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Title: A versatile synthetic route for the preparation of titanium metal–organic frameworks

Abstract

Through a versatile synthetic strategy, High Valence Metathesis and Oxidation (HVMO), a series of Ti-MOFs with predesigned topologies and structures were synthesized.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Texas A&M Univ., College Station, TX (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office; USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1236869
Alternate Identifier(s):
OSTI ID: 1386963
Grant/Contract Number:  
SC0001015
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 7; Journal Issue: 2; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; membrane, carbon capture, materials and chemistry by design, synthesis (novel materials), synthesis (self-assembly), synthesis (scalable processing)

Citation Formats

Zou, Lanfang, Feng, Dawei, Liu, Tian-Fu, Chen, Ying-Pin, Yuan, Shuai, Wang, Kecheng, Wang, Xuan, Fordham, Stephen, and Zhou, Hong-Cai. A versatile synthetic route for the preparation of titanium metal–organic frameworks. United States: N. p., 2015. Web. doi:10.1039/C5SC03620H.
Zou, Lanfang, Feng, Dawei, Liu, Tian-Fu, Chen, Ying-Pin, Yuan, Shuai, Wang, Kecheng, Wang, Xuan, Fordham, Stephen, & Zhou, Hong-Cai. A versatile synthetic route for the preparation of titanium metal–organic frameworks. United States. https://doi.org/10.1039/C5SC03620H
Zou, Lanfang, Feng, Dawei, Liu, Tian-Fu, Chen, Ying-Pin, Yuan, Shuai, Wang, Kecheng, Wang, Xuan, Fordham, Stephen, and Zhou, Hong-Cai. 2015. "A versatile synthetic route for the preparation of titanium metal–organic frameworks". United States. https://doi.org/10.1039/C5SC03620H. https://www.osti.gov/servlets/purl/1236869.
@article{osti_1236869,
title = {A versatile synthetic route for the preparation of titanium metal–organic frameworks},
author = {Zou, Lanfang and Feng, Dawei and Liu, Tian-Fu and Chen, Ying-Pin and Yuan, Shuai and Wang, Kecheng and Wang, Xuan and Fordham, Stephen and Zhou, Hong-Cai},
abstractNote = {Through a versatile synthetic strategy, High Valence Metathesis and Oxidation (HVMO), a series of Ti-MOFs with predesigned topologies and structures were synthesized.},
doi = {10.1039/C5SC03620H},
url = {https://www.osti.gov/biblio/1236869}, journal = {Chemical Science},
issn = {2041-6520},
number = 2,
volume = 7,
place = {United States},
year = {Mon Nov 02 00:00:00 EST 2015},
month = {Mon Nov 02 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 89 works
Citation information provided by
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Figures / Tables:

Fig. 1 Fig. 1: Schematic illustration of the stepwise HVMO procedure for the design of Ti-MOFs from the template MOFs: (a) MIL-100(Sc) and PCN-333(Sc) metal metathesis with Ti(III), followed by metal node oxidation in the air (PCN-333(Sc) and MIL-100(Sc) have same topology but different structures); (b) similar process for MOF-74(Zn) and MOF-74(Mg).

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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.