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Title: Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal Organic Framework

Authors:
; ; ; ;  [1]
  1. UCB
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
National Science Foundation (NSF)
OSTI Identifier:
1238293
Resource Type:
Journal Article
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 137; Journal Issue: (50) ; 12, 2015; Journal ID: ISSN 0002-7863
Country of Publication:
United States
Language:
ENGLISH

Citation Formats

Darago, Lucy E., Aubrey, Michael L., Yu, Chung Jui, Gonzalez, Miguel I., and Long, Jeffrey R. Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal Organic Framework. United States: N. p., 2016. Web. doi:10.1021/jacs.5b10385.
Darago, Lucy E., Aubrey, Michael L., Yu, Chung Jui, Gonzalez, Miguel I., & Long, Jeffrey R. Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal Organic Framework. United States. doi:10.1021/jacs.5b10385.
Darago, Lucy E., Aubrey, Michael L., Yu, Chung Jui, Gonzalez, Miguel I., and Long, Jeffrey R. Fri . "Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal Organic Framework". United States. doi:10.1021/jacs.5b10385.
@article{osti_1238293,
title = {Electronic Conductivity, Ferrimagnetic Ordering, and Reductive Insertion Mediated by Organic Mixed-Valence in a Ferric Semiquinoid Metal Organic Framework},
author = {Darago, Lucy E. and Aubrey, Michael L. and Yu, Chung Jui and Gonzalez, Miguel I. and Long, Jeffrey R.},
abstractNote = {},
doi = {10.1021/jacs.5b10385},
journal = {Journal of the American Chemical Society},
issn = {0002-7863},
number = (50) ; 12, 2015,
volume = 137,
place = {United States},
year = {2016},
month = {11}
}

Works referencing / citing this record:

An Organic Mixed-Valence Ligand for Multistate Redox-Active Coordination Networks
journal, March 2018

  • Ha, Joo Yeon; Koo, Jin Young; Ohtsu, Hiroyoshi
  • Angewandte Chemie International Edition, Vol. 57, Issue 17
  • DOI: 10.1002/anie.201713035

Thermally Induced Valence Tautomeric Transition in a Two-Dimensional Fe-Tetraoxolene Honeycomb Network
journal, August 2018

  • Chen, Jian; Sekine, Yoshihiro; Komatsumaru, Yuki
  • Angewandte Chemie International Edition, Vol. 57, Issue 37
  • DOI: 10.1002/anie.201807556

A Dicobalt Complex with an Unsymmetrical Quinonoid Bridge Isolated in Three Units of Charge: A Combined Structural, (Spectro)electrochemical, Magnetic and Spectroscopic Study
journal, August 2016

  • van der Meer, Margarethe; Rechkemmer, Yvonne; Frank, Uta
  • Chemistry - A European Journal, Vol. 22, Issue 39
  • DOI: 10.1002/chem.201601579

Isovalent Ag III /Ag III , Ag II /Ag II , Mixed-Valent Ag II /Ag III , and Corrolato-Based Mixed-Valency in β,β′-Linked [Bis{corrolato-silver}] n Complexes
journal, September 2017

  • Patra, Bratati; Sobottka, Sebastian; Sinha, Woormileela
  • Chemistry - A European Journal, Vol. 23, Issue 56
  • DOI: 10.1002/chem.201703512

Redox‐Reversible 2D Metal–Organic Framework Nanosheets (MONs) Based on the Hydroquinone/Quinone Couple
journal, February 2019

  • Maka, Vijay Kumar; Mukhopadhyay, Arindam; Jindal, Swati
  • Chemistry – A European Journal, Vol. 25, Issue 15
  • DOI: 10.1002/chem.201805188

Square Grid Metal–Chloranilate Networks as Robust Host Systems for Guest Sorption
journal, March 2019

  • Kingsbury, Christopher J.; Abrahams, Brendan F.; Auckett, Josie E.
  • Chemistry – A European Journal, Vol. 25, Issue 20
  • DOI: 10.1002/chem.201805600

A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior
journal, July 2018


Integration of a (–Cu–S–)n plane in a metal–organic framework affords high electrical conductivity
journal, April 2019


Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry
journal, September 2018

  • Pedersen, Kasper S.; Perlepe, Panagiota; Aubrey, Michael L.
  • Nature Chemistry, Vol. 10, Issue 10
  • DOI: 10.1038/s41557-018-0107-7

Cuboctahedron-based indium–organic frameworks for gas sorption and selective cation exchange
journal, January 2016

  • Yu, Panpan; Li, Qipeng; Hu, Yue
  • Chemical Communications, Vol. 52, Issue 51
  • DOI: 10.1039/c6cc03497g

Zinc and cadmium complexes based on bis-(1H-tetrazol-5-ylmethyl/ylethyl)-amine ligands: structures and photoluminescence properties
journal, January 2016

