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Title: Dynamic nuclear polarization solid-state NMR in heterogeneous catalysis research

Journal Article · · ACS Catalysis
 [1];  [1];  [2];  [2];  [2]
  1. Ames Lab., Ames, IA (United States)
  2. Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)

In this study, a revolution in solid-state nuclear magnetic resonance (SSNMR) spectroscopy is taking place, attributable to the rapid development of high-field dynamic nuclear polarization (DNP), a technique yielding sensitivity improvements of 2–3 orders of magnitude. This higher sensitivity in SSNMR has already impacted materials research, and the implications of new methods on catalytic sciences are expected to be profound.

Research Organization:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-07CH11358
OSTI ID:
1227432
Report Number(s):
IS-J-8825
Journal Information:
ACS Catalysis, Journal Name: ACS Catalysis; ISSN 2155-5435
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 133 works
Citation information provided by
Web of Science

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  • Wiench, Jerzy W.; Bronnimann, Charles E.; Lin, Victor S. -Y
  • Journal of the American Chemical Society, Vol. 129, Issue 40, p. 12076-12077 https://doi.org/10.1021/ja074746+
journal September 2007
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35 Cl dynamic nuclear polarization solid-state NMR of active pharmaceutical ingredients journal January 2016
Understanding Surface and Interfacial Chemistry in Functional Nanomaterials via Solid-State NMR journal March 2017
Single-Site Heterogeneous Catalysts: From Synthesis to NMR Signal Enhancement journal November 2018
Fast and accurate MAS–DNP simulations of large spin ensembles journal January 2017
DNP NMR spectroscopy of cross-linked organic polymers: rational guidelines towards optimal sample preparation journal January 2020
19 F Magic Angle Spinning Dynamic Nuclear Polarization Enhanced NMR Spectroscopy journal April 2019
Fast detection and structural identification of carbocations on zeolites by dynamic nuclear polarization enhanced solid-state NMR journal January 2018
Large-scale ab initio simulations of MAS DNP enhancements using a Monte Carlo optimization strategy journal October 2018
Shedding light on the atomic-scale structure of amorphous silica-alumina and its Brønsted acid sites text January 2019
19 F Magic Angle Spinning Dynamic Nuclear Polarization Enhanced NMR Spectroscopy journal May 2019
Resolving the Core and the Surface of CdSe Quantum Dots and Nanoplatelets Using Dynamic Nuclear Polarization Enhanced PASS–PIETA NMR Spectroscopy journal June 2018
One- and Two-Dimensional High-Resolution NMR from Flat Surfaces text January 2019