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Title: Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes

Abstract

The reaction of 248CmCl3 with excess 2,6-pyridinedicarboxylic acid (DPA) under mild solvothermal conditions results in crystallization of the tris-chelate complex Cm(HDPA)3·H2O. Approximately half of the curium remains in solution at the end of this process, and evaporation of the mother liquor results in crystallization of the bis-chelate complex [Cm(HDPA)- (H2DPA)(H2O)2Cl]Cl·2H2O. 248Cm is the daughter of the α decay of 252Cf and is extracted in high purity from this parent. However, trace amounts of 249,250,251Cf are still present in all samples of 248Cm. During the crystallization of Cm(HDPA)3·H2O and [Cm(HDPA)(H2DPA)(H2O)2Cl]Cl·2H2O, californium(III) spontaneously separates itself from the curium complexes and is found doped within crystals of DPA in the form of Cf(HDPA)3. These results add to the growing body of evidence that the chemistry of californium is fundamentally different from that of earlier actinides.

Authors:
; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1239311
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Inorganic Chemistry; Journal Volume: 54; Journal Issue: 23
Country of Publication:
United States
Language:
English

Citation Formats

Cary, Samantha K., Silver, Mark A., Liu, Guokui, Wang, Jamie C., Bogart, Justin A., Stritzinger, Jared T., Arico, Alexandra A., Hanson, Kenneth, Schelter, Eric J., and Albrecht-Schmitt, Thomas E. Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes. United States: N. p., 2015. Web. doi:10.1021/acs.inorgchem.5b02052.
Cary, Samantha K., Silver, Mark A., Liu, Guokui, Wang, Jamie C., Bogart, Justin A., Stritzinger, Jared T., Arico, Alexandra A., Hanson, Kenneth, Schelter, Eric J., & Albrecht-Schmitt, Thomas E. Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes. United States. doi:10.1021/acs.inorgchem.5b02052.
Cary, Samantha K., Silver, Mark A., Liu, Guokui, Wang, Jamie C., Bogart, Justin A., Stritzinger, Jared T., Arico, Alexandra A., Hanson, Kenneth, Schelter, Eric J., and Albrecht-Schmitt, Thomas E. Mon . "Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes". United States. doi:10.1021/acs.inorgchem.5b02052.
@article{osti_1239311,
title = {Spontaneous Partitioning of Californium from Curium: Curious Cases from the Crystallization of Curium Coordination Complexes},
author = {Cary, Samantha K. and Silver, Mark A. and Liu, Guokui and Wang, Jamie C. and Bogart, Justin A. and Stritzinger, Jared T. and Arico, Alexandra A. and Hanson, Kenneth and Schelter, Eric J. and Albrecht-Schmitt, Thomas E.},
abstractNote = {The reaction of 248CmCl3 with excess 2,6-pyridinedicarboxylic acid (DPA) under mild solvothermal conditions results in crystallization of the tris-chelate complex Cm(HDPA)3·H2O. Approximately half of the curium remains in solution at the end of this process, and evaporation of the mother liquor results in crystallization of the bis-chelate complex [Cm(HDPA)- (H2DPA)(H2O)2Cl]Cl·2H2O. 248Cm is the daughter of the α decay of 252Cf and is extracted in high purity from this parent. However, trace amounts of 249,250,251Cf are still present in all samples of 248Cm. During the crystallization of Cm(HDPA)3·H2O and [Cm(HDPA)(H2DPA)(H2O)2Cl]Cl·2H2O, californium(III) spontaneously separates itself from the curium complexes and is found doped within crystals of DPA in the form of Cf(HDPA)3. These results add to the growing body of evidence that the chemistry of californium is fundamentally different from that of earlier actinides.},
doi = {10.1021/acs.inorgchem.5b02052},
journal = {Inorganic Chemistry},
number = 23,
volume = 54,
place = {United States},
year = {Mon Dec 07 00:00:00 EST 2015},
month = {Mon Dec 07 00:00:00 EST 2015}
}