Oxidation of alloys for energy applications in supercritical CO2 and H2O

Holcomb, Gordon R.; Carney, Casey; Doğan, Ömer N.

doi:10.1016/j.corsci.2016.03.018

Title: Oxidation of alloys for energy applications in supercritical CO₂ and H₂O

Journal Article · Sat Mar 19 00:00:00 EDT 2016 · Corrosion Science

DOI:https://doi.org/10.1016/j.corsci.2016.03.018· OSTI ID:1247687

Holcomb, Gordon R. ^[1]; Carney, Casey ^[2]; Doğan, Ömer N. ^[1]

National Energy Technology Lab. (NETL), Albany, OR (United States)
National Energy Technology Lab. (NETL), Albany, OR (United States); AECOM, Albany, OR (United States)

To facilitate development of supercritical CO₂ (sCO₂) power plants, a comparison of the oxidation behavior of austenitic stainless steels and Ni-base alloys in sH₂O and sCO₂ were made. Experiments were conducted at 730 °C/207 bar (sCO₂) and 726 °C/208 bar (sH₂O). Ni-base alloys in sCO₂ did not exhibit much change with pressure. Ni-base alloys in sH₂O had an increase in corrosion rate and the log of the parabolic rate constant was proportional to pressure. Lastly, fine-grain austenitic stainless steels in sCO₂ and sH₂O were both less protective with pressure as the dense protective chromia scale was replaced with faster growing Fe-oxide rich scales.

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Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Organization:: USDOE

OSTI ID:: 1247687

Report Number(s):: NETL-PUB-20231; PII: S0010938X16301184

Journal Information:: Corrosion Science, Vol. 109, Issue C; ISSN 0010-938X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 64 works

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Effect of 730 °C Supercritical Fluid Exposure on the Fatigue Threshold of Ni-Based Superalloy Haynes 282 Rozman, K. A.; Holcomb, G. R.; Carney, C. S. Journal of Materials Engineering and Performance, Vol. 28, Issue 7 https://doi.org/10.1007/s11665-019-04164-2	journal	June 2019
High-temperature corrosion resistance of nickel-base alloy 617 in supercritical carbon dioxide environment Liang, Zhiyuan; Gui, Yong; Zhao, Qinxin Materials Research Express, Vol. 7, Issue 1 https://doi.org/10.1088/2053-1591/ab6388	journal	January 2020
Effect of high-temperature supercritical carbon dioxide exposure on the microstructure and tensile properties of diffusion-bonded Alloy 690 Chen, Hongsheng; Kim, Sung Hwan; Jang, Changheui Journal of Materials Science, Vol. 55, Issue 8 https://doi.org/10.1007/s10853-019-04222-z	journal	November 2019
Hydrogen transport during steam oxidation of iron and nickel alloys Holcomb, Gordon R.; Lukaszewicz, Mikolaj; Simms, Nigel J. Materials at High Temperatures https://doi.org/10.1080/09603409.2019.1582199	journal	March 2019
Effect of Surface Finish on High-Temperature Oxidation of Steels in CO2, Supercritical CO2, and Air Oleksak, Richard P.; Holcomb, Gordon R.; Carney, Casey S. Oxidation of Metals, Vol. 92, Issue 5-6 https://doi.org/10.1007/s11085-019-09938-6	journal	October 2019
High-Temperature Oxidation of Commercial Alloys in Supercritical CO2 and Related Power Cycle Environments Oleksak, Richard P.; Tylczak, Joseph H.; Carney, Casey S. JOM, Vol. 70, Issue 8 https://doi.org/10.1007/s11837-018-2952-7	journal	June 2018
Numerical Analysis on Heat Transfer Characteristics of Supercritical CO2 in Heated Vertical Up-Flow Tube Yan, Chenshuai; Xu, Jinliang; Zhu, Bingguo Materials, Vol. 13, Issue 3 https://doi.org/10.3390/ma13030723	journal	February 2020

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