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Title: Polymorphism in magic-sized Au144(SR)60 clusters

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Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
OSTI Identifier:
Resource Type:
Journal Article
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 7; Journal Issue: 06, 2016; Journal ID: ISSN 2041-1723
Nature Publishing Group
Country of Publication:
United States

Citation Formats

Jensen, Kirsten M. Ø., Juhas, Pavol, Tofanelli, Marcus A., Heinecke, Christine L., Vaughan, Gavin, Ackerson, Christopher J., and Billinge, Simon J. L. Polymorphism in magic-sized Au144(SR)60 clusters. United States: N. p., 2016. Web. doi:10.1038/ncomms11859.
Jensen, Kirsten M. Ø., Juhas, Pavol, Tofanelli, Marcus A., Heinecke, Christine L., Vaughan, Gavin, Ackerson, Christopher J., & Billinge, Simon J. L. Polymorphism in magic-sized Au144(SR)60 clusters. United States. doi:10.1038/ncomms11859.
Jensen, Kirsten M. Ø., Juhas, Pavol, Tofanelli, Marcus A., Heinecke, Christine L., Vaughan, Gavin, Ackerson, Christopher J., and Billinge, Simon J. L. Fri . "Polymorphism in magic-sized Au144(SR)60 clusters". United States. doi:10.1038/ncomms11859.
title = {Polymorphism in magic-sized Au144(SR)60 clusters},
author = {Jensen, Kirsten M. Ø. and Juhas, Pavol and Tofanelli, Marcus A. and Heinecke, Christine L. and Vaughan, Gavin and Ackerson, Christopher J. and Billinge, Simon J. L.},
abstractNote = {},
doi = {10.1038/ncomms11859},
journal = {Nature Communications},
issn = {2041-1723},
number = 06, 2016,
volume = 7,
place = {United States},
year = {2016},
month = {11}

Works referenced in this record:

Synthesis and reactions of functionalised gold nanoparticles
journal, January 1995

  • Brust, M.; Fink, J.; Bethell, D.
  • Journal of the Chemical Society, Chemical Communications, Issue 16
  • DOI: 10.1039/c39950001655

Synthesis of thiol-derivatised gold nanoparticles in a two-phase Liquid–Liquid system
journal, January 1994

  • Brust, Mathias; Walker, Merryl; Bethell, Donald
  • J. Chem. Soc., Chem. Commun., Vol. 0, Issue 7
  • DOI: 10.1039/C39940000801

Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 A Resolution
journal, October 2007

A unified view of ligand-protected gold clusters as superatom complexes
journal, July 2008

  • Walter, M.; Akola, J.; Lopez-Acevedo, O.
  • Proceedings of the National Academy of Sciences, Vol. 105, Issue 27
  • DOI: 10.1073/pnas.0801001105

Correlating the Crystal Structure of A Thiol-Protected Au25 Cluster and Optical Properties
journal, May 2008

  • Zhu, Manzhou; Aikens, Christine M.; Hollander, Frederick J.
  • Journal of the American Chemical Society, Vol. 130, Issue 18, p. 5883-5885
  • DOI: 10.1021/ja801173r

Information on quantum states pervades the visible spectrum of the ubiquitous Au144(SR)60 gold nanocluster
journal, April 2014

  • Weissker, H. -Ch.; Escobar, H. Barron; Thanthirige, V. D.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4785

Evolution of Nonlinear Optical Properties: From Gold Atomic Clusters to Plasmonic Nanocrystals
journal, January 2012

  • Philip, Reji; Chantharasupawong, Panit; Qian, Huifeng
  • Nano Letters, Vol. 12, Issue 9
  • DOI: 10.1021/nl301988v

A Critical Size for Emergence of Nonbulk Electronic and Geometric Structures in Dodecanethiolate-Protected Au Clusters
journal, January 2015

  • Negishi, Yuichi; Nakazaki, Tafu; Malola, Sami
  • Journal of the American Chemical Society, Vol. 137, Issue 3
  • DOI: 10.1021/ja5109968

Quantum sized, thiolate-protected gold nanoclusters
journal, January 2010

Quantum Sized Gold Nanoclusters with Atomic Precision
journal, June 2012

  • Qian, Huifeng; Zhu, Manzhou; Wu, Zhikun
  • Accounts of Chemical Research, Vol. 45, Issue 9
  • DOI: 10.1021/ar200331z

