Large magnetic entropy change and magnetoresistance in a Ni41Co9Mn40Sn10 magnetic shape memory alloy

Huang, L.; Cong, D. Y.; Ma, L.; Nie, Z. H.; Wang, M. G.; Wang, Z. L.; Suo, H. L.; Ren, Y.; Wang, Y. D.

doi:10.1016/j.jallcom.2015.06.175

Title: Large magnetic entropy change and magnetoresistance in a Ni₄₁Co₉Mn₄₀Sn₁₀ magnetic shape memory alloy

Journal Article · Thu Jul 02 00:00:00 EDT 2015 · Journal of Alloys and Compounds

DOI:https://doi.org/10.1016/j.jallcom.2015.06.175· OSTI ID:1245146

Huang, L. ^[1]; Cong, D. Y. ^[2]; Ma, L. ^[3]; Nie, Z. H. ^[4]; Wang, M. G. ^[5]; Wang, Z. L. ^[4]; Suo, H. L. ^[3]; Ren, Y. ^[6]; Wang, Y. D. ^[2]

Univ. of Science and Technology, Beijing (China); Beijing Institute of Technology, Beijing (China)
Univ. of Science and Technology, Beijing (China)
Beijing Univ. of Technology, Beijing (China)
Beijing Institute of Technology, Beijing (China)
Northeastern Univ., Shenyang (China)
Argonne National Lab. (ANL), Argonne, IL (United States)

A polycrystalline Ni₄₁Co₉Mn₄₀Sn₁₀ (at. %) magnetic shape memory alloy was prepared by arc melting and characterized mainly by magnetic measurements, in-situ high-energy X-ray diffraction (HEXRD), and mechanical testing. A large magnetoresistance of 53.8% (under 5 T) and a large magnetic entropy change of 31.9 J/(kg K) (under 5 T) were simultaneously achieved. Both of these values are among the highest values reported so far in Ni-Mn-Sn-based Heusler alloys. The large magnetic entropy change, closely related to the structural entropy change, is attributed to the large unit cell volume change across martensitic transformation as revealed by our in-situ HEXRD experiment. Furthermore, good compressive properties were also obtained. Lastly, the combination of large magnetoresistance, large magnetic entropy change, and good compressive properties, as well as low cost makes this alloy a promising candidate for multifunctional applications.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1245146

Alternate ID(s):: OSTI ID: 1422668

Journal Information:: Journal of Alloys and Compounds, Vol. 647, Issue C; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 47 works

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References (35)