  • Wang, Duo-Zhi; Fan, Jian-Zhong; Jia, Dianzeng
  • CrystEngComm, Vol. 18, Issue 35
  • DOI: 10.1039/c6ce01311b

A microporous europium–organic framework anchored with open –COOH groups for selective cation sensing
journal, January 2016

  • Qian, Jinjie; Yu, Panpan; Huang, Shaoming
  • CrystEngComm, Vol. 18, Issue 41
  • DOI: 10.1039/c6ce01801g

A 1,2,3-dithiazolyl-o-naphthoquinone: a neutral radical with isolable cation and anion oxidation states
journal, January 2016

  • Smithson, Chad S.; MacDonald, Daniel J.; Matt Letvenuk, T.
  • Dalton Transactions, Vol. 45, Issue 23
  • DOI: 10.1039/c6dt01249c

Chiral heterobimetallic chains from a dicyanideferrite building block including a π-conjugated TTF annulated ligand
journal, January 2016

  • Cui, Long; Lv, Zhong-Peng; Leong, Chanel F.
  • Dalton Transactions, Vol. 45, Issue 42
  • DOI: 10.1039/c6dt01756h

Tuning the iron redox state inside a microporous porphyrinic metal organic framework
journal, January 2017

  • Abeykoon, Brian; Grenèche, Jean-Marc; Jeanneau, Erwann
  • Dalton Transactions, Vol. 46, Issue 2
  • DOI: 10.1039/c6dt04208b

Syntheses, structures and magnetic properties of nine coordination polymers based on terphenyl-tetracarboxylic acid ligands
journal, January 2017

  • Zhou, Xinhui; Chen, Qianqian; Liu, Baolin
  • Dalton Transactions, Vol. 46, Issue 2
  • DOI: 10.1039/c6dt04270h

Benzoquinone-bridged Co 2 complexes with different magnetic anisotropy induced by solvent molecules
journal, January 2017

  • Cao, Wenhai; Zhu, Xiaoquan; Liu, Pengfei
  • Dalton Transactions, Vol. 46, Issue 11
  • DOI: 10.1039/c6dt04420d

Inter-ligand electronic coupling mediated through a dimetal bridge: dependence on metal ions and ancillary ligands
journal, January 2017

  • Majumdar, Moumita; Saha, Sayantani; Dutta, Indranil
  • Dalton Transactions, Vol. 46, Issue 17
  • DOI: 10.1039/c6dt04679g

Thermal expansion and magnetic properties of benzoquinone-bridged dinuclear rare-earth complexes
journal, January 2017

  • Moilanen, Jani O.; Mansikkamäki, Akseli; Lahtinen, Manu
  • Dalton Trans., Vol. 46, Issue 39
  • DOI: 10.1039/c7dt02565c

[Ln 16 ] complexes (Ln = Gd III , Dy III ): molecular analogues of natural minerals such as hydrotalcite
journal, January 2018

  • Richardson, Paul; Hsu, Ting-Jung; Kuo, Che-Jung
  • Dalton Transactions, Vol. 47, Issue 37
  • DOI: 10.1039/c8dt02609b

Electrochemical and spectroscopic properties of a cobalt framework with (3,7)-c topology
journal, January 2019

  • Hua, Carol; D'Alessandro, Deanna M.
  • CrystEngComm, Vol. 21, Issue 14
  • DOI: 10.1039/c9ce00050j

Ligand mixed-valence and electrical conductivity in coordination complexes containing a redox-active phenalenol-substituted ligand
journal, January 2019

  • Dale, Sarah; Bonanno, Nico M.; Pelaccia, Mark
  • Dalton Transactions, Vol. 48, Issue 23
  • DOI: 10.1039/c9dt01788g

Redox-active metal–organic frameworks for energy conversion and storage
journal, January 2019

  • Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron
  • Journal of Materials Chemistry A, Vol. 7, Issue 28
  • DOI: 10.1039/c9ta04680a

Elucidating metal and ligand redox activities of a copper-benzoquinoid coordination polymer as the cathode for lithium-ion batteries
journal, January 2019

  • Chang, Cheng-Han; Li, An-Che; Popovs, Ilja
  • Journal of Materials Chemistry A, Vol. 7, Issue 41
  • DOI: 10.1039/c9ta05244e

A chlorine-free protocol for processing germanium
journal, May 2017

  • Glavinović, Martin; Krause, Michael; Yang, Linju
  • Science Advances, Vol. 3, Issue 5
  • DOI: 10.1126/sciadv.1700149

A Two-Dimensional Coordination Polymer Based on 1,1':4',1''-Terphenyl-2',4,4'',5'-tetracarboxylate
journal, May 2018


The role of reticular chemistry in the design of CO2 reduction catalysts
journal, February 2018


