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Title: High-energy X-ray diffuse scattering studies on deformation-induced spatially confined martensitic transformations in multifunctional Ti-24Nb-4Zr-8Sn alloy

Abstract

Two main explanations exist for the deformation mechanisms in Ti-Nb-based gum metals, i.e. the formation of reversible nanodisturbance and reversible stress-induced martensitic transformation. In this work, we used the in situ synchrotron-based high-energy X-ray diffuse-scattering technique to reveal the existence of a specific deformation mechanism, i.e. deformation-induced spatially confined martensitic transformations, in Ti-24Nb-4Zr-8Sn-0.10O single crystals with cubic 13 parent phase, which explains well some anomalous mechanical properties of the alloy such as low elastic modulus and nonlinear superelasticity. Two kinds of nanosized martensites with different crystal structures were found during uniaxial tensile loading along the [11 0](beta) axis at room temperature and 190 K, respectively. The detailed changes in the martensitic phase transformation characteristics and the transformation kinetics were experimentally observed at different temperatures. The domain switch from non-modulated martensite to a modulated one occurred at 190 K, with its physical origin attributed to the heterogeneity of local phonon softening depending on temperature and inhomogeneous composition in the parent phase. An in-depth understanding of the formation of stress-induced spatially confined nanosized martensites with a large gradient in chemical composition may benefit designs of high-strength and high-ductility alloys. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Authors:
; ; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Basic Research Program of China; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities; USDOE Office of Science - Office of Basic Energy Sciences - Scientific User Facilities Division
OSTI Identifier:
1247720
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Acta Materialia
Additional Journal Information:
Journal Volume: 81; Journal ID: ISSN 1359-6454
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
martensitic transformation; nanodomains; nonlinear superelastic behavior; synchrotron diffraction; titanium alloys

Citation Formats

Liu, J. P., Wang, Y. D., Hao, Y. L., Wang, H. L., Wang, Y., Nie, Z. H., Su, R., Wang, D., Ren, Y., Lu, Z. P., Wang, J. G., Hui, X. D., and Yang, R. High-energy X-ray diffuse scattering studies on deformation-induced spatially confined martensitic transformations in multifunctional Ti-24Nb-4Zr-8Sn alloy. United States: N. p., 2014. Web. doi:10.1016/j.actamat.2014.08.019.
Liu, J. P., Wang, Y. D., Hao, Y. L., Wang, H. L., Wang, Y., Nie, Z. H., Su, R., Wang, D., Ren, Y., Lu, Z. P., Wang, J. G., Hui, X. D., & Yang, R. High-energy X-ray diffuse scattering studies on deformation-induced spatially confined martensitic transformations in multifunctional Ti-24Nb-4Zr-8Sn alloy. United States. https://doi.org/10.1016/j.actamat.2014.08.019
Liu, J. P., Wang, Y. D., Hao, Y. L., Wang, H. L., Wang, Y., Nie, Z. H., Su, R., Wang, D., Ren, Y., Lu, Z. P., Wang, J. G., Hui, X. D., and Yang, R. 2014. "High-energy X-ray diffuse scattering studies on deformation-induced spatially confined martensitic transformations in multifunctional Ti-24Nb-4Zr-8Sn alloy". United States. https://doi.org/10.1016/j.actamat.2014.08.019.
@article{osti_1247720,
title = {High-energy X-ray diffuse scattering studies on deformation-induced spatially confined martensitic transformations in multifunctional Ti-24Nb-4Zr-8Sn alloy},
author = {Liu, J. P. and Wang, Y. D. and Hao, Y. L. and Wang, H. L. and Wang, Y. and Nie, Z. H. and Su, R. and Wang, D. and Ren, Y. and Lu, Z. P. and Wang, J. G. and Hui, X. D. and Yang, R.},
abstractNote = {Two main explanations exist for the deformation mechanisms in Ti-Nb-based gum metals, i.e. the formation of reversible nanodisturbance and reversible stress-induced martensitic transformation. In this work, we used the in situ synchrotron-based high-energy X-ray diffuse-scattering technique to reveal the existence of a specific deformation mechanism, i.e. deformation-induced spatially confined martensitic transformations, in Ti-24Nb-4Zr-8Sn-0.10O single crystals with cubic 13 parent phase, which explains well some anomalous mechanical properties of the alloy such as low elastic modulus and nonlinear superelasticity. Two kinds of nanosized martensites with different crystal structures were found during uniaxial tensile loading along the [11 0](beta) axis at room temperature and 190 K, respectively. The detailed changes in the martensitic phase transformation characteristics and the transformation kinetics were experimentally observed at different temperatures. The domain switch from non-modulated martensite to a modulated one occurred at 190 K, with its physical origin attributed to the heterogeneity of local phonon softening depending on temperature and inhomogeneous composition in the parent phase. An in-depth understanding of the formation of stress-induced spatially confined nanosized martensites with a large gradient in chemical composition may benefit designs of high-strength and high-ductility alloys. (C) 2014 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.},
doi = {10.1016/j.actamat.2014.08.019},
url = {https://www.osti.gov/biblio/1247720}, journal = {Acta Materialia},
issn = {1359-6454},
number = ,
volume = 81,
place = {United States},
year = {Mon Dec 01 00:00:00 EST 2014},
month = {Mon Dec 01 00:00:00 EST 2014}
}