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Title: Transparent TiO2 nanotube array photoelectrodes prepared via two-step anodization

Journal Article · · Nano Convergence
 [1];  [2];  [2];  [2]
  1. Korea Institute of Science and Technology (KIST), Seoul (Republic of Korea); Korea Univ., Seoul (South Korea)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)

Two-step anodization of transparent TiO2 nanotube arrays has been demonstrated with aid of a Nb-doped TiO2 buffer layer deposited between the Ti layer and TCO substrate. Enhanced physical adhesion and electrochemical stability provided by the buffer layer has been found to be important for successful implementation of the two-step anodization process. As a result, with the proposed approach, the morphology and thickness of NT arrays could be controlled very precisely, which in turn, influenced their optical and photoelectrochemical properties.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1236450
Report Number(s):
NREL/JA-5900-61266
Journal Information:
Nano Convergence, Vol. 1, Issue 1; Related Information: Nano Convergence; ISSN 2196-5404
Country of Publication:
United States
Language:
English

References (28)

Use of Highly-Ordered TiO 2 Nanotube Arrays in Dye-Sensitized Solar Cells journal February 2006
Smooth Anodic TiO2 Nanotubes journal November 2005
A review on highly ordered, vertically oriented TiO2 nanotube arrays: Fabrication, material properties, and solar energy applications journal September 2006
Fabrication of Gold Nanodot Array Using Anodic Porous Alumina as an Evaporation Mask journal January 1996
Novel Carbon-Doped TiO 2 Nanotube Arrays with High Aspect Ratios for Efficient Solar Water Splitting journal January 2006
The Effect of Electrolyte Composition on the Fabrication of Self-Organized Titanium Oxide Nanotube Arrays by Anodic Oxidation journal January 2005
Enhanced Charge-Collection Efficiencies and Light Scattering in Dye-Sensitized Solar Cells Using Oriented TiO 2 Nanotubes Arrays journal January 2007
A New Benchmark for TiO 2 Nanotube Array Growth by Anodization journal May 2007
A Tracer Study of Porous Anodic Alumina journal January 2006
Transparent Highly Ordered TiO2 Nanotube Arrays via Anodization of Titanium Thin Films journal August 2005
Self-Organized Regular Arrays of Anodic TiO 2 Nanotubes journal October 2008
Long vertically aligned titania nanotubes on transparent conducting oxide for highly efficient solar cells journal August 2009
TiO2 nanotubes: H+insertion and strong electrochromic effects journal April 2006
TiO 2 Nanotubes with Tunable Morphology, Diameter, and Length: Synthesis and Photo-Electrical/Catalytic Performance journal March 2009
High-efficiency (7.2%) flexible dye-sensitized solar cells with Ti-metal substrate for nanocrystalline-TiO2photoanode journal January 2006
Enhanced Photocleavage of Water Using Titania Nanotube Arrays journal January 2005
High-Efficiency and Stable Mesoscopic Dye-Sensitized Solar Cells Based on a High Molar Extinction Coefficient Ruthenium Sensitizer and Nonvolatile Electrolyte journal April 2007
Removing Structural Disorder from Oriented TiO 2 Nanotube Arrays:  Reducing the Dimensionality of Transport and Recombination in Dye-Sensitized Solar Cells journal December 2007
Transparent TiO2 Nanotube Electrodes via Thin Layer Anodization: Fabrication and Use in Electrochromic Devices journal March 2009
General Strategy for Fabricating Transparent TiO 2 Nanotube Arrays for Dye-Sensitized Photoelectrodes: Illumination Geometry and Transport Properties journal March 2011
Towards ideal hexagonal self-ordering of TiO2 nanotubes journal October 2007
Fast formation of thick and transparent titania nanotubular films from sputtered Ti journal June 2009
Dye-sensitized anodic TiO2 nanotubes journal November 2005
Constructing Ordered Sensitized Heterojunctions: Bottom-Up Electrochemical Synthesis of p-Type Semiconductors in Oriented n-TiO 2 Nanotube Arrays journal February 2009
A Novel Protocol Toward Perfect Alignment of Anodized TiO2Nanotubes journal May 2009
Individually addressable epitaxial ferroelectric nanocapacitor arrays with near Tb inch−2 density journal June 2008
Dye-Sensitized Solar Cells Based on Oriented TiO 2 Nanotube Arrays: Transport, Trapping, and Transfer of Electrons journal October 2008
Application of Highly Ordered TiO 2 Nanotube Arrays in Flexible Dye-Sensitized Solar Cells journal May 2008