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Title: Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations

Abstract

A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.

Inventors:
; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1226816
Patent Number(s):
9,194,920
Application Number:
13/648,751
Assignee:
Battelle Memorial Institute (Richland, WA)
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 Oct 10
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., and Peden, Charles H. F. Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations. United States: N. p., 2015. Web.
Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., & Peden, Charles H. F. Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations. United States.
Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., and Peden, Charles H. F. Tue . "Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations". United States. https://www.osti.gov/servlets/purl/1226816.
@article{osti_1226816,
title = {Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations},
author = {Hu, Jian Zhi and Sears, Jr., Jesse A. and Hoyt, David W. and Mehta, Hardeep S. and Peden, Charles H. F.},
abstractNote = {A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2015},
month = {11}
}

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