Volatility characterization of nanoparticles from single and dual-fuel low temperature combustion in compression ignition engines
Abstract
Our work explores the volatility of particles produced from two diesel low temperature combustion (LTC) modes proposed for high-efficiency compression ignition engines. It also explores mechanisms of particulate formation and growth upon dilution in the near-tailpipe environment. Moreover, the number distribution of exhaust particles from low- and mid-load dual-fuel reactivity controlled compression ignition (RCCI) and single-fuel premixed charge compression ignition (PPCI) modes were experimentally studied over a gradient of dilution temperature. Particle volatility of select particle diameters was investigated using volatility tandem differential mobility analysis (V-TDMA). Evaporation rates for exhaust particles were compared with V-TDMA results for candidate pure n-alkanes to identify species with similar volatility characteristics. The results show that LTC particles are mostly comprised of material with volatility similar to engine oil alkanes. V-TDMA results were used as inputs to an aerosol condensation and evaporation model to support the finding that smaller particles in the distribution are comprised of lower volatility material than large particles under primary dilution conditions. Although the results show that saturation levels are high enough to drive condensation of alkanes onto existing particles under the dilution conditions investigated, they are not high We conclude that observed particles from LTC operation must grow from lowmore »
- Authors:
-
- Univ. of Minnesota, Minneapolis, MN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1241466
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Aerosol Science and Technology
- Additional Journal Information:
- Journal Volume: 50; Journal Issue: 5; Journal ID: ISSN 0278-6826
- Publisher:
- American Association for Aerosol Research
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 33 ADVANCED PROPULSION SYSTEMS
Citation Formats
Lucachick, Glenn, Curran, Scott, Storey, John Morse, Prikhodko, Vitaly Y., and Northrop, William F. Volatility characterization of nanoparticles from single and dual-fuel low temperature combustion in compression ignition engines. United States: N. p., 2016.
Web. doi:10.1080/02786826.2016.1163320.
Lucachick, Glenn, Curran, Scott, Storey, John Morse, Prikhodko, Vitaly Y., & Northrop, William F. Volatility characterization of nanoparticles from single and dual-fuel low temperature combustion in compression ignition engines. United States. https://doi.org/10.1080/02786826.2016.1163320
Lucachick, Glenn, Curran, Scott, Storey, John Morse, Prikhodko, Vitaly Y., and Northrop, William F. 2016.
"Volatility characterization of nanoparticles from single and dual-fuel low temperature combustion in compression ignition engines". United States. https://doi.org/10.1080/02786826.2016.1163320. https://www.osti.gov/servlets/purl/1241466.
@article{osti_1241466,
title = {Volatility characterization of nanoparticles from single and dual-fuel low temperature combustion in compression ignition engines},
author = {Lucachick, Glenn and Curran, Scott and Storey, John Morse and Prikhodko, Vitaly Y. and Northrop, William F.},
abstractNote = {Our work explores the volatility of particles produced from two diesel low temperature combustion (LTC) modes proposed for high-efficiency compression ignition engines. It also explores mechanisms of particulate formation and growth upon dilution in the near-tailpipe environment. Moreover, the number distribution of exhaust particles from low- and mid-load dual-fuel reactivity controlled compression ignition (RCCI) and single-fuel premixed charge compression ignition (PPCI) modes were experimentally studied over a gradient of dilution temperature. Particle volatility of select particle diameters was investigated using volatility tandem differential mobility analysis (V-TDMA). Evaporation rates for exhaust particles were compared with V-TDMA results for candidate pure n-alkanes to identify species with similar volatility characteristics. The results show that LTC particles are mostly comprised of material with volatility similar to engine oil alkanes. V-TDMA results were used as inputs to an aerosol condensation and evaporation model to support the finding that smaller particles in the distribution are comprised of lower volatility material than large particles under primary dilution conditions. Although the results show that saturation levels are high enough to drive condensation of alkanes onto existing particles under the dilution conditions investigated, they are not high We conclude that observed particles from LTC operation must grow from low concentrations of highly non-volatile compounds present in the exhaust.},
doi = {10.1080/02786826.2016.1163320},
url = {https://www.osti.gov/biblio/1241466},
journal = {Aerosol Science and Technology},
issn = {0278-6826},
number = 5,
volume = 50,
place = {United States},
year = {Thu Mar 10 00:00:00 EST 2016},
month = {Thu Mar 10 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Vapor Pressures and Vaporization Enthalpies of the n -Alkanes from C 21 to C 30 at T = 298.15 K by Correlation Gas Chromatography
journal, January 2004
- Chickos, James S.; Hanshaw, William
- Journal of Chemical & Engineering Data, Vol. 49, Issue 1
Vapor Pressures and Vaporization Enthalpies of the n -Alkanes from C 31 to C 38 at T = 298.15 K by Correlation Gas Chromatography
journal, May 2004
- Chickos, James S.; Hanshaw, William
- Journal of Chemical & Engineering Data, Vol. 49, Issue 3
Comparison of HC species from diesel combustion modes and characterization of a heat-up doc formulation
journal, August 2008
- Han, M.; Assanis, D. N.; Bohac, S. V.
