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Title: Characterization of the Electrical Properties of Individual Multi-Walled Carbon Nanotubes.


Abstract not provided.

; ; ;
Publication Date:
Research Org.:
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA)
OSTI Identifier:
Report Number(s):
DOE Contract Number:
Resource Type:
Resource Relation:
Conference: Proposed for presentation at the SPIE Smart Structures/NDE held March 9-12, 2015 in San Diego, CA.
Country of Publication:
United States

Citation Formats

Loyola, Bryan, Friddle, Raymond William, Krafcik, Karen Lee, and Sahlin, Kevin. Characterization of the Electrical Properties of Individual Multi-Walled Carbon Nanotubes.. United States: N. p., 2015. Web.
Loyola, Bryan, Friddle, Raymond William, Krafcik, Karen Lee, & Sahlin, Kevin. Characterization of the Electrical Properties of Individual Multi-Walled Carbon Nanotubes.. United States.
Loyola, Bryan, Friddle, Raymond William, Krafcik, Karen Lee, and Sahlin, Kevin. 2015. "Characterization of the Electrical Properties of Individual Multi-Walled Carbon Nanotubes.". United States. doi:.
title = {Characterization of the Electrical Properties of Individual Multi-Walled Carbon Nanotubes.},
author = {Loyola, Bryan and Friddle, Raymond William and Krafcik, Karen Lee and Sahlin, Kevin},
abstractNote = {Abstract not provided.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = 2015,
month = 3

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  • Highlights: ► Impurities in crude MWNTs were effectively removed after purification treatment. ► Many Ni nanoparticles were homogenously coated on the purified MWNTs. ► The saturation magnetization (Ms) of the MWNTs with Ni–P layers is 91.5 emu/g. -- Abstract: The multi-wall carbon nanotubes (MWNTs) with nickel–phosphorous (Ni–P) layers were prepared by electroless plating method. To obtain the MWNTs with Ni–P layers of high magnetic properties, an effective purification treatment and a pre-treatment procedure were developed. The crude MWNTs, the purified MWNTs and the MWNTs with Ni–P layers were characterized by scanning electron microscope (SEM)/energy dispersive spectroscopy (EDS), transmission electron microscopemore » (TEM), X-ray diffraction (XRD) and vibrating sample magnetometer (VSM). SEM results, TEM images and XRD results indicate that impurities in the crude MWNTs were effectively removed after the purification treatment and a large number of Ni nanoparticles were homogenously coated on the surface of the purified MWNTs. According to the VSM test, the saturation magnetization (Ms) of the MWNTs with Ni–P layers is 91.5 emu/g which is higher than results of other researchers.« less
  • The electronic structure of individual multi-walled carbon nanotubes (MWCNTs) has been probed using scanning transmission X-ray microscopy (STXM). Although transmission electron microscope (TEM) images show that the exterior of the MWCNTs are clean and straight; the inside structure of some of the MWCNTs is much less well ordered, as revealed by STXM. The amorphization of the interior tubes can be introduced in the growth or modification processes. Moreover, TEM measurement with high dose may also lead to the inside damage. Our results reveal that the structure of individual MWCNTs can be complex and suggest that electronic structure measurements are anmore » important tool for characterizing carbon nanomaterials.« less
  • Carbon aerogels (CAs) are novel mesoporous materials with applications such as electrode materials for super capacitors and rechargeable batteries, adsorbents and advanced catalyst supports. To expand the potential application for these unique materials, recent efforts have focused on the design of CA composites with the goal of modifying the structure, conductivity or catalytic activity of the aerogel. Carbon nanotubes (CNTs) possess a number of intrinsic properties that make them promising materials in the design of composite materials. In addition, the large aspect ratios (100-1000) of CNTs means that small additions (less than 1 vol%) of CNTs can produce a compositemore » with novel properties. Therefore, the homogeneous incorporation of CNTs into a CA matrix provides a viable route to new carbon-based composites with enhanced thermal, electrical and mechanical properties. One of the main challenges in preparing CNT composites is achieving a good uniform dispersion of nanotubes throughout the matrix. CAs are typically prepared through the sol-gel polymerization of resorcinol with formaldehyde in aqueous solution to produce organic gels that are supercritically dried and subsequently pyrolyzed in an inert atmosphere. Therefore, a significant issue in fabricating CA-CNT composites is dispersing the CNTs in the aqueous reaction media. Previous work in the design of CACNT composites have addressed this issue by using organic solvents in the sol-gel reaction to facilitate dispersion of the CNTs. To our knowledge, no data has been published involving the preparation of CA composites containing CNTs dispersed in aqueous media. In this report, we describe a new method for the synthesis of monolithic CA-CNT composites that involves the sol-gel polymerization of resorcinol and formaldehyde in an aqueous solution containing a surfactant-stabilized dispersion of double-walled carbon nanotubes (DWNT). One of the advantages of this approach is that it allows one to uniformly distribute CNTs in the CA matrix without compromising the synthetic control that is afforded by traditional organic sol-gel chemistry over the CA structure. We will describe the physical characterization of these novel materials as well as the influence of DWNT loading on the electrical conductivity of the CA composite.« less
  • Carbon nanotubes (CNT) have a wide variety of interesting properties and a large number of potential aplications in electronic and optical devices. In this study we concentrate on one important aspect of their electronic stucture: the plasmon dispersions in both single- and multi-wall CNTs and their relation to those in graphite. For the first time inelastic X-ray scattering is used to study these collective electronic excitations in oriented CNT samples. The experiments were performed on the IXS instrument at beamline 9ID CMC-XOR, APS, ANL. The incident energy was defined by a Si(333) monochromator, a spherically bent Ge(733) diced analyzer atmore » the end of a 1-m arm focused the incident radiation onto a solid-state detector. The overall resolution was {approx}300 meV FWHM. The incident photons were linearly polarized perpendicular to the scattering plane. Energy loss scans were taken by varying the incident energy while keeping the exit energy fixed at 8.9805 keV. The momentum transfer was kept along the nanotubes axis. Spectra were taken at room temperature. The samples were oriented CNTs (both single- and multi-wall) grown on a Si substrate. The samples referred to as 'single-wall' were in fact a few walls at most (1-5) while the multi-walled ones had {approx}12 walls. Fig. 1. shows the inelastic spectra for the single-, multi-wall, and highly oriented pyrolithic graphite (HOPG) from top to bottom. Momentum transfer was Q = 0.79 {angstrom}{sup -1} in all cases, its direction was along the tubes for the first two samples or parallel to the sheets for graphite. The peaks at {approx}10 and {approx}30 eV are known as the {pi} and {sigma} + {pi} plasmons respectively. Fig. 2. shows the complete dispersion curves for both plasmon modes as a function of momentum transfer for all three samples.« less
  • Abstract not provided.