skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: All-Polymer Solar Cell Performance Optimized via Systematic Molecular Weight Tuning of Both Donor and Acceptor Polymers

Journal Article · · Journal of the American Chemical Society
DOI:https://doi.org/10.1021/jacs.5b10735· OSTI ID:1239399

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - BASIC ENERGY SCIENCES
OSTI ID:
1239399
Journal Information:
Journal of the American Chemical Society, Vol. 138, Issue (4) ; 02, 2016; ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
ENGLISH

References (83)

Synthesis and Characterization of Solution-Processable Ladderized n-Type Naphthalene Bisimide Copolymers for OFET Applications journal June 2011
All-Polymer Bulk Heterojuction Solar Cells with 4.8% Efficiency Achieved by Solution Processing from a Co-Solvent journal July 2014
A high-mobility electron-transporting polymer for printed transistors journal January 2009
Alkoxy-Functionalized Thienyl-Vinylene Polymers for Field-Effect Transistors and All-Polymer Solar Cells journal January 2014
Supramolecular Order of Solution-Processed Perylenediimide Thin Films: High-Performance Small-Channel n-Type Organic Transistors journal October 2011
A Polythiophene Derivative with Superior Properties for Practical Application in Polymer Solar Cells journal July 2014
Molecular Weight Effect on the Efficiency of Polymer Solar Cells journal November 2013
Modern plastic solar cells: materials, mechanisms and modeling journal July 2013
Design Rules for Donors in Bulk-Heterojunction Solar Cells—Towards 10 % Energy-Conversion Efficiency journal March 2006
Effects of the Molecular Weight and the Side-Chain Length on the Photovoltaic Performance of Dithienosilole/Thienopyrrolodione Copolymers journal March 2012
n-Type Semiconducting Naphthalene Diimide-Perylene Diimide Copolymers: Controlling Crystallinity, Blend Morphology, and Compatibility Toward High-Performance All-Polymer Solar Cells journal March 2015
Molecular weight dependent vertical composition profiles of PCDTBT:PC71BM blends for organic photovoltaics journal June 2014
Bithiophene Imide and Benzodithiophene Copolymers for Efficient Inverted Polymer Solar Cells journal March 2012
Fine-Tuning the 3D Structure of Nonfullerene Electron Acceptors Toward High-Performance Polymer Solar Cells journal April 2015
Effect of Molecular Weight on the Structure and Crystallinity of Poly(3-hexylthiophene) journal March 2006
Evidence of Aggregate Formation for 2,5-Dialkylpoly( p -phenyleneethynylenes) in Solution and Thin Films journal December 1998
Charge Transport Orthogonality in All-Polymer Blend Transistors, Diodes, and Solar Cells journal November 2013
Aggregation in a High-Mobility n-Type Low-Bandgap Copolymer with Implications on Semicrystalline Morphology journal October 2012
Integrated Molecular, Interfacial, and Device Engineering towards High-Performance Non-Fullerene Based Organic Solar Cells journal June 2014
H- and J-Aggregate Behavior in Polymeric Semiconductors journal April 2014
Microstructural Characterization and Charge Transport in Thin Films of Conjugated Polymers journal July 2010
High-performance fullerene-free polymer solar cells with 6.31% efficiency journal January 2015
Molecular weight and end capping effects on the optoelectronic properties of structurally related ‘heavy atom’ donor–acceptor polymers journal January 2014
Perylene Imides for Organic Photovoltaics: Yesterday, Today, and Tomorrow journal January 2012
Competition between recombination and extraction of free charges determines the fill factor of organic solar cells journal May 2015
