Systems, compositions, and methods for fluid purification

Ho, W. S. Winston; Verweij, Hendrik; Shqau, Krenar; Ramasubranian, Kartik

Systems, compositions, and methods for fluid purification

Patent · 22 December 2015

OSTI ID:1233380

Ho, W. S. Winston; Verweij, Hendrik; Shqau, Krenar; Ramasubranian, Kartik

Disclosed herein are membranes comprising a substrate, a support layer, and a selective layer. In some embodiments the membrane may further comprise a permeable layer. Methods of forming membranes are also disclosed comprising forming a support layer on a substrate, removing adsorbed species from the support layer, preparing a solution containing inorganic materials of a selective layer, contacting the support layer with the solution, drying the membrane, and exposing the membrane to rapid thermal processing. Also disclosed are methods of fluid purification comprising providing a membrane having a feed side and a permeable side, passing a fluid mixture across the feed side of the membrane, providing a driving force for transmembrane permeation, removing from the permeate side a permeate stream enriched in a purified fluid, and withdrawing from the feed side a fluid that is depleted in a purified fluid.

View Patent

Research Organization:: Ohio State Innovation Foundation, Columbus, OH (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: FG02-06ER15776

Assignee:: Ohio State Innovation Foundation (Columbus, OH)

Patent Number(s):: 9,216,390

Application Number:: 13/184,433

OSTI ID:: 1233380

Country of Publication:: United States

Language:: English

References (45)