The Problem with Determining Atomic Structure at the Nanoscale
journal, April 2007

Nanocrystal gold molecules
journal, May 1996

  • Whetten, Robert L.; Khoury, Joseph T.; Alvarez, Marcos M.
  • Advanced Materials, Vol. 8, Issue 5
  • DOI: 10.1002/adma.19960080513

Properties of a Ubiquitous 29 kDa Au:SR Cluster Compound
journal, September 2001

  • Schaaff, T. Gregory; Shafigullin, Marat N.; Khoury, Joseph T.
  • The Journal of Physical Chemistry B, Vol. 105, Issue 37
  • DOI: 10.1021/jp011122w

Structural isomerism in gold nanoparticles revealed by X-ray crystallography
journal, October 2015

  • Tian, Shubo; Li, Yi-Zhi; Li, Man-Bo
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9667

Critical sizes in the growth of Au clusters
journal, February 1997

Structural Evolution of Smaller Gold Nanocrystals: The Truncated Decahedral Motif
journal, September 1997

Ubiquitous 8 and 29 kDa Gold:Alkanethiolate Cluster Compounds: Mass-Spectrometric Determination of Molecular Formulas and Structural Implications
journal, July 2008

  • Chaki, Nirmalya K.; Negishi, Yuichi; Tsunoyama, Hironori
  • Journal of the American Chemical Society, Vol. 130, Issue 27
  • DOI: 10.1021/ja8005379

Controlling Nanoparticles with Atomic Precision: The Case of Au 144 (SCH 2 CH 2 Ph) 60
journal, December 2009

Structure and Bonding in the Ubiquitous Icosahedral Metallic Gold Cluster Au 144 (SR) 60
journal, January 2009

  • Lopez-Acevedo, Olga; Akola, Jaakko; Whetten, Robert L.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 13
  • DOI: 10.1021/jp8115098

Ligand symmetry-equivalence on thiolate protected gold nanoclusters determined by NMR spectroscopy
journal, January 2012

  • Wong, O. Andrea; Heinecke, Christine L.; Simone, Ashli R.
  • Nanoscale, Vol. 4, Issue 14
  • DOI: 10.1039/c2nr30259d

STEM Electron Diffraction and High-Resolution Images Used in the Determination of the Crystal Structure of the Au 144 (SR) 60 Cluster
journal, March 2013

  • Bahena, Daniel; Bhattarai, Nabraj; Santiago, Ulises
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 6
  • DOI: 10.1021/jz400111d

The gold–sulfur interface at the nanoscale
journal, May 2012

Nanosized Pd145(CO)x(PEt3)30 Containing a Capped Three-Shell 145-Atom Metal-Core Geometry of Pseudo Icosahedral Symmetry
journal, November 2000

Applications of pair distribution function methods to contemporary problems in materials chemistry
journal, January 2011

  • Young, Callum A.; Goodwin, Andrew L.
  • Journal of Materials Chemistry, Vol. 21, Issue 18
  • DOI: 10.1039/c0jm04415f

Confirmation of disordered structure of ultrasmall CdSe nanoparticles from X-ray atomic pair distribution function analysis
journal, January 2013

  • Yang, Xiaohao; Masadeh, Ahmad S.; McBride, James R.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 22
  • DOI: 10.1039/c3cp00111c

Structure of nanoparticles from powder diffraction data using the pair distribution function
journal, January 2005

  • Neder, Reinhard B.; Korsunskiy, Vladimir I.
  • Journal of Physics: Condensed Matter, Vol. 17, Issue 5
  • DOI: 10.1088/0953-8984/17/5/013

Building and refining complete nanoparticle structures with total scattering data
journal, February 2011

  • Page, Katharine; Hood, Taylor C.; Proffen, Thomas
  • Journal of Applied Crystallography, Vol. 44, Issue 2
  • DOI: 10.1107/S0021889811001968

Ab initio determination of solid-state nanostructure
journal, March 2006

  • Juhás, P.; Cherba, D. M.; Duxbury, P. M.
  • Nature, Vol. 440, Issue 7084
  • DOI: 10.1038/nature04556

Structure Determination of Disordered Materials from Diffraction Data
journal, March 2010

Atomic Structure of Au 329 (SR) 84 Faradaurate Plasmonic Nanomolecules
journal, January 2015

  • Kumara, Chanaka; Zuo, Xiaobing; Ilavsky, Jan
  • The Journal of Physical Chemistry C, Vol. 119, Issue 20
  • DOI: 10.1021/jp512910a