Synthesis and characterization of fused-thiophene containing naphthalene diimide n -type copolymers for organic thin film transistor and all-polymer solar cell applications journal June 2013
Origin of the Reduced Fill Factor and Photocurrent in MDMO-PPV:PCNEPV All-Polymer Solar Cells journal July 2007
Organic tandem solar cells: A review journal January 2009
Strong scaling of general-purpose molecular dynamics simulations on GPUs journal July 2015
7.7% Efficient All-Polymer Solar Cells journal July 2015
Scherrer grain-size analysis adapted to grazing-incidence scattering with area detectors journal October 2009
Molecular Weight Dependence of the Morphology in P3HT:PCBM Solar Cells journal October 2014
VMD: Visual molecular dynamics journal February 1996
Streamlined microwave-assisted preparation of narrow-bandgap conjugated polymers for high-performance bulk heterojunction solar cells journal October 2009
Efficient Polythiophene/Polyfluorene Copolymer Bulk Heterojunction Photovoltaic Devices: Device Physics and Annealing Effects journal August 2008
The Palladium-Catalyzed Cross-Coupling Reactions of Organotin Reagents with Organic Electrophiles [New Synthetic Methods(58)] journal June 1986
Synthesis and Search for Design Principles of New Electron Accepting Polymers for All-Polymer Solar Cells journal May 2014
Control of conformational and interpolymer effects in conjugated polymers journal June 2001
Multiscale molecular simulations of the nanoscale morphologies of P3HT:PCBM blends for bulk heterojunction organic photovoltaic cells journal January 2011
Fluoro-Substituted n-Type Conjugated Polymers for Additive-Free All-Polymer Bulk Heterojunction Solar Cells with High Power Conversion Efficiency of 6.71% journal April 2015
High Electron Mobility and Ambient Stability in Solution-Processed Perylene-Based Organic Field-Effect Transistors journal April 2009
Organic Solar Cells Using a High-Molecular-Weight Benzodithiophene-Benzothiadiazole Copolymer with an Efficiency of 9.4% journal November 2014
A general relationship between disorder, aggregation and charge transport in conjugated polymers journal August 2013
Controlling Solution-Phase Polymer Aggregation with Molecular Weight and Solvent Additives to Optimize Polymer-Fullerene Bulk Heterojunction Solar Cells journal March 2014
Substantial photovoltaic response and morphology tuning in benzo[1,2-b:6,5-b′]dithiophene (bBDT) molecular donors journal January 2014
Semi-crystalline photovoltaic polymers with efficiency exceeding 9% in a ∼300 nm thick conventional single-cell device journal January 2014
Drastic Change of Molecular Orientation in a Thiazolothiazole Copolymer by Molecular-Weight Control and Blending with PC 61 BM Leads to High Efficiencies in Solar Cells journal December 2011
Influence of Aggregation on the Performance of All-Polymer Solar Cells Containing Low-Bandgap Naphthalenediimide Copolymers journal January 2012
Polymer solar cells with enhanced fill factors journal August 2013
All-Polymer Solar Cells with 3.3% Efficiency Based on Naphthalene Diimide-Selenophene Copolymer Acceptor journal September 2013
General purpose molecular dynamics simulations fully implemented on graphics processing units journal May 2008
Aggregation and morphology control enables multiple cases of high-efficiency polymer solar cells journal November 2014
Determining the Role of Polymer Molecular Weight for High-Performance All-Polymer Solar Cells: Its Effect on Polymer Aggregation and Phase Separation journal February 2015
