Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO3 Perovskites

Petrie, Jonathan R.; Cooper, Valentino R.; Freeland, John W.; Meyer, Tricia L.; Zhang, Zhiyong; Lutterman, Daniel A.; Lee, Ho Nyung

doi:10.1021/jacs.5b11713

Title: Enhanced Bifunctional Oxygen Catalysis in Strained LaNiO₃ Perovskites

Journal Article · Thu Feb 11 00:00:00 EST 2016 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b11713· OSTI ID:1247935

Petrie, Jonathan R. ^[1]; Cooper, Valentino R. ^[1]; Freeland, John W. ^[2]; Meyer, Tricia L. ^[1]; Zhang, Zhiyong ^[3]; Lutterman, Daniel A. ^[3]; Lee, Ho Nyung ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

Strain is known to greatly influence low-temperature oxygen electrocatalysis on noble metal films, leading to significant enhancements in bifunctional activity essential for fuel cells and metal-air batteries. Still, its catalytic impact on transition-metal oxide thin films, such as perovskites, is not widely understood. Here, we epitaxially strain the conducting perovskite LaNiO₃ to systematically determine its influence on both the oxygen reduction and oxygen evolution reaction. Uniquely, we found that compressive strain could significantly enhance both reactions, yielding a bifunctional catalyst that surpasses the performance of noble metals such as Pt. We attribute the improved bifunctionality to strain-induced splitting of the e_g orbitals, which can customize orbital asymmetry at the surface. Lastly, analogous to strain-induced shifts in the d-band center of noble metals relative to the Fermi level, such splitting can dramatically affect catalytic activity in this perovskite and other potentially more active oxides.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

OSTI ID:: 1247935

Journal Information:: Journal of the American Chemical Society, Vol. 138, Issue 8; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 255 works

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Single‐Crystal Cobalt Phosphate Nanosheets for Biomimetic Oxygen Evolution in Neutral Electrolytes Shao, Yue; Xiao, Xue; Zhu, Yun‐Pei Angewandte Chemie International Edition, Vol. 58, Issue 41 https://doi.org/10.1002/anie.201909326	journal	September 2019
Electronic parameters in cobalt-based perovskite-type oxides as descriptors for chemocatalytic reactions Simböck, Johannes; Ghiasi, M.; Schönebaum, Simon RWTH Aachen University https://doi.org/10.18154/rwth-2020-03978	text	January 2020
Low‐Coordinate Iridium Oxide Confined on Graphitic Carbon Nitride for Highly Efficient Oxygen Evolution Chen, Jiayi; Cui, Peixin; Zhao, Guoqiang Angewandte Chemie International Edition, Vol. 58, Issue 36 https://doi.org/10.1002/anie.201907017	journal	September 2019
Dynamic Tuning of a Thin Film Electrocatalyst by Tensile Strain Benson, Eric E.; Ha, Mai-Anh; Gregg, Brian. A. Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-52245-y	journal	November 2019
Sr, Fe Co-doped Perovskite Oxides With High Performance for Oxygen Evolution Reaction Guo, Qiang; Li, Xiang; Wei, Haifei Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00224	journal	April 2019

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