High pressure and temperature equation of state and spectroscopic study of CeO 2

Jacobsen, M. K.; Velisavljevic, N.; Dattelbaum, D. M.; Chellappa, R. S.; Park, C.

doi:10.1088/0953-8984/28/15/155401

Title: High pressure and temperature equation of state and spectroscopic study of CeO ₂

Journal Article · Thu Mar 17 00:00:00 EDT 2016 · Journal of Physics. Condensed Matter

DOI:https://doi.org/10.1088/0953-8984/28/15/155401· OSTI ID:1242313

Jacobsen, M. K.; Velisavljevic, N.; Dattelbaum, D. M.; Chellappa, R. S.; Park, C.

One of the most widely used x-ray standards and a highly applied component of catalysis systems, CeO2 has been studied for the purpose of better understanding its equation of state and electronic properties. Diamond anvil cells have been used to extend the equation of state for this material to 130 GPa and explore the electronic behavior with applied load. From the x-ray diffraction studies, it has been determined that the high pressure phase transition extends from approximately 35 to 75 GPa at ambient temperature. Elevation of temperature is found to decrease the initiation pressure for this transition, with multiple distinct temperature regions which indicate structural related anomalies. In addition, hydrostatic and non-hydrostatic effects are compared and exhibit a drastic difference in bulk moduli. The electronic results indicate a change in the scattering environment of the cerium atom, associated with the high pressure phase transition. Overall, these results present the first megabar pressure study and the first high pressure and temperature study of ceria. Additionally, this shows the first combined study of the K and LIII edges of this material to 33 GPa.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Carnegie Inst. of Science, Washington, DC (United States). Geophysical Lab.

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357; AC52-06NA25396; FG02-94ER14466; FG02-99ER45775; NA0001974; EAR1128799; EAR1157758; EAR 11-57758; EAR-1128799; NA0002006

OSTI ID:: 1242313

Alternate ID(s):: OSTI ID: 1242314; OSTI ID: 1247314; OSTI ID: 1379176

Report Number(s):: LA-UR-15-25295

Journal Information:: Journal of Physics. Condensed Matter, Journal Name: Journal of Physics. Condensed Matter Vol. 28 Journal Issue: 15; ISSN 0953-8984

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 8 works

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References (31)

