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Aromatization or dehydrocyclization of N-alkanes using soluble transition metal complexes

Patent ·
OSTI ID:1245597
; ;

The invention provides methods and compositions useful for synthesizing alkylaromatics from an n-alkanes.

Research Organization:
Rutgers, The State Univ. of New Jersey, New Brunswick, NJ (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG02-93ER14353
Assignee:
Rutgers, The State University of New Jersey (New Brunswick, NJ)
Patent Number(s):
9,302,954
Application Number:
13/657,723
OSTI ID:
1245597
Country of Publication:
United States
Language:
English

References (11)

Membrane reactors for hydrogenation and dehydrogenation processes based on supported palladium journal September 2001
Periphery-functionalized organometallic dendrimers for homogeneous catalysis journal October 1999
Hydrogen Storage in Microporous Metal-Organic Frameworks journal May 2003
Highly Effective Pincer-Ligated Iridium Catalysts for Alkane Dehydrogenation. DFT Calculations of Relevant Thermodynamic, Kinetic, and Spectroscopic Properties journal October 2004
Comparative studies of dehydrocyclization of n-octane and iso-octane on bifunctional and monofunctional Pt/Al2O3 catalysts journal February 1993
Thermodynamic Properties for Solution of Hydrogen in Palladium-Based Binary Alloys journal June 1995
Water-Tolerant Solid Acid Catalysts journal October 2002
Ligand exchanges and selective catalytic hydrogenation in molecular single crystals journal June 2010
Catalytic asymmetric Diels Alder reactions journal July 1992
Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes journal December 2010
Thermally Stable Homogeneous Catalysts for Alkane Dehydrogenation S.O. thanks the German Academic Exchange Service (DAAD) for financing a research stay with W.C.K. in the USA. This work was supported by the National Science Foundation (CHE 9800184 to M.B.H.), by the University of California Energy Institute and University of California Santa Barbara (to W.C.K.), and by the German Research Association (DFG, to M.W.H). We thank Dr. R. Mynott and Mrs. C. Wirtz, MPI für Kohlenforschung, for NMR spectroscopic investigations. journal October 2001

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