Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN 3 -Ru Pincer Complex

Min, Shixiong; Rasul, Shahid; Li, Huaifeng; Grills, David C.; Takanabe, Kazuhiro; Li, Lain-Jong; Huang, Kuo-Wei

doi:10.1002/cplu.201500474

Title: Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN ³ -Ru Pincer Complex

Journal Article · Fri Nov 13 00:00:00 EST 2015 · ChemPlusChem

DOI:https://doi.org/10.1002/cplu.201500474· OSTI ID:1248808

Min, Shixiong ^[1]; Rasul, Shahid ^[2]; Li, Huaifeng ^[2]; Grills, David C. ^[3]; Takanabe, Kazuhiro ^[2]; Li, Lain-Jong ^[2]; Huang, Kuo-Wei ^[2]

King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia); Beifang Univ. of Nationalities, Ningxia (Republic of China)
King Abdullah Univ. of Science and Technology, Thuwal (Saudi Arabia)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Abstract A well‐defined PN ³ −Ru pincer complex ( 5 ) bearing a redox‐active bipyridine ligand with an aminophosphine arm has been established as an effective and stable molecular electrocatalyst for CO ₂ reduction to CO and HCOOH with negligible formation of H ₂ in a H ₂ O/MeCN mixture.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704

OSTI ID:: 1248808

Alternate ID(s):: OSTI ID: 1400727

Report Number(s):: BNL-112076-2016-JA; R&D Project: CO026; KC0304030

Journal Information:: ChemPlusChem, Vol. 81, Issue 2; ISSN 2192-6506

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 18 works

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Effect of PDI ligand binding pattern on the electrocatalytic activity of two Ru(II) complexes for CO ₂ reduction Shi, Ning‐ning; Xie, Wang‐jing; Gao, Wei‐song Applied Organometallic Chemistry, Vol. 34, Issue 4 https://doi.org/10.1002/aoc.5551	journal	February 2020
Solvent and Ligand Substitution Effects on the Electrocatalytic Reduction of CO ₂ with [Mo(CO) ₄ ( x,x ′-dimethyl-2,2′-bipyridine)] ( x =4-6) Enhanced at a Gold Cathodic Surface Taylor, James O.; Leavey, Roisín D.; Hartl, František ChemElectroChem, Vol. 5, Issue 21 https://doi.org/10.1002/celc.201800879	journal	August 2018
Visible‐Light Photocatalytic Reduction of CO ₂ to Formic Acid with a Ru Catalyst Supported by N , N ′‐Bis(diphenylphosphino)‐2,6‐diaminopyridine Ligands Hameed, Yasmeen; Rao, Gyandshwar Kumar; Ovens, Jeffrey S. ChemSusChem https://doi.org/10.1002/cssc.201901326	journal	July 2019
Extending the Second-Generation Phosphorus-Nitrogen PN ³ -Pincer Ligand Family through Ligand Post-Modification : Extending the 2nd Generation PN3-Pincer Ligand Huang, Mei-Hui; Hu, Jinsong; Huang, Kuo-Wei Journal of the Chinese Chemical Society, Vol. 65, Issue 1 https://doi.org/10.1002/jccs.201700205	journal	October 2017

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
electrocatalysts
electrochemistry
N
P ligands
redox
ruthenium

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Title: Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN ³ -Ru Pincer Complex