In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures

Bell, Nelson S.; Dunphy, Darren R.; Lambert, Timothy N.; Lu, Ping; Boyle, Timothy J.

doi:10.1016/j.colsurfb.2015.06.030

Title: In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures

Journal Article · Fri Jun 26 00:00:00 EDT 2015 · Colloids and Surfaces. B, Biointerfaces

DOI:https://doi.org/10.1016/j.colsurfb.2015.06.030· OSTI ID:1236240

Bell, Nelson S. ^[1]; Dunphy, Darren R. ^[2]; Lambert, Timothy N. ^[1]; Lu, Ping ^[1]; Boyle, Timothy J. ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Univ. of New Mexico, Albuquerque, NM (United States)

In this study, the use of maltodextrin supramolecular structures (MD SMS) as a reducing agent and colloidal stabilizing agent for the synthesis of Ag nanoparticles (Ag NPs) identified three key points. First, the maltodextrin (MD) solutions are effective in the formation of well-dispersed Ag NPs utilizing alkaline solution conditions, with the resulting Ag NPs ranging in size from 5 to 50 nm diameter. Second, in situ characterization by Raman spectroscopy and small angle X-ray scattering (SAXS) are consistent with initial nucleation of Ag NPs within the MD SMS up to a critical size of ca. 1 nm, followed by a transition to more rapid growth by aggregation and fusion between MD SMS, similar to micelle aggregation reactions. Third, the stabilization of larger Ag NPs by adsorbed MD SMS is similar to hemi-micelle stabilization, and monomodal size distributions are proposed to relate to integer surface coverage of the Ag NPs. Conditions were identified for preparing Ag NPs with monomodal distributions centered at 30–35 nm Ag NPs.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1236240

Alternate ID(s):: OSTI ID: 1358968

Report Number(s):: SAND-2015-1001J; 566969

Journal Information:: Colloids and Surfaces. B, Biointerfaces, Vol. 134, Issue C; ISSN 0927-7765

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 2 works

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