Investigation of LaxSr1-xCoyM1-yO3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media

Babiniec, Sean Michael; Coker, Eric Nicholas; Miller, James E.; Ambrosini, Andrea

doi:10.1016/j.solener.2015.05.040

Title: Investigation of La_xSr_1-xCo_yM_1-yO_3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media

Journal Article · Tue Jun 23 00:00:00 EDT 2015 · Solar Energy

DOI:https://doi.org/10.1016/j.solener.2015.05.040· OSTI ID:1235322

Babiniec, Sean Michael ^[1]; Coker, Eric Nicholas ^[1]; Miller, James E. ^[1]; Ambrosini, Andrea ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Materials in the La_xSr_1–xCo_yMn_1–yO_3–δ (LSCM) and La_xSr_1–xCo_yFe_1–yO_3–δ (LSCF) families are candidates for high-temperature thermochemical energy storage due to their facility for cyclic endothermic reduction and exothermic oxidation. A set of 16 LSCM and 21 LSCF compositions were synthesized by a modified Pechini method and characterized by powder X-ray diffraction and thermogravimetric analysis. All materials were found to be various symmetries of the perovskite phase. LSCM was indexed as tetragonal, cubic, rhombohedral, or orthorhombic as a function of increased lanthanum content. For LSCF, compositions containing low lanthanum content were indexed as cubic while materials with high lanthanum content were indexed as rhombohedral. An initial screening of redox activity was completed by thermogravimetric analysis for each composition. The top three compositions with the greatest recoverable redox capacity for each family were further characterized in equilibrium thermogravimetric experiments over a range of temperatures and oxygen partial pressures. As a result, these equilibrium experiments allowed the extraction of thermodynamic parameters for LSCM and LSCF compositions operated in thermochemical energy storage conditions.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office

Grant/Contract Number:: AC04-94AL85000; FOA-0000805

OSTI ID:: 1235322

Alternate ID(s):: OSTI ID: 1237378; OSTI ID: 1245221

Report Number(s):: SAND-2015-4972J; SAND-2015-1455J; 594399

Journal Information:: Solar Energy, Vol. 118, Issue C; ISSN 0038-092X

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 100 works

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References (26)