Super-Stable, Highly Monodisperse Plasmonic Faradaurate-500 Nanocrystals with 500 Gold Atoms: Au ∼500 (SR) ∼120
journal, May 2014

  • Kumara, Chanaka; Zuo, Xiaobing; Ilavsky, Jan
  • Journal of the American Chemical Society, Vol. 136, Issue 20
  • DOI: 10.1021/ja502327a

Characterisation of amorphous and nanocrystalline molecular materials by total scattering
journal, January 2010

  • Billinge, Simon J. L.; Dykhne, Timur; Juhás, Pavol
  • CrystEngComm, Vol. 12, Issue 5
  • DOI: 10.1039/B915453A

Au 137 (SR) 56 nanomolecules: composition, optical spectroscopy, electrochemistry and electrocatalytic reduction of CO 2
journal, January 2014

  • Jupally, Vijay Reddy; Dharmaratne, Asantha C.; Crasto, David
  • Chemical Communications, Vol. 50, Issue 69
  • DOI: 10.1039/C4CC03424D

Au144−xCux(SC6H13)60 nanomolecules: effect of Cu incorporation on composition and plasmon-like peak emergence in optical spectra
journal, January 2014

  • Dharmaratne, Asantha C.; Dass, Amala
  • Chemical Communications, Vol. 50, Issue 14
  • DOI: 10.1039/c3cc47060a

Nondestructive Size Determination of Thiol-Stabilized Gold Nanoclusters in Solution by Diffusion Ordered NMR Spectroscopy
journal, March 2013

  • Salorinne, Kirsi; Lahtinen, Tanja; Koivisto, Jaakko
  • Analytical Chemistry, Vol. 85, Issue 7
  • DOI: 10.1021/ac303665b

Synthesis and Bioconjugation of 2 and 3 nm-Diameter Gold Nanoparticles
journal, February 2010

  • Ackerson, Christopher J.; Jadzinsky, Pablo D.; Sexton, Jonathan Z.
  • Bioconjugate Chemistry, Vol. 21, Issue 2
  • DOI: 10.1021/bc900135d

Vibrational Perturbations and Ligand–Layer Coupling in a Single Crystal of Au 144 (SC 2 H 4 Ph) 60 Nanocluster
journal, January 2014

  • Koivisto, Jaakko; Salorinne, Kirsi; Mustalahti, Satu
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 2
  • DOI: 10.1021/jz4026003

Measuring Correlated Atomic Motion Using X-ray Diffraction
journal, February 1999

  • Jeong, Il-Kyoung; Proffen, Thomas; Mohiuddin-Jacobs, Farida
  • The Journal of Physical Chemistry A, Vol. 103, Issue 7
  • DOI: 10.1021/jp9836978

Crystal Structure of Barrel-Shaped Chiral Au 130 ( p -MBT) 50 Nanocluster
journal, August 2015

  • Chen, Yuxiang; Zeng, Chenjie; Liu, Chong
  • Journal of the American Chemical Society, Vol. 137, Issue 32
  • DOI: 10.1021/jacs.5b05378

Au 133 (SPh- t Bu) 52 Nanomolecules: X-ray Crystallography, Optical, Electrochemical, and Theoretical Analysis
journal, April 2015

  • Dass, Amala; Theivendran, Shevanuja; Nimmala, Praneeth Reddy
  • Journal of the American Chemical Society, Vol. 137, Issue 14
  • DOI: 10.1021/ja513152h

Surface structure and energetics of multiply twinned particles
journal, July 1984

Experimental studies of small particle structures
journal, June 1994

The “Staple” Motif:  A Key to Stability of Thiolate-Protected Gold Nanoclusters
journal, March 2008

  • Jiang, De-en; Tiago, Murilo L.; Luo, Weidong
  • Journal of the American Chemical Society, Vol. 130, Issue 9
  • DOI: 10.1021/ja710991n

Crystal Structure of the Gold Nanoparticle [N(C 8 H 17 ) 4 ][Au 25 (SCH 2 CH 2 Ph) 18 ]
journal, March 2008

  • Heaven, Michael W.; Dass, Amala; White, Peter S.
  • Journal of the American Chemical Society, Vol. 130, Issue 12
  • DOI: 10.1021/ja800561b

Total Structure Determination of Thiolate-Protected Au 38 Nanoparticles
journal, June 2010

