Fe/SSZ-13 as an NH3-SCR catalyst: A reaction kinetics and FTIR/Mössbauer spectroscopic study

Gao, Feng; Kollár, Márton; Kukkadapu, Ravi K.; Washton, Nancy M.; Wang, Yilin; Szanyi, János; Peden, Charles H. F.

doi:10.1016/j.apcatb.2014.09.031

Title: Fe/SSZ-13 as an NH3-SCR catalyst: A reaction kinetics and FTIR/Mössbauer spectroscopic study

Journal Article · Sun Mar 01 00:00:00 EST 2015 · Applied Catalysis. B, Environmental

DOI:https://doi.org/10.1016/j.apcatb.2014.09.031· OSTI ID:1249855

Gao, Feng; Kollár, Márton; Kukkadapu, Ravi K.; Washton, Nancy M.; Wang, Yilin; Szanyi, János; Peden, Charles H. F.

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Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Biological and Environmental Research (BER)

OSTI ID:: 1249855

Journal Information:: Applied Catalysis. B, Environmental, Journal Name: Applied Catalysis. B, Environmental Vol. 164 Journal Issue: C; ISSN 0926-3373

Publisher:: ElsevierCopyright Statement

Country of Publication:: Netherlands

Language:: English

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Cited by: 99 works

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References (46)