Power conversion efficiency enhancement in diketopyrrolopyrrole based solar cells through polymer fractionation journal January 2014
A molecular dynamics method for simulations in the canonical ensemble journal June 1984
The Role of Regioregularity, Crystallinity, and Chain Orientation on Electron Transport in a High-Mobility n-Type Copolymer journal March 2014
Highly efficient charge-carrier generation and collection in polymer/polymer blend solar cells with a power conversion efficiency of 5.7% journal January 2014
Influence of Molecular Weight on the Performance of Organic Solar Cells Based on a Fluorene Derivative journal June 2010
Stille Polycondensation for Synthesis of Functional Materials journal March 2011
Nanoscale structure of solar cells based on pure conjugated polymer blends journal January 2007
Can computational approaches aid in untangling the inherent complexity of practical organic photovoltaic systems? journal April 2012
Synthesis of 5 H -Dithieno[3,2- b :2′,3′- d ]pyran as an Electron-Rich Building Block for Donor–Acceptor Type Low-Bandgap Polymers journal April 2013
Measurement of the lowest unoccupied molecular orbital energies of molecular organic semiconductors journal May 2009
Efficient Small Bandgap Polymer Solar Cells with High Fill Factors for 300 nm Thick Films journal March 2013
Morphology-Performance Relationships in High-Efficiency All-Polymer Solar Cells journal October 2013
Ultraflexible Polymer Solar Cells Using Amorphous Zinc−Indium−Tin Oxide Transparent Electrodes journal October 2013
Canonical dynamics: Equilibrium phase-space distributions journal March 1985
Relationship between the ionization and oxidation potentials of molecular organic semiconductors journal February 2005
Single-Junction Polymer Solar Cells Exceeding 10% Power Conversion Efficiency journal November 2014
For the Bright Future-Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4% journal May 2010
High-Efficiency All-Polymer Solar Cells Based on a Pair of Crystalline Low-Bandgap Polymers journal September 2014
Efficiency enhancement in low-bandgap polymer solar cells by processing with alkane dithiols journal May 2007
Bithiopheneimide–Dithienosilole/Dithienogermole Copolymers for Efficient Solar Cells: Information from Structure–Property–Device Performance Correlations and Comparison to Thieno[3,4- c ]pyrrole-4,6-dione Analogues journal October 2012
“Plastic” Solar Cells: Self-Assembly of Bulk Heterojunction Nanomaterials by Spontaneous Phase Separation journal November 2009
Outlook and Emerging Semiconducting Materials for Ambipolar Transistors journal October 2013
Polymer donor–polymer acceptor (all-polymer) solar cells journal April 2013
Controlling Molecular Weight of a High Efficiency Donor-Acceptor Conjugated Polymer and Understanding Its Significant Impact on Photovoltaic Properties journal March 2014
Semiconducting Thienothiophene Copolymers: Design, Synthesis, Morphology, and Performance in Thin-Film Organic Transistors journal March 2009
Long and winding polymeric roads journal October 2013
Development and Structure/Property Relationship of New Electron Accepting Polymers Based on Thieno[2′,3′:4,5]pyrido[2,3- g ]thieno[3,2- c ]quinoline-4,10-dione for All-Polymer Solar Cells journal August 2015
Influence of Semiconductor Thickness and Molecular Weight on the Charge Transport of a Naphthalenediimide-Based Copolymer in Thin-Film Transistors journal March 2015
Radical Chain Polymerization book January 2004
Principles of Polymerization book January 2004