  • Qian, Huifeng; Eckenhoff, William T.; Zhu, Yan
  • Journal of the American Chemical Society, Vol. 132, Issue 24
  • DOI: 10.1021/ja103592z

Structure Determination of [Au 18 (SR) 14 ]
journal, January 2015

  • Das, Anindita; Liu, Chong; Byun, Hee Young
  • Angewandte Chemie International Edition, Vol. 54, Issue 10
  • DOI: 10.1002/anie.201410161

Cyclopentanethiolato-Protected Au 36 (SC 5 H 9 ) 24 Nanocluster: Crystal Structure and Implications for the Steric and Electronic Effects of Ligand
journal, March 2014

  • Das, Anindita; Liu, Chong; Zeng, Chenjie
  • The Journal of Physical Chemistry A, Vol. 118, Issue 37
  • DOI: 10.1021/jp501073a

Electron microscopy of gold nanoparticles at atomic resolution
journal, August 2014

Variation of the Core Atomic Structure of Thiolated (Au x Ag 1– x ) 312±55 Nanoclusters with Composition from Aberration-Corrected HAADF STEM
journal, January 2015

  • Jian, Nan; Palmer, Richard E.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 20
  • DOI: 10.1021/jp5119103

Ligand Heterogeneity on Monolayer-Protected Gold Clusters
journal, June 2005

  • Song, Yang; Harper, Amanda S.; Murray, Royce W.
  • Langmuir, Vol. 21, Issue 12
  • DOI: 10.1021/la0503606

Structure & bonding of the gold-subhalide cluster I-Au144Cl60[z]
journal, January 2013

  • Tlahuice-Flores, Alfredo; Black, David M.; Bach, Stephan B. H.
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 44
  • DOI: 10.1039/c3cp53902d

Superatom Electron Configuration Predicts Thermal Stability of Au 25 (SR) 18 Nanoclusters
journal, October 2012

  • Tofanelli, Marcus A.; Ackerson, Christopher J.
  • Journal of the American Chemical Society, Vol. 134, Issue 41
  • DOI: 10.1021/ja3072644

Hierarchy of bond stiffnesses within icosahedral-based gold clusters protected by thiolates
journal, January 2016

  • Yamazoe, Seiji; Takano, Shinjiro; Kurashige, Wataru
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms10414

Thermally Robust Au 99 (SPh) 42 Nanoclusters for Chemoselective Hydrogenation of Nitrobenzaldehyde Derivatives in Water
journal, February 2014

  • Li, Gao; Zeng, Chenjie; Jin, Rongchao
  • Journal of the American Chemical Society, Vol. 136, Issue 9
  • DOI: 10.1021/ja500121v

Au 67 (SR) 35 Nanomolecules: Characteristic Size-Specific Optical, Electrochemical, Structural Properties and First-Principles Theoretical Analysis
journal, January 2013

  • Nimmala, Praneeth Reddy; Yoon, Bokwon; Whetten, Robert L.
  • The Journal of Physical Chemistry A, Vol. 117, Issue 2
  • DOI: 10.1021/jp311491v

Ambient Synthesis of Au 144 (SR) 60 Nanoclusters in Methanol
journal, April 2011

  • Qian, Huifeng; Jin, Rongchao
  • Chemistry of Materials, Vol. 23, Issue 8
  • DOI: 10.1021/cm200143s

Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996

  • Hammersley, A. P.; Svensson, S. O.; Hanfland, M.
  • High Pressure Research, Vol. 14, Issue 4-6, p. 235-248
  • DOI: 10.1080/08957959608201408

PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions
journal, March 2013

    Works referencing / citing this record:

    N-heterocyclic carbene-functionalized magic-number gold nanoclusters
    journal, April 2019

    • Narouz, Mina R.; Osten, Kimberly M.; Unsworth, Phillip J.
    • Nature Chemistry, Vol. 11, Issue 5
    • DOI: 10.1038/s41557-019-0246-5

    Stibine-protected Au 13 nanoclusters: syntheses, properties and facile conversion to GSH-protected Au 25 nanocluster
    journal, January 2018

    • Li, Ying-Zhou; Ganguly, Rakesh; Hong, Kar Yiu
    • Chemical Science, Vol. 9, Issue 46
    • DOI: 10.1039/c8sc03132k

    Unraveling the long-pursued Au 144 structure by x-ray crystallography
    journal, October 2018