A nanosecond pulsed laser heating system for studying liquid and supercooled liquid films in ultrahigh vacuum

Xu, Yuntao; Dibble, Collin J.; Petrik, Nikolay G.; Smith, R. Scott; Joly, Alan G.; Tonkyn, Russell G.; Kay, Bruce D.; Kimmel, Greg A.

doi:10.1063/1.4947304

Title: A nanosecond pulsed laser heating system for studying liquid and supercooled liquid films in ultrahigh vacuum

Journal Article · Tue Apr 26 00:00:00 EDT 2016 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4947304· OSTI ID:1327144

Xu, Yuntao ^[1]; Dibble, Collin J. ^[1]; Petrik, Nikolay G. ^[2];

^[1]; Joly, Alan G. ^[1]; Tonkyn, Russell G. ^[1]; Kay, Bruce D. ^[1];

^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Physical Sciences Division
Physical Sciences Division, Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352, USA

A pulsed laser heating system has been developed that enables investigations of the dynamics and kinetics of nanoscale liquid films and liquid/solid interfaces on the nanosecond timescale in ultrahigh vacuum (UHV). Details of the design, implementation and characterization of a nanosecond pulsed laser system for transiently heating nanoscale films are described herein. Nanosecond pulses from a Nd:YAG laser are used to rapidly heat thin films of adsorbed water or other volatile materials on a clean, well-characterized Pt(111) crystal in UHV. Heating rates of ~1010 K/s for temperature increases of ~100 – 200 K are obtained. Subsequent rapid cooling (~5 × 109 K/s) quenches the film, permitting in-situ, post-mortem analysis using a variety of surface science techniques. Lateral variations in the laser pulse energy are ~ ± 3% leading to a temperature uncertainty of ~ ± 5 K for a temperature jump of 200 K. Initial experiments with the apparatus demonstrate that crystalline ice films initially held at 90 K can be rapidly transformed into liquid water films with T > 273 K. No discernable recrystallization occurs during the rapid cooling back to cryogenic temperatures. In contrast, amorphous solid water films heated below the melting point rapidly crystallize. The nanosecond pulsed laser heating system can prepare nanoscale liquid and supercooled liquid films that persist for nanoseconds per heat pulse in an UHV environment, enabling experimental studies of a wide range of phenomena in liquids and at liquid/solid interfaces.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1327144

Alternate ID(s):: OSTI ID: 1249957

Report Number(s):: PNNL-SA-115728; JCPSA6; 49144; KC0301050

Journal Information:: Journal of Chemical Physics, Vol. 144, Issue 16; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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