Exploitation of thermochemical cycles based on solid oxide redox systems for thermochemical storage of solar heat. Part 1: Testing of cobalt oxide-based powders Agrafiotis, Christos; Roeb, Martin; Schmücker, Martin Solar Energy, Vol. 102 https://doi.org/10.1016/j.solener.2013.12.032	journal	April 2014
Synthesis and characterization of the double-substituted perovskites LaxSr1−xCo1−yMnyO3−δ for use in high-temperature oxygen separations Ambrosini, A.; Garino, T.; Nenoff, T. Solid State Ionics, Vol. 177, Issue 26-32 https://doi.org/10.1016/j.ssi.2006.05.023	journal	October 2006
The cobalt-oxide/iron-oxide binary system for use as high temperature thermochemical energy storage material Block, Tina; Knoblauch, Nicole; Schmücker, Martin Thermochimica Acta, Vol. 577 https://doi.org/10.1016/j.tca.2013.11.025	journal	February 2014
Thermochemical energy storage at high temperature via redox cycles of Mn and Co oxides: Pure oxides versus mixed ones Carrillo, Alfonso J.; Moya, Javier; Bayón, Alicia Solar Energy Materials and Solar Cells, Vol. 123 https://doi.org/10.1016/j.solmat.2013.12.018	journal	April 2014
Nano-structured (La, Sr)(Co, Fe)O3+YSZ composite cathodes for intermediate temperature solid oxide fuel cells Chen, Jing; Liang, Fengli; Liu, Lina Journal of Power Sources, Vol. 183, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.05.082	journal	September 2008
Oxygen transport in La1−xSrxMn1−yCoyO3±δ perovskites Part I. Oxygen tracer diffusion De Souza, R. Solid State Ionics, Vol. 106, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00499-2	journal	February 1998
Development of Solid-Oxide Fuel Cells That Operate at 500°C Doshi, Rajiv Journal of The Electrochemical Society, Vol. 146, Issue 4 https://doi.org/10.1149/1.1391758	journal	January 1999
Kinetic and thermodynamic considerations for oxygen absorption/desorption using cobalt oxide Hutchings, K.; Wilson, M.; Larsen, P. Solid State Ionics, Vol. 177, Issue 1-2 https://doi.org/10.1016/j.ssi.2005.10.005	journal	January 2006
A comparison of O2 reduction reactions on porous (La,Sr)MnO3 and (La,Sr)(Co,Fe)O3 electrodes Jiang, S. Solid State Ionics, Vol. 146, Issue 1-2 https://doi.org/10.1016/S0167-2738(01)00997-3	journal	January 2002
Effect of A-site lanthanum doping on the CO2 tolerance of SrCo0.8Fe0.2O3−-δ oxygen-transporting membranes Klande, Tobias; Ravkina, Olga; Feldhoff, Armin Journal of Membrane Science, Vol. 437 https://doi.org/10.1016/j.memsci.2013.02.051	journal	June 2013
Perovskite-type Sr(Mn1−xNix)O3 materials and their chemical-looping oxygen transfer properties Ksepko, Ewelina International Journal of Hydrogen Energy, Vol. 39, Issue 15 https://doi.org/10.1016/j.ijhydene.2014.03.093	journal	May 2014
Considerations in the Design of Materials for Solar-Driven Fuel Production Using Metal-Oxide Thermochemical Cycles Miller, James E.; McDaniel, Anthony H.; Allendorf, Mark D. Advanced Energy Materials, Vol. 4, Issue 2, Article No. 1300469 https://doi.org/10.1002/aenm.201300469	journal	October 2013
Nonstoichiometry and thermochemical stability of the perovskite-type La1−xSrxMnO3−δ Mizusaki, J. Solid State Ionics, Vol. 49 https://doi.org/10.1016/0167-2738(91)90076-N	journal	December 1991
A kinetic study of the decomposition of the cubic perovskite-type oxide BaxSr1−xCo0.8Fe0.2O3−δ (BSCF) (x = 0.1 and 0.5) Mueller, David N.; De Souza, Roger A.; Weirich, Thomas E. Physical Chemistry Chemical Physics, Vol. 12, Issue 35 https://doi.org/10.1039/c0cp00004c	journal	January 2010
Morphology control of La(Sr)Fe(Co)O3−a cathodes for IT-SOFCs Murata, Kenji; Fukui, Takehisa; Abe, Hiroya Journal of Power Sources, Vol. 145, Issue 2 https://doi.org/10.1016/j.jpowsour.2004.12.063	journal	August 2005
A review on high temperature thermochemical heat energy storage Pardo, P.; Deydier, A.; Anxionnaz-Minvielle, Z. Renewable and Sustainable Energy Reviews, Vol. 32 https://doi.org/10.1016/j.rser.2013.12.014	journal	April 2014
Chemical Structures and Performance of Perovskite Oxides Pena, M.; Fierro, J. Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018 https://doi.org/10.1021/cr980129f	journal	July 2001
Oxygen non-stoichiometry, redox thermodynamics, and structure of LaFe1 − x Co x O3 − δ Pishahang, Mehdi; Bakken, Egil; Stølen, Svein Ionics, Vol. 19, Issue 6 https://doi.org/10.1007/s11581-012-0811-z	journal	October 2012
Reactivity of LSCF perovskites Scott, S. Solid State Ionics, Vol. 152-153 https://doi.org/10.1016/S0167-2738(02)00327-2	journal	December 2002
Technical Challenges and Opportunities for Concentrating Solar Power With Thermal Energy Storage Stekli, Joseph; Irwin, Levi; Pitchumani, Ranga Journal of Thermal Science and Engineering Applications, Vol. 5, Issue 2 https://doi.org/10.1115/1.4024143	journal	May 2013
Electrochemical Properties of Mixed Conducting Perovskites La[sub 1−x]M[sub x]Co[sub 1−y]Fe[sub y]O[sub 3−δ] (M = Sr, Ba, Ca) Stevenson, J. W. Journal of The Electrochemical Society, Vol. 143, Issue 9 https://doi.org/10.1149/1.1837098	journal	January 1996
The reduction and oxidation behaviour of manganese oxides Stobbe, E. R.; de Boer, B. A.; Geus, J. W. Catalysis Today, Vol. 47, Issue 1-4 https://doi.org/10.1016/S0920-5861(98)00296-X	journal	January 1999
Thermochemical Stability, Electrical Conductivity, and Seebeck Coefficient of Sr-Doped LaCo0.2Fe0.8O3-δ Tai, L-W.; Nasrallah, M. M.; Anderson, H. U. Journal of Solid State Chemistry, Vol. 118, Issue 1 https://doi.org/10.1006/jssc.1995.1319	journal	August 1995
Thermochemical Solar Energy Storage Via Redox Oxides: Materials and Reactor/Heat Exchanger Concepts Tescari, S.; Agrafiotis, C.; Breuer, S. Energy Procedia, Vol. 49 https://doi.org/10.1016/j.egypro.2014.03.111	journal	January 2014
High-performance lanthanum-ferrite-based cathode for SOFC Wang, W.; Mogensen, M. Solid State Ionics, Vol. 176, Issue 5-6 https://doi.org/10.1016/j.ssi.2004.09.007	journal	February 2005
Experimental study on optimized composition of mixed carbonate salt for sensible heat storage in solar thermal power plant Wu, Yu-ting; Ren, Nan; Wang, Tao Solar Energy, Vol. 85, Issue 9 https://doi.org/10.1016/j.solener.2011.05.004	journal	September 2011

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Progress in thermochemical energy storage for concentrated solar power: A review Liu, Dai; Xin-Feng, Long; Bo, Lou International Journal of Energy Research, Vol. 42, Issue 15 https://doi.org/10.1002/er.4183	journal	August 2018
Thermodynamic and mechanism study of syngas production via integration of nitrous oxide decomposition and methane partial oxidation in the presence of 10%NiO–La0.3Sr0.7Co0.7Fe0.3O3−δ Khajonvittayakul, C.; Tongnan, V.; Kangsadan, T. Reaction Kinetics, Mechanisms and Catalysis, Vol. 127, Issue 2 https://doi.org/10.1007/s11144-019-01600-1	journal	June 2019

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Title: Investigation of LaxSr1-xCoyM1-yO3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media

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Title: Investigation of La_xSr_1-xCo_yM_1-yO_3-δ (M = Mn Fe) perovskite materials as thermochemical energy storage media