Synergistic interaction between oxides of copper and iron for production of fatty alcohols from fatty acids
Abstract
In this study, the selective hydrogenation of fatty acids to fatty alcohols can be achieved under moderate conditions (180 °C, 30 bar H2) by simultaneously supporting copper and iron oxides on mesoporous silica nanoparticles. The activity of the cosupported oxides is significantly higher than that of each supported metal oxide and of a physical mixture of both individually supported metal oxides. A strong interaction between both metal oxides is evident from dispersion, XRD, TPR, and acetic acid TPD measurements, which is likely responsible for the synergistic behavior of the catalyst. Copper oxide is reduced in situ to its metallic form and thereby activates hydrogen.
- Authors:
-
- Iowa State Univ., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1227427
- Report Number(s):
- IS-J-8732
Journal ID: ISSN 2155-5435
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 11; Journal ID: ISSN 2155-5435
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; fatty alcohols; fatty acids; biorenewables; mesoporous silica; iron oxide; copper oxide
Citation Formats
Kandel, Kapil, Chaudhary, Umesh, Nelson, Nicholas C., and Slowing, Igor I. Synergistic interaction between oxides of copper and iron for production of fatty alcohols from fatty acids. United States: N. p., 2015.
Web. doi:10.1021/acscatal.5b01664.
Kandel, Kapil, Chaudhary, Umesh, Nelson, Nicholas C., & Slowing, Igor I. Synergistic interaction between oxides of copper and iron for production of fatty alcohols from fatty acids. United States. https://doi.org/10.1021/acscatal.5b01664
Kandel, Kapil, Chaudhary, Umesh, Nelson, Nicholas C., and Slowing, Igor I. 2015.
"Synergistic interaction between oxides of copper and iron for production of fatty alcohols from fatty acids". United States. https://doi.org/10.1021/acscatal.5b01664. https://www.osti.gov/servlets/purl/1227427.
@article{osti_1227427,
title = {Synergistic interaction between oxides of copper and iron for production of fatty alcohols from fatty acids},
author = {Kandel, Kapil and Chaudhary, Umesh and Nelson, Nicholas C. and Slowing, Igor I.},
abstractNote = {In this study, the selective hydrogenation of fatty acids to fatty alcohols can be achieved under moderate conditions (180 °C, 30 bar H2) by simultaneously supporting copper and iron oxides on mesoporous silica nanoparticles. The activity of the cosupported oxides is significantly higher than that of each supported metal oxide and of a physical mixture of both individually supported metal oxides. A strong interaction between both metal oxides is evident from dispersion, XRD, TPR, and acetic acid TPD measurements, which is likely responsible for the synergistic behavior of the catalyst. Copper oxide is reduced in situ to its metallic form and thereby activates hydrogen.},
doi = {10.1021/acscatal.5b01664},
url = {https://www.osti.gov/biblio/1227427},
journal = {ACS Catalysis},
issn = {2155-5435},
number = 11,
volume = 5,
place = {United States},
year = {Thu Oct 08 00:00:00 EDT 2015},
month = {Thu Oct 08 00:00:00 EDT 2015}
}
Web of Science
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