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Title: Standard Electrode Potentials Involving Radicals in Aqueous Solution: Inorganic Radicals

Abstract

Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pK a’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations

Authors:
; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences, and Biosciences Division
OSTI Identifier:
1236950
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Pure and Applied Chemistry (Online)
Additional Journal Information:
Journal Volume: 87; Journal ID: ISSN 1365-3075
Publisher:
de Gruyter
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Active Thermochemical Tables; Thermochemical Network; aqueous thermochemistry; electrode potentials; enthalpy of formation; free energy; thermochemistry

Citation Formats

Armstrong, David A., Huie, Robert E., Koppenol, Willem H., Lymar, Sergei V., Merenyi, Gabor, Neta, Pedatsur, Ruscic, Branko, Stanbury, David M., Steenken, Steen, and Wardman, Peter. Standard Electrode Potentials Involving Radicals in Aqueous Solution: Inorganic Radicals. United States: N. p., 2015. Web. doi:10.1515/pac-2014-0502.
Armstrong, David A., Huie, Robert E., Koppenol, Willem H., Lymar, Sergei V., Merenyi, Gabor, Neta, Pedatsur, Ruscic, Branko, Stanbury, David M., Steenken, Steen, & Wardman, Peter. Standard Electrode Potentials Involving Radicals in Aqueous Solution: Inorganic Radicals. United States. doi:10.1515/pac-2014-0502.
Armstrong, David A., Huie, Robert E., Koppenol, Willem H., Lymar, Sergei V., Merenyi, Gabor, Neta, Pedatsur, Ruscic, Branko, Stanbury, David M., Steenken, Steen, and Wardman, Peter. Tue . "Standard Electrode Potentials Involving Radicals in Aqueous Solution: Inorganic Radicals". United States. doi:10.1515/pac-2014-0502.
@article{osti_1236950,
title = {Standard Electrode Potentials Involving Radicals in Aqueous Solution: Inorganic Radicals},
author = {Armstrong, David A. and Huie, Robert E. and Koppenol, Willem H. and Lymar, Sergei V. and Merenyi, Gabor and Neta, Pedatsur and Ruscic, Branko and Stanbury, David M. and Steenken, Steen and Wardman, Peter},
abstractNote = {Recommendations are made for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. The recommended data are summarized in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations},
doi = {10.1515/pac-2014-0502},
journal = {Pure and Applied Chemistry (Online)},
issn = {1365-3075},
number = ,
volume = 87,
place = {United States},
year = {2015},
month = {12}
}

Works referenced in this record:

A Fundamental Equation of State for Heavy Water
journal, January 1982

  • Hill, P. G.; MacMillan, R. D. Chris; Lee, V.
  • Journal of Physical and Chemical Reference Data, Vol. 11, Issue 1
  • DOI: 10.1063/1.555661

Names for inorganic radicals (IUPAC Recommendations 2000)
journal, January 2000


    Works referencing / citing this record:

    A bi-functional cobalt-porphyrinoid electrocatalyst: balance between overpotential and selectivity
    journal, May 2019