Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer
Abstract
Multiphase, reactive transport modeling was used to identify the mechanisms controlling trace metal release under elevated CO2 conditions from a well-characterized carbonate aquifer. Modeling was conducted for two experimental scenarios: batch experiments to simulate sudden, fast, and short-lived release of CO2 as would occur in the case of well failure during injection, and column experiments to simulate more gradual leaks such as those occurring along undetected faults, fractures, or well linings. Observed and predicted trace metal concentrations are compared to groundwater concentrations from this aquifer to determine the potential for leaking CO2 to adversely impact drinking water quality. Finally, a three-dimensional multiphase flow and reactive-transport simulation of CO2 leakage from an abandoned wellbore into a generalized model of the shallow, unconfined portion of the aquifer is used to determine potential impacts on groundwater quality. As a measure of adverse impacts on groundwater quality, both the EPA’s MCL limits and the maximum trace metal concentration observed in the aquifer were used as threshold values.
- Authors:
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1234785
- Report Number(s):
- PNNL-SA-105184
Journal ID: ISSN 1750-5836; AA9010200
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Journal Article
- Journal Name:
- International Journal of Greenhouse Gas Control
- Additional Journal Information:
- Journal Volume: 44; Journal ID: ISSN 1750-5836
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Aquifer; CO2; modeling; PHREEQc; STOMP; trace metals.
Citation Formats
Bacon, Diana H., Qafoku, Nikolla, Dai, Zhenxue, Keating, Elizabeth, and Brown, Christopher F. Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer. United States: N. p., 2016.
Web. doi:10.1016/j.ijggc.2015.04.008.
Bacon, Diana H., Qafoku, Nikolla, Dai, Zhenxue, Keating, Elizabeth, & Brown, Christopher F. Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer. United States. https://doi.org/10.1016/j.ijggc.2015.04.008
Bacon, Diana H., Qafoku, Nikolla, Dai, Zhenxue, Keating, Elizabeth, and Brown, Christopher F. 2016.
"Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer". United States. https://doi.org/10.1016/j.ijggc.2015.04.008.
@article{osti_1234785,
title = {Modeling the Impact of Carbon Dioxide Leakage into an Unconfined, Oxidizing Carbonate Aquifer},
author = {Bacon, Diana H. and Qafoku, Nikolla and Dai, Zhenxue and Keating, Elizabeth and Brown, Christopher F.},
abstractNote = {Multiphase, reactive transport modeling was used to identify the mechanisms controlling trace metal release under elevated CO2 conditions from a well-characterized carbonate aquifer. Modeling was conducted for two experimental scenarios: batch experiments to simulate sudden, fast, and short-lived release of CO2 as would occur in the case of well failure during injection, and column experiments to simulate more gradual leaks such as those occurring along undetected faults, fractures, or well linings. Observed and predicted trace metal concentrations are compared to groundwater concentrations from this aquifer to determine the potential for leaking CO2 to adversely impact drinking water quality. Finally, a three-dimensional multiphase flow and reactive-transport simulation of CO2 leakage from an abandoned wellbore into a generalized model of the shallow, unconfined portion of the aquifer is used to determine potential impacts on groundwater quality. As a measure of adverse impacts on groundwater quality, both the EPA’s MCL limits and the maximum trace metal concentration observed in the aquifer were used as threshold values.},
doi = {10.1016/j.ijggc.2015.04.008},
url = {https://www.osti.gov/biblio/1234785},
journal = {International Journal of Greenhouse Gas Control},
issn = {1750-5836},
number = ,
volume = 44,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 2016},
month = {Fri Jan 01 00:00:00 EST 2016}
}