Transition metal nitride coated with atomic layers of Pt as a low-cost, highly stable electrocatalyst for the oxygen reduction reaction

Tian, Xinlong; Adzic, Radoslav R.; Luo, Junming; Nan, Haoxiong; Zou, Haobin; Chen, Rong; Shu, Ting; Li, Xiuhua; Li, Yingwei; Song, Huiyi; Liao, Shijun

doi:10.1021/jacs.5b11364

Title: Transition metal nitride coated with atomic layers of Pt as a low-cost, highly stable electrocatalyst for the oxygen reduction reaction

Journal Article · Wed Feb 10 00:00:00 EST 2016 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b11364· OSTI ID:1257951

Tian, Xinlong ^[1]; Adzic, Radoslav R. ^[2]; Luo, Junming ^[1]; Nan, Haoxiong ^[1]; Zou, Haobin ^[1]; Chen, Rong ^[1]; Shu, Ting ^[1]; Li, Xiuhua ^[1]; Li, Yingwei ^[1]; Song, Huiyi ^[1]; Liao, Shijun ^[1]

South China Univ. of Technology, Guangzhou (China)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Here, the main challenges to the commercial viability of polymer electrolyte membrane fuel cells are (i) the high cost associated with using large amounts of Pt in fuel cell cathodes to compensate for the sluggish kinetics of the oxygen reduction reaction, (ii) catalyst degradation, and (iii) carbon-support corrosion. To address these obstacles, our group has focused on robust, carbon-free transition metal nitride materials with low Pt content that exhibit tunable physical and catalytic properties. Here, we report on the high performance of a novel catalyst with low Pt content, prepared by placing several layers of Pt atoms on nanoparticles of titanium nickel binary nitride. For the ORR, the catalyst exhibited a more than 400% and 200% increase in mass activity and specific activity, respectively, compared with the commercial Pt/C catalyst. It also showed excellent stability/durability, experiencing only a slight performance loss after 10,000 potential cycles, while TEM results showed its structure had remained intact. The catalyst’s outstanding performance may have resulted from the ultrahigh dispersion of Pt (several atomic layers coated on the nitride nanoparticles), and the excellent stability/durability may have been due to the good stability of nitride and synergetic effects between ultrathin Pt layer and the robust TiNiN support.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1257951

Report Number(s):: BNL-112237-2016-JA; R&D Project: MA510MAEA; KC0302010

Journal Information:: Journal of the American Chemical Society, Vol. 138, Issue 5; ISSN 0002-7863

Country of Publication:: United States

Language:: English

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Cited by: 310 works

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Programmable Exposure of Pt Active Facets for Efficient Oxygen Reduction Wang, Guanzhi; Yang, Zhenzhong; Du, Yingge Angewandte Chemie International Edition, Vol. 58, Issue 44 https://doi.org/10.1002/anie.201907322	journal	September 2019
Mechanochemical-Assisted Synthesis of High-Entropy Metal Nitride via a Soft Urea Strategy Jin, Tian; Sang, Xiahan; Unocic, Raymond R. Advanced Materials, Vol. 30, Issue 23 https://doi.org/10.1002/adma.201707512	journal	April 2018
Recent Developments in Electrocatalysts and Hybrid Electrocatalyst Support Systems for Polymer Electrolyte Fuel Cells Sharma, Surbhi Electrocatalysts for Low Temperature Fuel Cells: Fundamentals and Recent Trends https://doi.org/10.1002/9783527803873.ch7	book	January 2017
A facile one-pot method to prepare nitrogen and fluorine co-doped three-dimensional graphene-like materials for supercapacitors Duan, Diancheng; Hu, Fang; Ma, Jiaojun Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 21 https://doi.org/10.1007/s10854-019-02316-7	journal	October 2019
Cobalt Nanoparticles Encapsulated in Nitrogen-Doped Carbon Nanotube as Bifunctional-Catalyst for Rechargeable Zn-Air Batteries Liu, Yang; Dong, Peng; Li, Mian Frontiers in Materials, Vol. 6 https://doi.org/10.3389/fmats.2019.00085	journal	April 2019
Facile synthesis of N-doped graphene supported porous cobalt molybdenum oxynitride nanodendrites for the oxygen reduction reaction Sharma, Kamaldeep; Hui, David; Kim, Nam Hoon Nanoscale, Vol. 11, Issue 3 https://doi.org/10.1039/c8nr06780e	journal	January 2019
Adding refractory 5d transition metal W into PtCo system: an advanced ternary alloy for efficient oxygen reduction reaction Wu, Yijun; Zhao, Yige; Liu, Jingjun Journal of Materials Chemistry A, Vol. 6, Issue 23 https://doi.org/10.1039/c8ta00029h	journal	January 2018
Kern-Schale-Strukturierung rein metallischer Aerogele für eine hocheffiziente Nutzung von Platin für die Sauerstoffreduktion Cai, Bin; Hübner, René; Sasaki, Kotaro Angewandte Chemie, Vol. 130, Issue 11 https://doi.org/10.1002/ange.201710997	journal	February 2018
Highly stable Pt ₃ Ni nanowires tailored with trace Au for the oxygen reduction reaction Wu, Zhifu; Su, Ya-Qiong; Hensen, Emiel J. M. Journal of Materials Chemistry A, Vol. 7, Issue 46 https://doi.org/10.1039/c9ta08682j	journal	January 2019
Pt–Cu based nanocrystals as promising catalysts for various electrocatalytic reactions Chaudhari, Nitin K.; Hong, Yongju; Kim, Byeongyoon Journal of Materials Chemistry A, Vol. 7, Issue 29 https://doi.org/10.1039/c9ta05309c	journal	January 2019
Soft chemistry of ion-exchangeable layered metal oxides Uppuluri, Ritesh; Sen Gupta, Arnab; Rosas, Alyssa S. Chemical Society Reviews, Vol. 47, Issue 7 https://doi.org/10.1039/c7cs00290d	journal	January 2018
UIO-66-NH ₂ -Derived Mesoporous Carbon Catalyst Co-Doped with Fe/N/S as Highly Efficient Cathode Catalyst for PEMFCs Zheng, Long; Dong, Yuanyuan; Chi, Bin Small, Vol. 15, Issue 4 https://doi.org/10.1002/smll.201803520	journal	December 2018
Understanding the boosted sodium storage behavior of a nanoporous bismuth-nickel anode using operando X-ray diffraction and density functional theory calculations Gao, Hui; Song, Lin; Niu, Jiazheng Journal of Materials Chemistry A, Vol. 7, Issue 22 https://doi.org/10.1039/c9ta03810h	journal	January 2019
Improving the Visible-Light Photocatalytic Activity of Graphitic Carbon Nitride by Carbon Black Doping Zhang, Luhong; Jin, Zhengyuan; Lu, Hao ACS Omega, Vol. 3, Issue 11 https://doi.org/10.1021/acsomega.8b01933	journal	November 2018
Low content Pt nanoparticles anchored on N-doped reduced graphene oxide with high and stable electrocatalytic activity for oxygen reduction reaction Li, Zeyu; Gao, Qiuming; Zhang, Hang Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep43352	journal	February 2017
Tuning the Catalytic Activity of Ir@Pt Nanoparticles Through Controlling Ir Core Size on Cathode Performance for PEM Fuel Cell Application Zheng, Hao-Bo; An, Lu; Zheng, Yuying Frontiers in Chemistry, Vol. 6 https://doi.org/10.3389/fchem.2018.00299	journal	July 2018

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