The simultaneous catalytic reduction of NO and N2O by NH3 using an Fe-zeolite-beta catalyst Coq, Bernard; Mauvezin, Mathias; Delahay, Gérard Applied Catalysis B: Environmental, Vol. 27, Issue 3 https://doi.org/10.1016/S0926-3373(00)00148-X	journal	August 2000
Steam-activated FeMFI zeolites. Evolution of iron species and activity in direct N2O decomposition Perezramirez, J. Journal of Catalysis, Vol. 214, Issue 1 https://doi.org/10.1016/S0021-9517(02)00021-0	journal	February 2003
The State of the Art in Selective Catalytic Reduction of NO _x by Ammonia Using Metal‐Exchanged Zeolite Catalysts Brandenberger, Sandro; Kröcher, Oliver; Tissler, Arno Catalysis Reviews, Vol. 50, Issue 4 https://doi.org/10.1080/01614940802480122	journal	December 2008
A M�ssbauer spectroscopic study of the reversible oxidation of ferrous ions in Y zeolite Garten, R. Journal of Catalysis, Vol. 18, Issue 1 https://doi.org/10.1016/0021-9517(70)90316-7	journal	July 1970
Fe/ZSM-5 Prepared by Sublimation of FeCl3: The Structure of the Fe Species as Determined by IR, 27Al MAS NMR, and EXAFS Spectroscopy Marturano, Pasqualino; Drozdová, Lucie; Kogelbauer, Andreas Journal of Catalysis, Vol. 192, Issue 1 https://doi.org/10.1006/jcat.2000.2837	journal	May 2000
On the nature of active sites in Fe/ZSM-5 catalysts for NOx abatement Voskoboinikov, Timur V.; Chen, Hai-Ying; Sachtler, Wolfgang M. H. Applied Catalysis B: Environmental, Vol. 19, Issue 3-4 https://doi.org/10.1016/S0926-3373(98)00082-4	journal	December 1998
Current Understanding of Cu-Exchanged Chabazite Molecular Sieves for Use as Commercial Diesel Engine DeNOx Catalysts Gao, Feng; Kwak, Ja Hun; Szanyi, Janos Topics in Catalysis, Vol. 56, Issue 15-17 https://doi.org/10.1007/s11244-013-0145-8	journal	August 2013
NO Adsorption on Ex-Framework [Fe,X]MFI Catalysts: Novel IR Bands and Evaluation of Assignments Mul, G.; Pérez-Ramírez, J.; Kapteijn, F. Catalysis Letters, Vol. 80, Issue 3/4, p. 129-138 https://doi.org/10.1023/A:1015456308687	journal	January 2002
Investigations of the State of Fe in H–ZSM-5 Lobree, Lisa J.; Hwang, In-Chul; Reimer, Jeffrey A. Journal of Catalysis, Vol. 186, Issue 2 https://doi.org/10.1006/jcat.1999.2548	journal	September 1999
A Common Intermediate for N ₂ Formation in Enzymes and Zeolites: Side-On Cu-Nitrosyl Complexes Kwak, Ja Hun; Lee, Jong H.; Burton, Sarah D. Angewandte Chemie International Edition, Vol. 52, Issue 38 https://doi.org/10.1002/anie.201303498	journal	August 2013
Nature of active species in copper-based catalysts and their chemistry of transformation of nitrogen oxides Centi, Gabriele; Perathoner, Siglinda Applied Catalysis A: General, Vol. 132, Issue 2 https://doi.org/10.1016/0926-860X(95)00154-9	journal	November 1995
NO-Assisted N2O Decomposition over Fe-Based Catalysts: Effects of Gas-Phase Composition and Catalyst Constitution Pérez-Ramı́rez, Javier; Kapteijn, Freek; Mul, Guido Journal of Catalysis, Vol. 208, Issue 1 https://doi.org/10.1006/jcat.2002.3559	journal	May 2002
NO _x Storage−Reduction Catalysis: From Mechanism and Materials Properties to Storage−Reduction Performance Roy, Sounak; Baiker, Alfons Chemical Reviews, Vol. 109, Issue 9 https://doi.org/10.1021/cr800496f	journal	September 2009
Characterization of Adsorbed Iron in Montmorillonite by Mössbauer Spectroscopy1 Diamant, A. Clays and Clay Minerals, Vol. 30, Issue 1 https://doi.org/10.1346/CCMN.1982.0300108	journal	January 1982
Characterization of Fe-Exchanged BEA Zeolite Under NH ₃ Selective Catalytic Reduction Conditions Kim, Jeongnam; Jentys, Andreas; Maier, Sarah M. The Journal of Physical Chemistry C, Vol. 117, Issue 2 https://doi.org/10.1021/jp309277n	journal	January 2013