A Series of Early Lanthanide Chloranilate Frameworks with a Square Grid Topology
journal, January 2019

  • Hua, Carol; Tay, Hui Min; He, Qilin
  • Australian Journal of Chemistry, Vol. 72, Issue 10
  • DOI: 10.1071/ch19193

Novel semiconducting iron–quinizarin metal–organic framework for application in supercapacitors
journal, August 2019


An Organic Mixed-Valence Ligand for Multistate Redox-Active Coordination Networks
journal, March 2018

  • Ha, Joo Yeon; Koo, Jin Young; Ohtsu, Hiroyoshi
  • Angewandte Chemie International Edition, Vol. 57, Issue 17
  • DOI: 10.1002/anie.201713035

Thermally Induced Valence Tautomeric Transition in a Two-Dimensional Fe-Tetraoxolene Honeycomb Network
journal, August 2018

  • Chen, Jian; Sekine, Yoshihiro; Komatsumaru, Yuki
  • Angewandte Chemie International Edition, Vol. 57, Issue 37
  • DOI: 10.1002/anie.201807556

A Dicobalt Complex with an Unsymmetrical Quinonoid Bridge Isolated in Three Units of Charge: A Combined Structural, (Spectro)electrochemical, Magnetic and Spectroscopic Study
journal, August 2016

  • van der Meer, Margarethe; Rechkemmer, Yvonne; Frank, Uta
  • Chemistry - A European Journal, Vol. 22, Issue 39
  • DOI: 10.1002/chem.201601579

Isovalent Ag III /Ag III , Ag II /Ag II , Mixed-Valent Ag II /Ag III , and Corrolato-Based Mixed-Valency in β,β′-Linked [Bis{corrolato-silver}] n Complexes
journal, September 2017

  • Patra, Bratati; Sobottka, Sebastian; Sinha, Woormileela
  • Chemistry - A European Journal, Vol. 23, Issue 56
  • DOI: 10.1002/chem.201703512

Redox‐Reversible 2D Metal–Organic Framework Nanosheets (MONs) Based on the Hydroquinone/Quinone Couple
journal, February 2019

  • Maka, Vijay Kumar; Mukhopadhyay, Arindam; Jindal, Swati
  • Chemistry – A European Journal, Vol. 25, Issue 15
  • DOI: 10.1002/chem.201805188

Square Grid Metal–Chloranilate Networks as Robust Host Systems for Guest Sorption
journal, March 2019

  • Kingsbury, Christopher J.; Abrahams, Brendan F.; Auckett, Josie E.
  • Chemistry – A European Journal, Vol. 25, Issue 20
  • DOI: 10.1002/chem.201805600

A coronene-based semiconducting two-dimensional metal-organic framework with ferromagnetic behavior
journal, July 2018


Integration of a (–Cu–S–)n plane in a metal–organic framework affords high electrical conductivity
journal, April 2019


Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry
journal, September 2018

  • Pedersen, Kasper S.; Perlepe, Panagiota; Aubrey, Michael L.
  • Nature Chemistry, Vol. 10, Issue 10
  • DOI: 10.1038/s41557-018-0107-7

The role of reticular chemistry in the design of CO2 reduction catalysts
journal, February 2018


Cuboctahedron-based indium–organic frameworks for gas sorption and selective cation exchange
journal, January 2016

  • Yu, Panpan; Li, Qipeng; Hu, Yue
  • Chemical Communications, Vol. 52, Issue 51
  • DOI: 10.1039/c6cc03497g

Zinc and cadmium complexes based on bis-(1H-tetrazol-5-ylmethyl/ylethyl)-amine ligands: structures and photoluminescence properties
journal, January 2016

  • Wang, Duo-Zhi; Fan, Jian-Zhong; Jia, Dianzeng
  • CrystEngComm, Vol. 18, Issue 35
  • DOI: 10.1039/c6ce01311b

A microporous europium–organic framework anchored with open –COOH groups for selective cation sensing
journal, January 2016

  • Qian, Jinjie; Yu, Panpan; Huang, Shaoming
  • CrystEngComm, Vol. 18, Issue 41
  • DOI: 10.1039/c6ce01801g

A 1,2,3-dithiazolyl-o-naphthoquinone: a neutral radical with isolable cation and anion oxidation states
journal, January 2016

  • Smithson, Chad S.; MacDonald, Daniel J.; Matt Letvenuk, T.
  • Dalton Transactions, Vol. 45, Issue 23
  • DOI: 10.1039/c6dt01249c

Chiral heterobimetallic chains from a dicyanideferrite building block including a π-conjugated TTF annulated ligand
journal, January 2016

  • Cui, Long; Lv, Zhong-Peng; Leong, Chanel F.
  • Dalton Transactions, Vol. 45, Issue 42
  • DOI: 10.1039/c6dt01756h