Selective Defect-Patching of Zeolite Membranes Using Chemical Liquid Deposition at Organic/Aqueous Interfaces Zhang, Baoquan; Wang, Cong; Lang, Lin Advanced Functional Materials, Vol. 18, Issue 21, p. 3434-3443 https://doi.org/10.1002/adfm.200800054	journal	November 2008
CO₂ sorption of a thin silica layer determined by spectroscopic ellipsometry Benes, Nieck E.; Spijksma, Gerald; Verweij, Henk AIChE Journal, Vol. 47, Issue 5, p. 1212-1218 https://doi.org/10.1002/aic.690470527	journal	May 2001
Permeability of silicone polymers to hydrogen Bhide, B. D.; Stern, S. A. Journal of Applied Polymer Science, Vol. 42, Issue 9, p. 2397-2403 https://doi.org/10.1002/app.1991.070420904	journal	May 1991
Synthesis and characterization of new polybenzimidazopyrrolones derived from pyridine-bridged aromatic tetraamines and dianhydrides Liu, Jin-Gang; Wang, Li-Fang; Yang, Hai-Xia Journal of Polymer Science Part A: Polymer Chemistry, Vol. 42, Issue 8 https://doi.org/10.1002/pola.20030	journal	January 2004
Membrane Handbook Ho, W. S. Winston; Sirkar, Kamalesh K. https://doi.org/10.1007/978-1-4615-3548-5	book	January 1992
Supported inorganic membranes: Promises and challenges Zhang, Lanlin; Park, In-Soo; Shqau, Krenar JOM, Vol. 61, Issue 4 https://doi.org/10.1007/s11837-009-0054-2	journal	April 2009
Surface diffusion of tetramethylsilane and neopentane on Ru(001) Westre, E. D.; Arena, M. V.; Deckert, A. A. Surface Science, Vol. 233, Issue 3, p. 293-307 https://doi.org/10.1016/0039-6028(90)90642-L	journal	July 1990
Formation and characterization of supported microporous ceramic membranes prepared by sol-gel modification techniques de Lange, R. S. A.; Hekkink, J. H. A.; Keizer, K. Journal of Membrane Science, Vol. 99, Issue 1, p. 57-75 https://doi.org/10.1016/0376-7388(94)00206-E	journal	February 1995
Prediction of flux and selectivity in pervaporation through a membrane Doong, S. J.; Ho, W. S.; Mastondrea, R. P. Journal of Membrane Science, Vol. 107, Issue 1-2, p. 129-146 https://doi.org/10.1016/0376-7388(95)00109-P	journal	November 1995
Stationary and transient kinetics of the high temperature water-gas shift reaction Keiski, Riitta L.; Salmi, Tapio; Niemistö, Pekka Applied Catalysis A: General, Vol. 137, Issue 2, p. 349-370 https://doi.org/10.1016/0926-860X(95)00315-0	journal	April 1996
Multi-component lattice gas diffusion Benes, Nieck E.; Bouwmeester, Henny J. M.; Verweij, Henk Chemical Engineering Science, Vol. 57, Issue 14, p. 2673-2678 https://doi.org/10.1016/S0009-2509(02)00154-9	journal	July 2002
Improvement of ethanol selectivity of silicalite membrane in pervaporation by silicone rubber coating Matsuda, H.; Yanagishita, H.; Negishi, H. Journal of Membrane Science, Vol. 210, Issue 2, p. 433-437 https://doi.org/10.1016/S0376-7388(02)00364-2	journal	December 2002
Capillary carbon molecular sieve membranes derived from Kapton for high temperature gas separation Petersen, Joachim; Matsuda, Masaji; Haraya, Kenji Journal of Membrane Science, Vol. 131, Issue 1-2, p. 85-94 https://doi.org/10.1016/S0376-7388(97)00041-0	journal	August 1997
A study of silicone rubber/polysulfone composite membranes: correlating H₂/N₂ and O₂/N₂ permselectivities Feng, Xianshe; Shao, Pinghai; Huang, Robert Y. M. Separation and Purification Technology, Vol. 27, Issue 3, p. 211-223 https://doi.org/10.1016/S1383-5866(01)00196-4	journal	June 2002
Membrane processes for post-combustion carbon dioxide capture: A parametric study Bounaceur, R.; Lape, N.; Roizard, D. Energy, Vol. 31, Issue 14 https://doi.org/10.1016/j.energy.2005.10.038	journal	November 2006
Synthesis of Pd particle-deposited microporous silica membranes via a vacuum-impregnation method and their gas permeation behavior Lee, Dong-Wook; Yu, Chang-Yeol; Lee, Kew-Ho Journal of Colloid and Interface Science, Vol. 325, Issue 2, p. 447-452 https://doi.org/10.1016/j.jcis.2008.06.021	journal	September 2008
Characterization of silicone rubber membrane materials at low temperature and low pressure conditions Jha, Praveen; Mason, Larry W.; Douglas Way, J. Journal of Membrane Science, Vol. 272, Issue 1-2, p. 125-136 https://doi.org/10.1016/j.memsci.2005.07.039	journal	March 2006
Carbon dioxide recovery from post-combustion processes: Can gas permeation membranes compete with absorption? Favre, Eric Journal of Membrane Science, Vol. 294, Issue 1-2, p. 50-59 https://doi.org/10.1016/j.memsci.2007.02.007	journal	May 2007
Permeation porometry: Effect of probe diffusion in the condensate Mottern, M. L.; Shqau, K.; Zalar, F. Journal of Membrane Science, Vol. 313, Issue 1-2, p. 2-8 https://doi.org/10.1016/j.memsci.2007.08.053	journal	April 2008
Micro-structural optimization of supported γ-alumina membranes Kuzniatsova, T.; Mottern, M. L.; Shqau, K. Journal of Membrane Science, Vol. 316, Issue 1-2, p. 80-88 https://doi.org/10.1016/j.memsci.2007.11.047	journal	May 2008
Upgrading low-quality natural gas with H₂S- and CO₂-selective polymer membranes Hao, J.; Rice, P. A.; Stern, S. A. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 108-122 https://doi.org/10.1016/j.memsci.2008.03.040	journal	July 2008
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Tubular ceramic-supported sol–gel silica-based membranes for flue gas carbon dioxide capture and sequestration Xomeritakis, G.; Tsai, C. Y.; Jiang, Y. B. Journal of Membrane Science, Vol. 341, Issue 1-2, p. 30-36 https://doi.org/10.1016/j.memsci.2009.05.024	journal	September 2009