Investigation of thermodynamic properties of cerium dioxide by statistical moment method Hung, Vu Van; Lee, Jaichan; Masuda-Jindo, K. Journal of Physics and Chemistry of Solids, Vol. 67, Issue 4 https://doi.org/10.1016/j.jpcs.2005.09.100	journal	April 2006
Raman study of ${CeO}_{2}$ : Second-order scattering, lattice dynamics, and particle-size effects Weber, W. H.; Hass, K. C.; McBride, J. R. Physical Review B, Vol. 48, Issue 1 https://doi.org/10.1103/PhysRevB.48.178	journal	July 1993
Many-body calculation for high energy spectra of insulating RE compounds Delley, B.; Beck, H. Journal of Magnetism and Magnetic Materials, Vol. 47-48 https://doi.org/10.1016/0304-8853(85)90412-3	journal	February 1985
High-pressure x-ray diffraction study of ${CeO}_{2}$ to 70 GPa and pressure-induced phase transformation from the fluorite structure Duclos, Steven J.; Vohra, Yogesh K.; Ruoff, Arthur L. Physical Review B, Vol. 38, Issue 11 https://doi.org/10.1103/PhysRevB.38.7755	journal	October 1988
Strength and equation of state of fluorite phase CeO ₂ under high pressure Liu, Lei; Song, Hong X.; Wang, Zhigang Journal of Applied Physics, Vol. 112, Issue 1 https://doi.org/10.1063/1.4736555	journal	July 2012
Ceria in automotive exhaust catalysts I. Oxygen storage Yao, H. Journal of Catalysis, Vol. 86, Issue 2 https://doi.org/10.1016/0021-9517(84)90371-3	journal	April 1984
Effective hydrostatic limits of pressure media for high-pressure crystallographic studies Angel, Ross J.; Bujak, Maciej; Zhao, Jing Journal of Applied Crystallography, Vol. 40, Issue 1 https://doi.org/10.1107/S0021889806045523	journal	January 2007
Pressure-induced transition in titanium metal a systematic study of the effects of uniaxial stress Errandonea, Daniel; Meng, Y.; Somayazulu, M. Physica B: Condensed Matter, Vol. 355, Issue 1-4, p. 116-125 https://doi.org/10.1016/j.physb.2004.10.030	journal	January 2005
CeO ₂ : An alternative insulator material for superconducting field effect devices Walkenhorst, A.; Schmitt, M.; Adrian, H. Applied Physics Letters, Vol. 64, Issue 14 https://doi.org/10.1063/1.111783	journal	April 1994
Resonant inelastic x-ray scattering at the Ce $L_{3}$ edge of ${CePO}_{4}$ and ${CeO}_{2}$ : Implications for the valence of ${CeO}_{2}$ and related phenomena Sham, T. K.; Gordon, R. A.; Heald, S. M. Physical Review B, Vol. 72, Issue 3 https://doi.org/10.1103/PhysRevB.72.035113	journal	July 2005
Crystal structure and the structural disorder of ceria from 40 to 1497 °C Yashima, Masatomo; Kobayashi, Syuuhei; Yasui, Tadashi Solid State Ionics, Vol. 177, Issue 3-4 https://doi.org/10.1016/j.ssi.2005.10.033	journal	January 2006
HPCAT: an integrated high-pressure synchrotron facility at the Advanced Photon Source Shen, Guoyin; Chow, Paul; Xiao, Yuming High Pressure Research, Vol. 28, Issue 3 https://doi.org/10.1080/08957950802208571	journal	September 2008
Finite Elastic Strain of Cubic Crystals Birch, Francis Physical Review, Vol. 71, Issue 11 https://doi.org/10.1103/PhysRev.71.809	journal	June 1947
New developments in micro-X-ray diffraction and X-ray absorption spectroscopy for high-pressure research at 16-BM-D at the Advanced Photon Source Park, Changyong; Popov, Dmitry; Ikuta, Daijo Review of Scientific Instruments, Vol. 86, Issue 7 https://doi.org/10.1063/1.4926893	journal	July 2015
Powder diffraction analysis of cerium dioxide at high pressure Gerward, L.; Olsen, J. Staun Powder Diffraction, Vol. 8, Issue 2 https://doi.org/10.1017/S0885715600017966	journal	June 1993
Redox response of actinide materials to highly ionizing radiation Tracy, Cameron L.; Lang, Maik; Pray, John M. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7133	journal	January 2015
Specific intermediate-valence state of insulating 4 f compounds detected by $L_{3}$ x-ray absorption Bianconi, A.; Marcelli, A.; Dexpert, H. Physical Review B, Vol. 35, Issue 2 https://doi.org/10.1103/PhysRevB.35.806	journal	January 1987
Catalytic Properties of Ceria and CeO ₂ -Containing Materials Trovarelli, Alessandro Catalysis Reviews, Vol. 38, Issue 4 https://doi.org/10.1080/01614949608006464	journal	November 1996
Bulk modulus of CeO2 and PrO2—An experimental and theoretical study Gerward, L.; Staun Olsen, J.; Petit, L. Journal of Alloys and Compounds, Vol. 400, Issue 1-2 https://doi.org/10.1016/j.jallcom.2005.04.008	journal	September 2005
Hydrostatic limits in liquids and solids to 100 kbar Piermarini, G. J.; Block, S.; Barnett, J. D. Journal of Applied Physics, Vol. 44, Issue 12 https://doi.org/10.1063/1.1662159	journal	December 1973
Equations of state of MgO, Au, Pt, NaCl-B1, and NaCl-B2: Internally consistent high-temperature pressure scales Dorogokupets, P. I.; Dewaele, A. High Pressure Research, Vol. 27, Issue 4 https://doi.org/10.1080/08957950701659700	journal	December 2007
Direct study of the f-electron configuration in lanthanide systems Kvashnina, Kristina O.; Butorin, Sergei M.; Glatzel, Pieter Journal of Analytical Atomic Spectrometry, Vol. 26, Issue 6 https://doi.org/10.1039/c0ja00142b	journal	January 2011
Experimental constraints on the phase diagram of elemental zirconium Zhang, Jianzhong; Zhao, Yusheng; Pantea, Cristian Journal of Physics and Chemistry of Solids, Vol. 66, Issue 7 https://doi.org/10.1016/j.jpcs.2005.03.004	journal	July 2005
Theory of core photoabsorption spectra in CeO2 Jo, T.; Kotani, A. Solid State Communications, Vol. 54, Issue 5 https://doi.org/10.1016/0038-1098(85)90948-2	journal	May 1985
Comment on “High-pressure x-ray diffraction study of YBO ₃ /Eu ³⁺ , GdBO ₃ , and EuBO ₃ : Pressure-induced amorphization in GdBO ₃ ” [J. Appl. Phys. 115 , 043507 (2014)] Errandonea, D.; Muñoz, A.; Gonzalez-Platas, J. Journal of Applied Physics, Vol. 115, Issue 21 https://doi.org/10.1063/1.4881057	journal	June 2014
A new method of directly determining the core–hole effect in the Ce L3 XAS of mixed valence Ce compounds—An application of resonant X-ray emission spectroscopy Kotani, A.; Kvashnina, K. O.; Butorin, S. M. Journal of Electron Spectroscopy and Related Phenomena, Vol. 184, Issue 3-6 https://doi.org/10.1016/j.elspec.2010.12.028	journal	April 2011
Pressure-induced changes in $L_{III}$ x-ray-absorption near-edge structure of Ce $O_{2}$ and Ce $F_{4}$ : Relevance to $4 f$ -electronic structure Kaindl, G.; Schmiester, G.; Sampathkumaran, E. V. Physical Review B, Vol. 38, Issue 14 https://doi.org/10.1103/PhysRevB.38.10174	journal	November 1988
Effects of interstitial impurities on the high pressure martensitic α to ω structural transformation and grain growth in zirconium Velisavljevic, Nenad; Chesnut, Gary N.; Stevens, Lewis L. Journal of Physics: Condensed Matter, Vol. 23, Issue 12 https://doi.org/10.1088/0953-8984/23/12/125402	journal	March 2011
Theoretical study of CeO2 and Ce2O3 using a screened hybrid density functional Hay, P. Jeffrey; Martin, Richard L.; Uddin, Jamal The Journal of Chemical Physics, Vol. 125, Issue 3 https://doi.org/10.1063/1.2206184	journal	July 2006
High-pressure Raman study of ${CeO}_{2}$ to 35 GPa and pressure-induced phase transformation from the fluorite structure Kourouklis, G. A.; Jayaraman, A.; Espinosa, G. P. Physical Review B, Vol. 37, Issue 8 https://doi.org/10.1103/PhysRevB.37.4250	journal	March 1988
Refinement of the ruby luminescence pressure scale Holzapfel, Wilfried B. Journal of Applied Physics, Vol. 93, Issue 3 https://doi.org/10.1063/1.1525856	journal	February 2003

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Title: High pressure and temperature equation of state and spectroscopic study of CeO 2

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Title: High pressure and temperature equation of state and spectroscopic study of CeO ₂