Tuning the iron redox state inside a microporous porphyrinic metal organic framework
journal, January 2017

  • Abeykoon, Brian; Grenèche, Jean-Marc; Jeanneau, Erwann
  • Dalton Transactions, Vol. 46, Issue 2
  • DOI: 10.1039/c6dt04208b

Syntheses, structures and magnetic properties of nine coordination polymers based on terphenyl-tetracarboxylic acid ligands
journal, January 2017

  • Zhou, Xinhui; Chen, Qianqian; Liu, Baolin
  • Dalton Transactions, Vol. 46, Issue 2
  • DOI: 10.1039/c6dt04270h

Benzoquinone-bridged Co 2 complexes with different magnetic anisotropy induced by solvent molecules
journal, January 2017

  • Cao, Wenhai; Zhu, Xiaoquan; Liu, Pengfei
  • Dalton Transactions, Vol. 46, Issue 11
  • DOI: 10.1039/c6dt04420d

Inter-ligand electronic coupling mediated through a dimetal bridge: dependence on metal ions and ancillary ligands
journal, January 2017

  • Majumdar, Moumita; Saha, Sayantani; Dutta, Indranil
  • Dalton Transactions, Vol. 46, Issue 17
  • DOI: 10.1039/c6dt04679g

The organic-moiety-dominated Li + intercalation/deintercalation mechanism of a cobalt-based metal–organic framework
journal, January 2016

  • Li, Chao; Hu, Xiaoshi; Lou, Xiaobing
  • Journal of Materials Chemistry A, Vol. 4, Issue 41
  • DOI: 10.1039/c6ta06413b

Thermal expansion and magnetic properties of benzoquinone-bridged dinuclear rare-earth complexes
journal, January 2017

  • Moilanen, Jani O.; Mansikkamäki, Akseli; Lahtinen, Manu
  • Dalton Trans., Vol. 46, Issue 39
  • DOI: 10.1039/c7dt02565c

[Ln 16 ] complexes (Ln = Gd III , Dy III ): molecular analogues of natural minerals such as hydrotalcite
journal, January 2018

  • Richardson, Paul; Hsu, Ting-Jung; Kuo, Che-Jung
  • Dalton Transactions, Vol. 47, Issue 37
  • DOI: 10.1039/c8dt02609b

Electrochemical and spectroscopic properties of a cobalt framework with (3,7)-c topology
journal, January 2019

  • Hua, Carol; D'Alessandro, Deanna M.
  • CrystEngComm, Vol. 21, Issue 14
  • DOI: 10.1039/c9ce00050j

Ligand mixed-valence and electrical conductivity in coordination complexes containing a redox-active phenalenol-substituted ligand
journal, January 2019

  • Dale, Sarah; Bonanno, Nico M.; Pelaccia, Mark
  • Dalton Transactions, Vol. 48, Issue 23
  • DOI: 10.1039/c9dt01788g

Redox-active metal–organic frameworks for energy conversion and storage
journal, January 2019

  • Calbo, Joaquín; Golomb, Matthias J.; Walsh, Aron
  • Journal of Materials Chemistry A, Vol. 7, Issue 28
  • DOI: 10.1039/c9ta04680a

Elucidating metal and ligand redox activities of a copper-benzoquinoid coordination polymer as the cathode for lithium-ion batteries
journal, January 2019

  • Chang, Cheng-Han; Li, An-Che; Popovs, Ilja
  • Journal of Materials Chemistry A, Vol. 7, Issue 41
  • DOI: 10.1039/c9ta05244e

A Series of Early Lanthanide Chloranilate Frameworks with a Square Grid Topology
journal, January 2019

  • Hua, Carol; Tay, Hui Min; He, Qilin
  • Australian Journal of Chemistry, Vol. 72, Issue 10
  • DOI: 10.1071/ch19193

Novel semiconducting iron–quinizarin metal–organic framework for application in supercapacitors
journal, August 2019


A chlorine-free protocol for processing germanium
journal, May 2017

  • Glavinović, Martin; Krause, Michael; Yang, Linju
  • Science Advances, Vol. 3, Issue 5
  • DOI: 10.1126/sciadv.1700149

A Two-Dimensional Coordination Polymer Based on 1,1':4',1''-Terphenyl-2',4,4'',5'-tetracarboxylate
journal, May 2018


Strong antiferromagnetic coupling of the cobalt( ii )–semiquinone radical in a dinuclear complex with 2,2′-bipyrimidine ligands
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  • New Journal of Chemistry
  • DOI: 10.1039/d0nj00767f

New functionalized acenaphthene-1,2-diimines and derived zinc and copper complexes
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  • Sokolov, V. G.; Moskalev, M. V.; Koptseva, T. S.
  • Russian Chemical Bulletin, Vol. 69, Issue 1
  • DOI: 10.1007/s11172-020-2733-7