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Microporous coordination complex and method of making the same

Patent ·
OSTI ID:1255212
;

Disclosed herein is a three-dimensional coordination complex that includes a plurality of inorganic centers; a plurality of a first bis(bidentate) linker; and a plurality of a second bis(bidentate) linker, where the first and the second bis(bidentate) linkers are have different lengths, and the bidentate binding sites on each linker face in opposite directions on an axis.

Research Organization:
The Regents Of The University Of Michigan, Ann Arbor, MI (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0004888
Assignee:
The Regents Of The University Of Michigan (Ann Arbor, MI)
Patent Number(s):
9,353,129
Application Number:
14/130,607
OSTI ID:
1255212
Country of Publication:
United States
Language:
English

References (8)

Coexistence of two aromatic bicarboxylate ligands with distinct conformations in a fluorescent zinc(II) polymer journal February 2008
A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal January 2008
Interpenetrated metal–organic frameworks and their uptake of CO2 at relatively low pressures journal January 2012
Reticular Chemistry and Metal-Organic Frameworks for Clean Energy journal September 2009
Novel 2D and 3D Indium Metal-Organic Frameworks:  Topology and Catalytic Properties † journal May 2005
Coordination Copolymerization Mediated by Zn 4 O(CO 2 R) 6 Metal Clusters: a Balancing Act between Statistics and Geometry journal October 2010
Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications journal January 2011
Exceptional surface area from coordination copolymers derived from two linear linkers of differing lengths journal January 2012

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY