perovskite solar cells via admittance spectroscopy measurements
journal, January 2020


Encapsulated room-temperature synthesized CsPbX 3 perovskite quantum dots with high stability and wide color gamut for display
journal, January 2018

  • Xie, Yujun; Yu, Yan; Gong, Junyi
  • Optical Materials Express, Vol. 8, Issue 11
  • DOI: 10.1364/ome.8.003494

Environment versus sustainable energy: The case of lead halide perovskite-based solar cells
journal, January 2018

  • Babayigit, Aslihan; Boyen, Hans-Gerd; Conings, Bert
  • MRS Energy & Sustainability, Vol. 5
  • DOI: 10.1557/mre.2017.17

Recent Progress in Two-Dimensional Nanomaterials for Laser Protection
journal, January 2019


Perovskite Solar Cells: Progress and Advancements
journal, October 2016

  • Elumalai, Naveen; Mahmud, Md; Wang, Dian
  • Energies, Vol. 9, Issue 11
  • DOI: 10.3390/en9110861

Emergence of Nanoplatelet Light-Emitting Diodes
journal, August 2018

  • Xiao, Peng; Huang, Junhua; Yan, Dong
  • Materials, Vol. 11, Issue 8
  • DOI: 10.3390/ma11081376

MOF-Confined Sub-2 nm Stable CsPbX3 Perovskite Quantum Dots
journal, August 2019

  • Li, Zhenxing; Yu, Chengcheng; Wen, Yangyang
  • Nanomaterials, Vol. 9, Issue 8
  • DOI: 10.3390/nano9081147