- International Journal of Automotive Technology, Vol. 9, Issue 4
The attainment of premixed compression ignition low-temperature combustion in a compression ignition direct injection engine
journal, January 2007
- Jacobs, Timothy J.; Assanis, Dennis N.
- Proceedings of the Combustion Institute, Vol. 31, Issue 2
Engines and nanoparticles
journal, June 1998
- Kittelson, David B.
- Journal of Aerosol Science, Vol. 29, Issue 5-6
Comparison of Methods for Online Measurement of Diesel Particulate Matter
journal, May 2012
- Liu, Zhun; Swanson, Jacob; Kittelson, David B.
- Environmental Science & Technology, Vol. 46, Issue 11
Exploration of Semi-Volatile Particulate Matter Emissions from Low Temperature Combustion in a Light-Duty Diesel Engine
journal, April 2014
- Lucachick, Glenn; Avenido, Aaron; Kittelson, David
- SAE International Journal of Engines, Vol. 7, Issue 2
Effects of Aftertreatment on Semi-Volatile Particulate Matter Emissions from Low Temperature Combustion in a Light-Duty Diesel Engine
journal, January 2015
- Lucachick, Glenn A.; Kittelson, David; Northrop, William
- SAE International Journal of Engines, Vol. 8, Issue 2
Conceptual models for partially premixed low-temperature diesel combustion
journal, April 2013
- Musculus, Mark P. B.; Miles, Paul C.; Pickett, Lyle M.
- Progress in Energy and Combustion Science, Vol. 39, Issue 2-3
Comparison of Filter Smoke Number and Elemental Carbon Mass From Partially Premixed Low Temperature Combustion in a Direct-Injection Diesel Engine
journal, May 2011
- Northrop, William F.; Bohac, Stanislav V.; Chin, Jo-Yu
- Journal of Engineering for Gas Turbines and Power, Vol. 133, Issue 10
Condensational Growth of Particulate Matter from Partially Premixed Low Temperature Combustion of Biodiesel in a Compression Ignition Engine
journal, January 2011
- Northrop, William F.; Madathil, Praveen V.; Bohac, Stanislav V.
- Aerosol Science and Technology, Vol. 45, Issue 1
Effectiveness of Diesel Oxidation Catalyst in Reducing HC and CO Emissions from Reactivity Controlled Compression Ignition
journal, April 2013
- Prikhodko, Vitaly Y.; Curran, Scott J.; Parks, James E.
- SAE International Journal of Fuels and Lubricants, Vol. 6, Issue 2
Review of high efficiency and clean reactivity controlled compression ignition (RCCI) combustion in internal combustion engines
journal, February 2015
- Reitz, Rolf D.; Duraisamy, Ganesh
- Progress in Energy and Combustion Science, Vol. 46
Vapor Phase Homogeneous Nucleation of Higher Alkanes: Dodecane, Hexadecane, and Octadecane. 1. Critical Supersaturation and Nucleation Rate Measurements †
journal, November 2001
- Rusyniak, Mark; Abdelsayed, Victor; Campbell, Jason
- The Journal of Physical Chemistry B, Vol. 105, Issue 47
Size-Dependent Mixing Characteristics of Volatile and Nonvolatile Components in Diesel Exhaust Aerosols
journal, December 2003
- Sakurai, Hiromu; Park, Kihong; McMurry, Peter H.
- Environmental Science & Technology, Vol. 37, Issue 24
On-line measurements of diesel nanoparticle composition and volatility
journal, March 2003
- Sakurai, Hiromu; Tobias, Herbert J.; Park, Kihong
- Atmospheric Environment, Vol. 37, Issue 9-10
Size distribution dynamics reveal particle-phase chemistry in organic aerosol formation
journal, July 2013
- Shiraiwa, M.; Yee, L. D.; Schilling, K. A.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 29
The Contribution of Lubricant to the Formation of Particulate Matter with Reactivity Controlled Compression Ignition in Light-Duty Diesel Engines
journal, December 2014
- Storey, John; Curran, Scott; Dempsey, Adam
- Emission Control Science and Technology, Vol. 1, Issue 1
Vapor pressures and surface free energies of C14-C18 monocarboxylic acids and C5 and C6 dicarboxylic acids
journal, December 1989
- Tao, Ye; McMurry, Peter H.
- Environmental Science & Technology, Vol. 23, Issue 12
Works referencing / citing this record:
Effects of multiple injection strategies on gaseous emissions and particle size distribution in a two-stroke compression-ignition engine operating with the gasoline partially premixed combustion concept
journal, September 2018
- Bermúdez, Vicente; Ruiz, Santiago; Novella, Ricardo
- Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, Vol. 233, Issue 10
Evolution and current understanding of physicochemical characterization of particulate matter from reactivity controlled compression ignition combustion on a multicylinder light-duty engine
journal, August 2016
- Storey, John ME; Curran, Scott J.; Lewis, Samuel A.
- International Journal of Engine Research, Vol. 18, Issue 5-6
Assessment on the consequences of injection strategies on combustion process and particle size distributions in Euro VI medium-duty diesel engine
journal, July 2019
- Bermúdez, Vicente; García, Antonio; Villalta, David
- International Journal of Engine Research, Vol. 21, Issue 4