Magnetic-field-induced shape recovery by reverse phase transformation Kainuma, R.; Imano, Y.; Ito, W. Nature, Vol. 439, Issue 7079 https://doi.org/10.1038/nature04493	journal	February 2006
Magnetic Field-Induced Phase Transformation in NiMnCoIn Magnetic Shape-Memory Alloys-A New Actuation Mechanism with Large Work Output Karaca, Haluk E.; Karaman, Ibrahim; Basaran, Burak Advanced Functional Materials, Vol. 19, Issue 7 https://doi.org/10.1002/adfm.200801322	journal	April 2009
Inverse magnetocaloric effect in ferromagnetic Ni–Mn–Sn alloys Krenke, Thorsten; Duman, Eyüp; Acet, Mehmet Nature Materials, Vol. 4, Issue 6 https://doi.org/10.1038/nmat1395	journal	May 2005
Giant magnetic refrigeration capacity near room temperature in Ni ₄₀ Co ₁₀ Mn ₄₀ Sn ₁₀ multifunctional alloy Huang, L.; Cong, D. Y.; Suo, H. L. Applied Physics Letters, Vol. 104, Issue 13 https://doi.org/10.1063/1.4870771	journal	March 2014
Large magnetoresistance in Ni50Mn34In16 alloy Sharma, V. K.; Chattopadhyay, M. K.; Shaeb, K. H. B. Applied Physics Letters, Vol. 89, Issue 22 https://doi.org/10.1063/1.2399365	journal	November 2006
Observation of large magnetoresistance of magnetic Heusler alloy Ni50Mn36Sn14 in high magnetic fields Koyama, Keiichi; Okada, Hironari; Watanabe, Kazuo Applied Physics Letters, Vol. 89, Issue 18 https://doi.org/10.1063/1.2374868	journal	October 2006
Giant magnetothermal conductivity in the Ni–Mn–In ferromagnetic shape memory alloys Zhang, B.; Zhang, X. X.; Yu, S. Y. Applied Physics Letters, Vol. 91, Issue 1 https://doi.org/10.1063/1.2753710	journal	July 2007
Large entropy change associated with the elastocaloric effect in polycrystalline Ni-Mn-Sb-Co magnetic shape memory alloys Millán-Solsona, Rubén; Stern-Taulats, Enric; Vives, Eduard Applied Physics Letters, Vol. 105, Issue 24 https://doi.org/10.1063/1.4904419	journal	December 2014
Magnetic field-induced martensitic transformation and large magnetoresistance in NiCoMnSb alloys Yu, S. Y.; Ma, L.; Liu, G. D. Applied Physics Letters, Vol. 90, Issue 24 https://doi.org/10.1063/1.2748095	journal	June 2007
Large magnetoresistance in single-crystalline Ni50Mn50−xInx alloys (x=14–16) upon martensitic transformation Yu, S. Y.; Liu, Z. H.; Liu, G. D. Applied Physics Letters, Vol. 89, Issue 16 https://doi.org/10.1063/1.2362581	journal	October 2006
Novel Design of La(Fe,Si)13 Alloys Towards High Magnetic Refrigeration Performance Lyubina, Julia; Schäfer, Rudolf; Martin, Norbert Advanced Materials, Vol. 22, Issue 33 https://doi.org/10.1002/adma.201000177	journal	August 2010
Large magnetic entropy change and enhanced mechanical properties of Ni–Mn–Sn–C alloys Zhang, Yu; Liu, Jian; Zheng, Qiang Scripta Materialia, Vol. 75 https://doi.org/10.1016/j.scriptamat.2013.11.009	journal	March 2014
Phase diagram and composition optimization for magnetic shape memory effect in Ni–Co–Mn–Sn alloys Cong, D. Y.; Roth, S.; Pötschke, M. Applied Physics Letters, Vol. 97, Issue 2 https://doi.org/10.1063/1.3454239	journal	July 2010
The martensitic transformation, magnetocaloric effect, and magnetoresistance in high-Mn content Mn47+xNi43−xSn10 ferromagnetic shape memory alloys Xuan, H. C.; Zheng, Y. X.; Ma, S. C. Journal of Applied Physics, Vol. 108, Issue 10 https://doi.org/10.1063/1.3511748	journal	November 2010
Excess Ni-doping induced enhanced room temperature magneto-functionality in Ni-Mn-Sn based shape memory alloy Pramanick, S.; Chatterjee, S.; Giri, S. Applied Physics Letters, Vol. 105, Issue 11 https://doi.org/10.1063/1.4896033	journal	September 2014
Magnetoresistance origin in martensitic and austenitic phases of Ni2Mn1+xSn1−x Singh, Sandeep; Biswas, C. Applied Physics Letters, Vol. 98, Issue 21 https://doi.org/10.1063/1.3592853	journal	May 2011
Magnetoresistance and its relation to magnetization in Ni ₅₀ Mn ₃₅ Sn ₁₅ shape-memory epitaxial films Dubowik, J.; Załȩski, K.; Gościańska, I. Applied Physics Letters, Vol. 100, Issue 16 https://doi.org/10.1063/1.4704562	journal	April 2012
The phase transitions, magnetocaloric effect, and magnetoresistance in Co doped Ni–Mn–Sb ferromagnetic shape memory alloys Han, Z. D.; Wang, D. H.; Zhang, C. L. Journal of Applied Physics, Vol. 104, Issue 5 https://doi.org/10.1063/1.2975146	journal	September 2008
Reversibility of magnetostructural transition and associated magnetocaloric effect in Ni–Mn–In–Co Liu, Jian; Scheerbaum, Nils; Lyubina, Julia Applied Physics Letters, Vol. 93, Issue 10 https://doi.org/10.1063/1.2981210	journal	September 2008
