Conversion of glucose to sorbose

Davis, Mark E.; Gounder, Rajamani

Title: Conversion of glucose to sorbose

Patent · Tue Feb 09 00:00:00 EST 2016

OSTI ID:1241342

Davis, Mark E.; Gounder, Rajamani

The present invention is directed to methods for preparing sorbose from glucose, said method comprising: (a) contacting the glucose with a silica-containing structure comprising a zeolite having a topology of a 12 membered-ring or larger, an ordered mesoporous silica material, or an amorphous silica, said structure containing Lewis acidic Ti.sup.4+ or Zr.sup.4+ or both Ti.sup.4+ and Zr.sup.4+ framework centers, said contacting conducted under reaction conditions sufficient to isomerize the glucose to sorbose. The sorbose may be (b) separated or isolated; or (c) converted to ascorbic acid.

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Research Organization:: California Institute of Technology (CalTech), Pasadena, CA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: SC0001004/T-106028

Assignee:: California Institute of Technology (Pasadena, CA)

Patent Number(s):: 9,255,120

Application Number:: 14/197,511

OSTI ID:: 1241342

Resource Relation:: Patent File Date: 2014 Mar 05

Country of Publication:: United States

Language:: English

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