Power plant post-combustion carbon dioxide capture: An opportunity for membranes Merkel, Tim C.; Lin, Haiqing; Wei, Xiaotong Journal of Membrane Science, Vol. 359, Issue 1-2, p. 126-139 https://doi.org/10.1016/j.memsci.2009.10.041	journal	September 2010
Robust method for micro-porous silica membrane fabrication Luiten, M. W. J.; Benes, Nieck E.; Huiskes, Cindy Journal of Membrane Science, Vol. 348, Issue 1-2, p. 1-5 https://doi.org/10.1016/j.memsci.2009.11.029	journal	February 2010
Blocking defects in SAPO-34 membranes with cyclodextrin Zhang, Yanfeng; Avila, Adolfo M.; Tokay, Begum Journal of Membrane Science, Vol. 358, Issue 1-2, p. 7-12 https://doi.org/10.1016/j.memsci.2010.04.006	journal	August 2010
Rapid thermal processing of inorganic membranes Schillo, M. C.; Park, I.-S.; Chiu, W. V. Journal of Membrane Science, Vol. 362, Issue 1-2, p. 127-133 https://doi.org/10.1016/j.memsci.2010.06.030	journal	October 2010
Microporous niobia–silica membranes: Influence of sol composition and structure on gas transport properties Boffa, V.; ten Elshof, J. E.; Garcia, R. Microporous and Mesoporous Materials, Vol. 118, Issue 1-3, p. 202-209 https://doi.org/10.1016/j.micromeso.2008.08.038	journal	February 2009
Evaluation of energy consumption for separation of CO₂ in flue gas by hollow fiber facilitated transport membrane module with permeation of amine solution Matsumiya, Norifumi; Teramoto, Masaaki; Kitada, Satoshi Separation and Purification Technology, Vol. 46, Issue 1-2, p. 26-32 https://doi.org/10.1016/j.seppur.2005.04.006	journal	November 2005
Palladium and palladium alloy membranes for hydrogen separation and production: History, fabrication strategies, and current performance Hatlevik, Øyvind; Gade, Sabina K.; Keeling, Matthew K. Separation and Purification Technology, Vol. 73, Issue 1 https://doi.org/10.1016/j.seppur.2009.10.020	journal	May 2010
Textured indium tin oxide thin films by chemical solution deposition and rapid thermal processing Mottern, Matthew L.; Tyholdt, Frode; Ulyashin, Alexander Thin Solid Films, Vol. 515, Issue 7-8, p. 3918-3926 https://doi.org/10.1016/j.tsf.2006.11.015	journal	February 2007
Diffusion of hydrocarbons in polyethylene Doong, Shain J.; Ho, W. S. Winston Industrial & Engineering Chemistry Research, Vol. 31, Issue 4 https://doi.org/10.1021/ie00004a013	journal	April 1992
Sorption of organic vapors in polyethylene Doong, Shain J.; Ho, W. S. Winston Industrial & Engineering Chemistry Research, Vol. 30, Issue 6 https://doi.org/10.1021/ie00054a042	journal	June 1991
Synthesis and Characterization of Silica Membranes Prepared by Pyridine-Catalyzed Atomic Layer Deposition McCool, Benjamin A.; DeSisto, William J. Industrial & Engineering Chemistry Research, Vol. 43, Issue 10 https://doi.org/10.1021/ie030829x	journal	May 2004
Carbon Dioxide Capture Using a CO ₂ -Selective Facilitated Transport Membrane Huang, Jin; Zou, Jian; Ho, W. S. Winston Industrial & Engineering Chemistry Research, Vol. 47, Issue 4 https://doi.org/10.1021/ie070794r	journal	February 2008
Reducing the Cost of CO ₂ Capture from Flue Gases Using Pressure Swing Adsorption Ho, Minh T.; Allinson, Guy W.; Wiley, Dianne E. Industrial & Engineering Chemistry Research, Vol. 47, Issue 14 https://doi.org/10.1021/ie070831e	journal	July 2008
Silicalite Membranes Modified by Counterdiffusion CVD Technique Nomura, Mikihiro; Yamaguchi, Takeo; Nakao, Shin-ichi Industrial & Engineering Chemistry Research, Vol. 36, Issue 10 https://doi.org/10.1021/ie970338a	journal	October 1997
Synthesis of Ultrathin Zeolite Y Membranes and their Application for Separation of Carbon Dioxide and Nitrogen Gases White, Jeremy C.; Dutta, Prabir K.; Shqau, Krenar Langmuir, Vol. 26, Issue 12, p. 10287-10293 https://doi.org/10.1021/la100463j	journal	June 2010
A Novel Approach to Gas Separations Using Composite Hollow Fiber Membranes Henis, Jay M. S.; Tripodi, Mary K. Separation Science and Technology, Vol. 15, Issue 4 https://doi.org/10.1080/01496398008076287	journal	May 1980
Preparation and Properties of Hydrothermally Stable γ-Alumina Membranes Nijmeijer, Arian; Kruidhof, Henk; Bredesen, Rune Journal of the American Ceramic Society, Vol. 84, Issue 1 https://doi.org/10.1111/j.1151-2916.2001.tb00620.x	journal	January 2001
Preparation and Properties of Porous α‐Al₂O₃ Membrane Supports Shqau, Krenar; Mottern, Matthew L.; Yu, Di Journal of the American Ceramic Society, Vol. 89, Issue 6, p. 1790-1794 https://doi.org/10.1111/j.1551-2916.2006.01037.x	journal	June 2006
Amine Scrubbing for CO2 Capture Rochelle, G. T. Science, Vol. 325, Issue 5948 https://doi.org/10.1126/science.1176731	journal	September 2009
Synthesis and Properties of PMR Matrix Resins of Poly(Pyrrolone-Benzimidazole)s Yan-Feng, Li; Hai-Xia, Yang; Lin-Cheng, Zhou High Performance Polymers, Vol. 16, Issue 1 https://doi.org/10.1177/0954008304036196	journal	March 2004
Microporous Silica and Zeolite Membranes for Hydrogen Purification Verweij, Henk; Lin, Y. S.; Dong, Junhang MRS Bulletin, Vol. 31, Issue 10 https://doi.org/10.1557/mrs2006.189	journal	October 2006
A Review of Carbon Dioxide Selective Membranes: A Topical Report Shekhawat, Dushyant; Luebke, David R.; Pennline, Henry W. https://doi.org/10.2172/819990	report	December 2003

Similar Records

Composite membranes for fluid separation

Patent · 1990 · OSTI ID:7237447

Enchanced gas separation process

Patent · 1987 · OSTI ID:6068240

Organic fluid permeation through fluoropolymer membranes

Patent · 2015 · OSTI ID:1193398

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Systems, compositions, and methods for fluid purification

Citation Formats

References (45)

Similar Records

Related Subjects