Selective reduction of NO with Fe-ZSM-5 catalysts of low Fe contentI. Relations between active site structure and catalytic performance Schwidder, M.; Kumar, M.; Klementiev, K. Journal of Catalysis, Vol. 231, Issue 2 https://doi.org/10.1016/j.jcat.2005.01.031	journal	April 2005
Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange Gao, Feng; Walter, Eric D.; Washton, Nancy M. ACS Catalysis, Vol. 3, Issue 9 https://doi.org/10.1021/cs4004672	journal	August 2013
FTIR Characterization of Fe3+–OH Groups in Fe–H–BEA Zeolite: Interaction with CO and NO Kefirov, Radoslav; Ivanova, Elena; Hadjiivanov, Konstantin Catalysis Letters, Vol. 125, Issue 3-4 https://doi.org/10.1007/s10562-008-9577-3	journal	July 2008
Selective catalytic reduction of NO with NH3 on iron zeolite monolithic catalysts: Steady-state and transient kinetics Metkar, Pranit S.; Salazar, Nelson; Muncrief, Rachel Applied Catalysis B: Environmental, Vol. 104, Issue 1-2 https://doi.org/10.1016/j.apcatb.2011.02.022	journal	April 2011
Experimental Study of the NO Oxidation to NO2 Over Metal Promoted Zeolites Aimed at the Identification of the Standard SCR Rate Determining Step Ruggeri, Maria Pia; Nova, Isabella; Tronconi, Enrico Topics in Catalysis, Vol. 56, Issue 1-8 https://doi.org/10.1007/s11244-013-9937-0	journal	February 2013
Effects of hydrothermal aging on NH3-SCR reaction over Cu/zeolites Kwak, Ja Hun; Tran, Diana; Burton, Sarah D. Journal of Catalysis, Vol. 287 https://doi.org/10.1016/j.jcat.2011.12.025	journal	March 2012
Multiple Adsorption of NO on Fe²⁺ Cations in the α- and β-Positions of Ferrierite: An Experimental and Density Functional Study Benco, L.; Bucko, T.; Grybos, R. The Journal of Physical Chemistry C, Vol. 111, Issue 26 https://doi.org/10.1021/jp0724018	journal	June 2007
FeZSM-5: A Durable SCR Catalyst for NOxRemoval from Combustion Streams Feng, Xiaobing; Keith Hall, W. Journal of Catalysis, Vol. 166, Issue 2 https://doi.org/10.1006/jcat.1997.1530	journal	March 1997
Oxo- and hydroxo-bridged diiron complexes: a chemical perspective on a biological unit Kurtz, Donald M. Chemical Reviews, Vol. 90, Issue 4 https://doi.org/10.1021/cr00102a002	journal	June 1990
Coordination Chemistry of Fe ²⁺ Ions in Fe,H-ZSM-5 Zeolite as Revealed by the IR Spectra of Adsorbed CO and NO Mihaylov, Mihail; Ivanova, Elena; Drenchev, Nikola The Journal of Physical Chemistry C, Vol. 114, Issue 2 https://doi.org/10.1021/jp906213a	journal	December 2009
NOxStorage in Barium-Containing Catalysts Fridell, Erik; Skoglundh, Magnus; Westerberg, Björn Journal of Catalysis, Vol. 183, Issue 2 https://doi.org/10.1006/jcat.1999.2415	journal	April 1999
The chemistry of the NO/NO2–NH3 “fast” SCR reaction over Fe-ZSM5 investigated by transient reaction analysis Grossale, A.; Nova, I.; Tronconi, E. Journal of Catalysis, Vol. 256, Issue 2 https://doi.org/10.1016/j.jcat.2008.03.027	journal	June 2008
IR spectroscopy of adsorbed NO as a useful tool for the characterisation of low concentrated Fe-silicalite catalysts Berlier, G.; Spoto, G.; Ricchiardi, G. Journal of Molecular Catalysis A: Chemical, Vol. 182-183 https://doi.org/10.1016/S1381-1169(01)00510-6	journal	May 2002
Structure–activity relationships in NH3-SCR over Cu-SSZ-13 as probed by reaction kinetics and EPR studies Gao, Feng; Walter, Eric D.; Karp, Eric M. Journal of Catalysis, Vol. 300 https://doi.org/10.1016/j.jcat.2012.12.020	journal	April 2013
Investigation of the selective catalytic reduction of NO by NH3 on Fe-ZSM5 monolith catalysts Kröcher, Oliver; Devadas, Mukundan; Elsener, Martin Applied Catalysis B: Environmental, Vol. 66, Issue 3-4 https://doi.org/10.1016/j.apcatb.2006.03.012	journal	July 2006
Catalytic removal of NO Pârvulescu, V. I.; Grange, P.; Delmon, B. Catalysis Today, Vol. 46, Issue 4, p. 233-316 https://doi.org/10.1016/S0920-5861(98)00399-X	journal	December 1998