Magnetic properties and structural transformations in Ni–Co–Mn–Sn multifunctional alloys Cong, D. Y.; Roth, S.; Schultz, L. Acta Materialia, Vol. 60, Issue 13-14 https://doi.org/10.1016/j.actamat.2012.06.034	journal	August 2012
Stable magnetostructural coupling with tunable magnetoresponsive effects in hexagonal ferromagnets Liu, Enke; Wang, Wenhong; Feng, Lin Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1868	journal	January 2012
Direct Measurement of the “Giant” Adiabatic Temperature Change in ${Gd}_{5} {Si}_{2} {Ge}_{2}$ Giguère, A.; Foldeaki, M.; Ravi Gopal, B. Physical Review Letters, Vol. 83, Issue 11 https://doi.org/10.1103/PhysRevLett.83.2262	journal	September 1999
Influence of Ni/Mn concentration on the structural, magnetic and magnetocaloric properties in Ni _{50− x} Mn _{37+ x} Sn ₁₃ Heusler alloys Muthu, S. Esakki; Rao, N. V. Rama; Raja, M. Manivel Journal of Physics D: Applied Physics, Vol. 43, Issue 42 https://doi.org/10.1088/0022-3727/43/42/425002	journal	October 2010
Effect of Co and Cu substitution on the magnetic entropy change in Ni ₄₆ Mn ₄₃ Sn ₁₁ alloy Das, Rahul; Sarma, S.; Perumal, A. Journal of Applied Physics, Vol. 109, Issue 7 https://doi.org/10.1063/1.3540327	journal	April 2011
Effect of annealing on the martensitic transformation and magnetocaloric effect in Ni44.1Mn44.2Sn11.7 ribbons Xuan, H. C.; Xie, K. X.; Wang, D. H. Applied Physics Letters, Vol. 92, Issue 24 https://doi.org/10.1063/1.2948904	journal	June 2008
Magnetocaloric effect and martensitic transition in Ni50Mn36−xCoxSn14 Yang, L. H.; Zhang, H.; Hu, F. X. Journal of Alloys and Compounds, Vol. 588 https://doi.org/10.1016/j.jallcom.2013.10.196	journal	March 2014
The “colossal” magnetocaloric effect in Mn1−xFexAs: What are we really measuring? Balli, Mohamed; Fruchart, Daniel; Gignoux, Damien Applied Physics Letters, Vol. 95, Issue 7 https://doi.org/10.1063/1.3194144	journal	August 2009
Magnetoresistance and magnetocaloric properties involving strong metamagnetic behavior in Fe-doped Ni ₄₅ (Co _1−x Fe _x ) ₅ Mn _36.6 In _13.4 alloys Chen, L.; Hu, F. X.; Wang, J. Applied Physics Letters, Vol. 101, Issue 1 https://doi.org/10.1063/1.4732525	journal	July 2012
Martensitic transformation and magnetic domains in Mn ₅₀ Ni ₄₀ Sn ₁₀ studied by in-situ transmission electron microscopy Tian, H. F.; Lu, J. B.; Ma, L. Journal of Applied Physics, Vol. 112, Issue 3 https://doi.org/10.1063/1.4740458	journal	August 2012
The crystal structure and phase transitions of the magnetic shape memory compound Ni₂MnGa Brown, P. J.; Crangle, J.; Kanomata, T. Journal of Physics: Condensed Matter, Vol. 14, Issue 43, p. 10159-10171 https://doi.org/10.1088/0953-8984/14/43/313	journal	October 2002
On the nature of the magnetocaloric effect of the first-order magnetostructural transition Gschneidner, K. A.; Mudryk, Y.; Pecharsky, V. K. Scripta Materialia, Vol. 67, Issue 6 https://doi.org/10.1016/j.scriptamat.2011.12.042	journal	September 2012
Giant room‐temperature magnetoresistance in the FeRh alloy Algarabel, P. A.; Ibarra, M. R.; Marquina, C. Applied Physics Letters, Vol. 66, Issue 22 https://doi.org/10.1063/1.114278	journal	May 1995
Magnetic-field-induced structural phase transition in ${Gd}_{5} {(S i}_{1.8} {Ge}_{2.2})$ Morellon, L.; Algarabel, P. A.; Ibarra, M. R. Physical Review B, Vol. 58, Issue 22 https://doi.org/10.1103/PhysRevB.58.R14721	journal	December 1998
Very large magnetic entropy change near room temperature in LaFe11.2Co0.7Si1.1 Hu, Feng-xia; Shen, Bao-gen; Sun, Ji-rong Applied Physics Letters, Vol. 80, Issue 5 https://doi.org/10.1063/1.1447592	journal	February 2002
Giant magnetocaloric effects by tailoring the phase transitions Trung, N. T.; Zhang, L.; Caron, L. Applied Physics Letters, Vol. 96, Issue 17 https://doi.org/10.1063/1.3399773	journal	April 2010

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Powder Metallurgy Synthesis of Heusler Alloys: Effects of Process Parameters Ahamed, Riaz; Ghomashchi, Reza; Xie, Zonghan Materials, Vol. 12, Issue 10 https://doi.org/10.3390/ma12101596	journal	May 2019
Martensitic transformation and magnetic properties in Mn49−xCuxNi41Sn10(x = 0–2) Zhao, Meng-Zhe; Qiu, Hong-Mei; Zhu, Ze-Ya Rare Metals https://doi.org/10.1007/s12598-018-1117-8	journal	September 2018
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Title: Large magnetic entropy change and magnetoresistance in a Ni41Co9Mn40Sn10 magnetic shape memory alloy

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Title: Large magnetic entropy change and magnetoresistance in a Ni₄₁Co₉Mn₄₀Sn₁₀ magnetic shape memory alloy