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Title: Sub-Doppler infrared spectroscopy of propargyl radical (H2CCCH) in a slit supersonic expansion

Journal Article · · The Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.4922931· OSTI ID:1228648
ORCiD logo [1];  [1]
  1. JILA, National Institute of Standards and Technology, University of Colorado, Boulder, Colorado 80309, USA and Department of Chemistry and Biochemistry, University of Colorado at Boulder, Boulder, Colorado 80309, USA

Sponsoring Organization:
USDOE
Grant/Contract Number:
FG02-09ER16021
OSTI ID:
1228648
Journal Information:
The Journal of Chemical Physics, Journal Name: The Journal of Chemical Physics Vol. 142 Journal Issue: 24; ISSN 0021-9606
Publisher:
American Institute of PhysicsCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

References (58)

The i.r., Raman and microwave spectra of 1-butene-3-yne (vinylacetylene) and 1-butene-3-yne-4d journal January 1980
The Recombination of Propargyl Radicals:  Solving the Master Equation journal August 2001
Concentration modulation spectroscopy with a pulsed slit supersonic discharge expansion source journal August 2001
Intramolecular competition in the photodissociation of C3D3 radicals at 248 and 193 nm journal January 2010
Is Soot Composed Predominantly of Carbon Clusters? journal March 1990
Rotationally resolved spectrum of the ν1 CH stretch of the propargyl radical (H2CCCH) journal July 1992
An intense slit discharge source of jet-cooled molecular ions and radicals (Trot < 30 K journal August 1996
Benchmark calculations with correlated molecular wave functions. IV. The classical barrier height of the H+H 2 →H 2 +H reaction journal May 1994
Time‐resolved diode laser spectroscopy of the ν 6 band of propargyl produced by the UV photolysis of allene journal October 1995
Sub-Doppler Spectroscopy of the trans -HOCO Radical in the OH Stretching Mode journal June 2013
Exploring formation pathways of aromatic compounds in laboratory-based model flames of aliphatic fuels journal September 2012
Detailed kinetic modeling of soot formation in shock tube pyrolysis and oxidation of toluene and n-heptane journal January 2007
Ab initio calculation of electronic absorption spectra and ionization potentials of C3H3 radicals journal January 2005
Matrix isolation study of the vacuum ultraviolet photolysis of allene and methylacetylene. Vibrational and electronic spectra of the species C3, C3H, C3H2, and C3H3 journal April 1974
The millimeter-wave spectrum and the dipole moment of vinylacetylene journal January 2003
Microwave Spectroscopy of Nonlinear Free Radicals. I. General Theory and Application to the Zeeman Effect in HCO
  • Bowater, I. C.; Brown, J. M.; Carrington, A.
  • Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 333, Issue 1594 https://doi.org/10.1098/rspa.1973.0062
journal May 1973
Photofragment translational spectroscopy of propargyl radicals at 248nm journal March 2008
Spectroscopy in slit supersonic jet discharges: fine and hyperfine structure calculations for asymmetric top radicals with multiple nuclear spins journal March 2007
Detailed kinetic modeling of soot formation in shock-tube pyrolysis of acetylene journal January 1985
The Coupling of Angular Momentum Vectors in Molecules journal July 1951
Theoretical studies on the ground state and low-lying doublet excited states of the propargyl radical journal August 1987
Carbon in the Universe journal December 1998
A Theoretical Investigation of the Propargyl Radical and its Cation journal January 1995
Jet cooled spectroscopy of H2DO+: Barrier heights and isotope-dependent tunneling dynamics from H3O+ to D3O+ journal October 2006
Chemistry of Molecular Growth Processes in Flames journal June 1987
Application of the Theory of Irreducible Tensor Operators to Molecular Hyperfine Structure journal December 1971
Benchmark calculations with correlated molecular wave functions. II. Configuration interaction calculations on first row diatomic hydrides journal August 1993
Rate Constant Measurement of the Recombination Reaction C3H3 + C3H3 journal July 1994
Absolute photoionization cross-section of the propargyl radical journal April 2012
Propargyl Radical:  Ab Initio Anharmonic Modes and the Polarized Infrared Absorption Spectra of Matrix-Isolated HCCCH 2 journal May 2005
The vinyl radical investigated by infrared diode laser kinetic spectroscopy journal January 1990
Electron spin resonance studies of vinyl, propargyl, and butatrienyl radicals isolated in argon matrices journal August 1972
Calculations of Rate Coefficients for the Chemically Activated Reactions of Acetylene with Vinylic and Aromatic Radicals journal November 1994
A reduced form of the spin-rotation Hamiltonian for asymmetric-top molecules, with applications to HO2 and NH2 journal April 1979
The C–D Stretch of Monodeuterated Propargyl Radical (CH2CCD) journal November 1997
Spin-rotation interaction constants for bent AH 2 molecules in doublet electronic states journal January 1965
Reaction mechanism of soot formation in flames journal February 2002
“Imaging” combustion chemistry via multiplexed synchrotron-photoionization mass spectrometry journal January 2008
Supersonically cooled hydronium ions in a slit-jet discharge: High-resolution infrared spectroscopy and tunneling dynamics of HD2O+ journal June 2005
High-resolution infrared spectroscopy of jet-cooled vinyl radical: Symmetric CH2 stretch excitation and tunneling dynamics journal January 2008
Reactions between Resonance-Stabilized Radicals: Propargyl + Allyl journal April 2010
Calculation of inertia defect journal January 1961
The ν3 Fundamental in C2H2 journal February 1993
The Electronic Absorption Spectrum of the Propargyl Radical journal July 1966
Electron spin resonance of free radicals from acetylenes and allenes journal July 1970
Infrared Laser Absorption Measurements of the Kinetics of Propargyl Radical Self-Reaction and the 193 nm Photolysis of Propyne journal June 2003
Association rate constants for reactions between resonance-stabilized radicals: C3H3 + C3H3, C3H3 + C3H5, and C3H5 + C3H5 journal January 2007
Infrared diode laser spectroscopic detection of the propargyl radical produced in a supersonic jet expansion by UV laser photolysis journal December 1994
Propargyl from the Reaction of Singlet Methylene with Acetylene journal January 1996
Analysis of theK-Subband Structure of the ν1Fundamental of Propargyl Radical H2CC≡CH journal January 1998
Microwave Spectrum of Chlorine Dioxide. III. Interpretation of the Hyperfine Coupling Constants Obtained in Terms of the Electronic Structure journal August 1962
The Recombination of Propargyl Radicals and Other Reactions on a C 6 H 6 Potential journal October 2003
Space, Stars, C60, and Soot journal November 1988
Ultrasensitive laser measurements without tears journal January 1997
High-Resolution Rovibrational Spectroscopy of Jet-Cooled Phenyl Radical: The ν 19 Out-of-Phase Symmetric CH Stretch journal March 2013
Pulsed discharge nozzle Fourier transform microwave spectroscopy of the propargyl radical (H2CCCH) journal August 1997
Disclosing Identities in Diffuse Interstellar Bands journal January 2011
Chemical Kinetics and Combustion Modeling journal October 1990

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