Tailoring of the structure of Fe-cationic species in Fe-ZSM-5 by distribution of Al atoms in the framework for N2O decomposition and NH3-SCR-NOx Sazama, Petr; Wichterlová, Blanka; Tábor, Edyta Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.019	journal	April 2014
Overview of the Fundamental Reactions and Degradation Mechanisms of NOx Storage/Reduction Catalysts Epling, William S.; Campbell, Larry E.; Yezerets, Aleksey Catalysis Reviews, Vol. 46, Issue 2 https://doi.org/10.1081/CR-200031932	journal	December 2004
On the nature of different iron sites and their catalytic role in Fe-ZSM-5 DeNOx catalysts: new insights by a combined EPR and UV/VIS spectroscopic approach Kumar, M. Santhosh; Schwidder, M.; Grünert, W. Journal of Catalysis, Vol. 227, Issue 2 https://doi.org/10.1016/j.jcat.2004.08.003	journal	October 2004
Preparation, Characterization, and Performance of Fe−ZSM-5 Catalysts Joyner, Richard; Stockenhuber, Michael The Journal of Physical Chemistry B, Vol. 103, Issue 29 https://doi.org/10.1021/jp990978m	journal	July 1999
The role of Brønsted acidity in the selective catalytic reduction of NO with ammonia over Fe-ZSM-5 Brandenberger, Sandro; Kröcher, Oliver; Wokaun, Alexander Journal of Catalysis, Vol. 268, Issue 2 https://doi.org/10.1016/j.jcat.2009.09.028	journal	December 2009
Local Environment and Nature of Cu Active Sites in Zeolite-Based Catalysts for the Selective Catalytic Reduction of NO _x Deka, Upakul; Lezcano-Gonzalez, Ines; Weckhuysen, Bert M. ACS Catalysis, Vol. 3, Issue 3 https://doi.org/10.1021/cs300794s	journal	February 2013
Study of a Fe–zeolite-based system as NH3-SCR catalyst for diesel exhaust aftertreatment Grossale, Antonio; Nova, Isabella; Tronconi, Enrico Catalysis Today, Vol. 136, Issue 1-2 https://doi.org/10.1016/j.cattod.2007.10.117	journal	July 2008
Thermal durability of Cu-CHA NH3-SCR catalysts for diesel NOx reduction Schmieg, Steven J.; Oh, Se H.; Kim, Chang H. Catalysis Today, Vol. 184, Issue 1 https://doi.org/10.1016/j.cattod.2011.10.034	journal	April 2012
Evolution of Iron States and Formation of α-Sites upon Activation of FeZSM-5 Zeolites Dubkov, K. A.; Ovanesyan, N. S.; Shteinman, A. A. Journal of Catalysis, Vol. 207, Issue 2 https://doi.org/10.1006/jcat.2002.3552	journal	April 2002
The role of NO2 in the selective catalytic reduction of nitrogen oxides over Fe-ZSM-5 catalysts: Active sites for the conversion of NO and of NO/NO2 mixtures Schwidder, M.; Heikens, S.; Detoni, A. Journal of Catalysis, Vol. 259, Issue 1 https://doi.org/10.1016/j.jcat.2008.07.014	journal	October 2008
Confirmation of Isolated Cu ²⁺ Ions in SSZ-13 Zeolite as Active Sites in NH ₃ -Selective Catalytic Reduction Deka, Upakul; Juhin, Amélie; Eilertsen, Einar A. The Journal of Physical Chemistry C, Vol. 116, Issue 7 https://doi.org/10.1021/jp212450d	journal	February 2012
Adsorption and reactivity of nitrogen oxides (NO2, NO, N2O) on Fe–zeolites Rivallan, Mickaël; Ricchiardi, Gabriele; Bordiga, Silvia Journal of Catalysis, Vol. 264, Issue 2 https://doi.org/10.1016/j.jcat.2009.03.012	journal	June 2009
Characterization of Cu-SSZ-13 NH3 SCR catalysts: an in situ FTIR study Szanyi, János; Kwak, Ja Hun; Zhu, Haiyang Physical Chemistry Chemical Physics, Vol. 15, Issue 7 https://doi.org/10.1039/c2cp43467a	journal	January 2013
Pertechnetate (TcO4−) reduction by reactive ferrous iron forms in naturally anoxic, redox transition zone sediments from the Hanford Site, USA Peretyazhko, T. S.; Zachara, J. M.; Kukkadapu, R. K. Geochimica et Cosmochimica Acta, Vol. 92 https://doi.org/10.1016/j.gca.2012.05.041	journal	September 2012
Dehydration and adsorbate interactions of iron-yttrium zeolite by Moessbauer spectroscopy Delgass, W. Nicholas; Garten, Robert L.; Boudart, Michel The Journal of Physical Chemistry, Vol. 73, Issue 9 https://doi.org/10.1021/j100843a033	journal	September 1969

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