Cited By (47)

Side-Chain Optimization of Phthalimide−Bithiophene Copolymers for Efficient All-Polymer Solar Cells with Large Fill Factors journal May 2018
Influence of alkyl chains on photovoltaic properties of 3D rylene propeller electron acceptors journal January 2017
High-Performance and Stable All-Polymer Solar Cells Using Donor and Acceptor Polymers with Complementary Absorption journal March 2017
Pt complex-based terpolymer acceptors linked through ancillary ligand for all-polymer solar cells journal January 2018
Improving Performance of All‐Polymer Solar Cells Through Backbone Engineering of Both Donors and Acceptors journal September 2018
Polymer physics across scales: Modeling the multiscale behavior of functional soft materials and biological systems journal December 2019
Photoactive Blend Morphology Engineering through Systematically Tuning Aggregation in All-Polymer Solar Cells journal January 2018
A Vinylene-Bridged Perylenediimide-Based Polymeric Acceptor Enabling Efficient All-Polymer Solar Cells Processed under Ambient Conditions journal August 2016
Charge-transfer state dynamics in all-polymer solar cells: formation, dissociation and decoherence journal January 2019
Tuning the performance of the non-fullerene organic solar cells by the polarizability journal January 2018
Distinctive phase separation dynamics of polymer blends: roles of Janus nanoparticles journal January 2019
Polymer Acceptor Based on Double B←N Bridged Bipyridine (BNBP) Unit for High-Efficiency All-Polymer Solar Cells journal May 2016
Highly Flexible and Efficient All-Polymer Solar Cells with High-Viscosity Processing Polymer Additive toward Potential of Stretchable Devices journal September 2018
Efficient non-fullerene polymer solar cells based on a wide bandgap polymer of meta-alkoxy-phenyl-substituted benzodithiophene and difluorobenzotriazole journal January 2017
Mesopolymer synthesis by ligand-modulated direct arylation polycondensation towards n-type and ambipolar conjugated systems journal January 2019
Recent Advances in n‐Type Polymers for All‐Polymer Solar Cells journal February 2019
Effect of polymer molecular weight on J51 based organic solar cells journal January 2019
All-Polymer Solar Cells: Recent Progress, Challenges, and Prospects journal February 2019
Design of Cyanovinylene-Containing Polymer Acceptors with Large Dipole Moment Change for Efficient Charge Generation in High-Performance All-Polymer Solar Cells journal September 2017
The interplay of interfaces, supramolecular assembly, and electronics in organic semiconductors journal July 2019
High-Performance As-Cast Nonfullerene Polymer Solar Cells with Thicker Active Layer and Large Area Exceeding 11% Power Conversion Efficiency journal December 2017
Understanding the Impact of Oligomeric Polystyrene Side Chain Arrangement on the All-Polymer Solar Cell Performance journal September 2017
Improved Tandem All-Polymer Solar Cells Performance by Using Spectrally Matched Subcells journal January 2018
Polymersolarzellen: Fortschritt, Herausforderungen und Perspektiven journal March 2019
Novel unsymmetrical squaraine-based small molecules for organic solar cells journal January 2018
Controlling Molecular Orientation of Naphthalenediimide-Based Polymer Acceptors for High Performance All-Polymer Solar Cells journal June 2016
Advances in Non-Fullerene Acceptor Based Ternary Organic Solar Cells journal December 2017
Synergistic effect of fluorination on both donor and acceptor materials for high performance non-fullerene polymer solar cells with 13.5% efficiency journal January 2018
Benzodithiophene-modified terpolymer acceptors with reduced molecular planarity and crystallinity: improved performance and stability for all-polymer solar cells journal January 2019
Alkyl Chain Length Effects of Polymer Donors on the Morphology and Device Performance of Polymer Solar Cells with Different Acceptors journal July 2019
Highly Flexible and Efficient All‐Polymer Solar Cells with High‐Viscosity Processing Polymer Additive toward Potential of Stretchable Devices journal September 2018
Diacenaphthylene-fused benzo[1,2-b:4,5-b′]dithiophenes: polycyclic heteroacenes containing full-carbon five-membered aromatic rings journal January 2017
Tuning the Molecular Weight of the Electron Accepting Polymer in All-Polymer Solar Cells: Impact on Morphology and Charge Generation journal March 2018
Construction of dimetal-containing dithiolene and Schiff base conjugated polymer coating: exploiting metal coordination as a design strategy for improving infrared stealth properties journal January 2019
Thieno[3,4- c ]pyrrole-4,6-dione-3,4-difluorothiophene Polymer Acceptors for Efficient All-Polymer Bulk Heterojunction Solar Cells journal October 2016
High voltage all polymer solar cells with a polymer acceptor based on NDI and benzotriazole journal January 2019
The Impact of Sequential Fluorination of π-Conjugated Polymers on Charge Generation in All-Polymer Solar Cells journal May 2017
Stretchable Polymer Semiconductors for Plastic Electronics journal January 2018
Ternary Organic Solar Cells Based on Two Compatible Nonfullerene Acceptors with Power Conversion Efficiency >10% journal September 2016
Roll-to-Roll Printed Large-Area All-Polymer Solar Cells with 5% Efficiency Based on a Low Crystallinity Conjugated Polymer Blend journal March 2017
Thieno[3,4- c ]pyrrole-4,6-dione-3,4-difluorothiophene Polymer Acceptors for Efficient All-Polymer Bulk Heterojunction Solar Cells journal October 2016
Realizing 8.6% Efficiency from Non‐Halogenated Solvent Processed Additive Free All Polymer Solar Cells with a Quinoxaline Based Polymer journal January 2019
Conjugated polymers and composites for stretchable organic electronics journal January 2019
Thieno[3,4- c ]Pyrrole-4,6-Dione-Based Polymer Acceptors for High Open-Circuit Voltage All-Polymer Solar Cells journal April 2017
High-Performance Thick-Film All-Polymer Solar Cells Created Via Ternary Blending of a Novel Wide-Bandgap Electron-Donating Copolymer journal February 2018
Recent Advances in Wide-Bandgap Photovoltaic Polymers journal March 2017
Microwave-Assisted Classic Ullmann C–C Coupling Polymerization for Acceptor-Acceptor Homopolymers journal October 2019

Related Subjects