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Title: X-ray Absorption Spectroscopy Characterization of a Li/S Cell

Abstract

The X-ray absorption spectroscopy technique has been applied to study different stages of the lithium/sulfur (Li/S) cell life cycle. We investigated how speciation of S in Li/S cathodes changes upon the introduction of CTAB (cetyltrimethylammonium bromide, CH 3(CH 2) 15N+(CH 3) 3Br₋) and with charge/discharge cycling. The introduction of CTAB changes the synthesis reaction pathway dramatically due to the interaction of CTAB with the terminal S atoms of the polysulfide ions in the Na 2S x solution. For the cycled Li/S cell, the loss of electrochemically active sulfur and the accumulation of a compact blocking insulating layer of unexpected sulfur reaction products on the cathode surface during the charge/discharge processes make the capacity decay. Lastly, a modified coin cell and a vacuum-compatible three-electrode electro-chemical cell have been introduced for further in-situ/in-operando studies.

Authors:
 [1];  [2];  [3];  [4];  [5];  [5];  [5];  [2];  [6];  [7]
  1. Univ. of Science and Technology of China, Hefei (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Environmental Energy Technologies Division; Univ. of California, Berkeley, CA (United States)
  3. Washington State Univ., Pullman, WA (United States)
  4. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Harbin Inst. of Technology (China)
  5. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  6. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS); Univ. of California, Santa Cruz, CA (United States)
  7. Univ. of Science and Technology of China, Hefei (China)
Publication Date:
Research Org.:
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1254009
Alternate Identifier(s):
OSTI ID: 1379029
Grant/Contract Number:  
AC02-05CH11231; 2013CB834605; U1232102; 21173200; 21473178; (2015SRG-HSC031; 2015HSC-UP022
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nanomaterials
Additional Journal Information:
Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2079-4991
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
62 RADIOLOGY AND NUCLEAR MEDICINE; lithium/sulfur cell; X-ray absorption spectroscopy; cetyltrimethylammonium bromide; synthesis; capacity decay; cycled cathode materials; insulating layer; in-situ/in-operando

Citation Formats

Ye, Yifan, Kawase, Ayako, Song, Min-Kyu, Feng, Bingmei, Liu, Yi-Sheng, Marcus, Matthew A., Feng, Jun, Cairns, Elton J., Guo, Jinghua, and Zhu, Junfa. X-ray Absorption Spectroscopy Characterization of a Li/S Cell. United States: N. p., 2016. Web. doi:10.3390/nano6010014.
Ye, Yifan, Kawase, Ayako, Song, Min-Kyu, Feng, Bingmei, Liu, Yi-Sheng, Marcus, Matthew A., Feng, Jun, Cairns, Elton J., Guo, Jinghua, & Zhu, Junfa. X-ray Absorption Spectroscopy Characterization of a Li/S Cell. United States. doi:10.3390/nano6010014.
Ye, Yifan, Kawase, Ayako, Song, Min-Kyu, Feng, Bingmei, Liu, Yi-Sheng, Marcus, Matthew A., Feng, Jun, Cairns, Elton J., Guo, Jinghua, and Zhu, Junfa. Mon . "X-ray Absorption Spectroscopy Characterization of a Li/S Cell". United States. doi:10.3390/nano6010014. https://www.osti.gov/servlets/purl/1254009.
@article{osti_1254009,
title = {X-ray Absorption Spectroscopy Characterization of a Li/S Cell},
author = {Ye, Yifan and Kawase, Ayako and Song, Min-Kyu and Feng, Bingmei and Liu, Yi-Sheng and Marcus, Matthew A. and Feng, Jun and Cairns, Elton J. and Guo, Jinghua and Zhu, Junfa},
abstractNote = {The X-ray absorption spectroscopy technique has been applied to study different stages of the lithium/sulfur (Li/S) cell life cycle. We investigated how speciation of S in Li/S cathodes changes upon the introduction of CTAB (cetyltrimethylammonium bromide, CH3(CH2)15N+(CH3)3Br₋) and with charge/discharge cycling. The introduction of CTAB changes the synthesis reaction pathway dramatically due to the interaction of CTAB with the terminal S atoms of the polysulfide ions in the Na2Sx solution. For the cycled Li/S cell, the loss of electrochemically active sulfur and the accumulation of a compact blocking insulating layer of unexpected sulfur reaction products on the cathode surface during the charge/discharge processes make the capacity decay. Lastly, a modified coin cell and a vacuum-compatible three-electrode electro-chemical cell have been introduced for further in-situ/in-operando studies.},
doi = {10.3390/nano6010014},
journal = {Nanomaterials},
issn = {2079-4991},
number = 1,
volume = 6,
place = {United States},
year = {2016},
month = {1}
}

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